Use of weibull statistics to quantify property variability in TiAl alloys

Tensile experiments have been performed on specimens of four different investment-cast TiAl-based alloys with variations in casting conditions. The average ductilities obtained in these experiments vary between approximately 0.8 to 2.0 pct plastic strain to failure in tension. By using the three-parameter form of the Weibull relation, with the 0.2 pct offset yield strength as the minimum failure strength, the resulting variability in the data can be quantified and is found to be similar for those alloys with similar microstructural scale (grain size). Large variations in lamellar volume fraction, segregation, and phase distribution have a minor influence on property variability, compared to changes in the scale of the grain structure caused by either variations in cooling rate during casting or the addition of grain refiners.     

Atmospheric dry deposition of persistent organic pollutants to the Atlantic and inferences for the global oceans

Atmospheric deposition to the oceans is a key process affecting the global dynamics and sinks of persistent organic pollutants (POPs). A new methodology that combines aerosol remote sensing measurements with measured POP aerosol-phase concentrations is presented to derive dry particulate depositional fluxes of POPs to the oceans. These fluxes are compared with those due to diffusive air-water exchange. For all polychlorinated biphenyl (PCB) congeners and lower chlorinated dibenzo-p-dioxins and furans (PCDD/Fs), air-water exchange dominates the dry deposition mechanism. However, this tendency reverses in some areas, such as in marine aerosol influenced areas and dust outflow regions, consistent with the important variability encountered for the depositional fluxes. Seasonal variability is mainly found in mid-high latitudes, due to the important influence of wind speed enhancing dry deposition fluxes and temperature as a driver of the gas-particle partitioning of POPs. The average dry aerosol deposition flux of sigmaPCBs and sigmaPCDD/Fs to the Atlantic Ocean is calculated to be in the order of 66 ng m(-2) yr(-1) and 9 ng m(-2)yr(-1) respectively. The total dry aerosol deposition of sigmaPCBs and sigmaPCDD/Fs to the Atlantic Ocean is estimated to be 2200 kg yr(-1) and 500 kg yr(-1), respectively, while the net air-water exchange is higher, 22000 kg sigmaPCBs yr(-1) for PCBs and 1300 kg sigmaPCDD/Fs yr(-1). Furthermore, it is suggested that marine aerosol plays an important role in scavenging atmospheric contaminants.     

Cast structure and property variability in gamma titanium aluminides

Aspects of cast structure that influence mechanical property variability, and in particular tensile ductility, have been studied in a Ti-48Al-2Cr-2Nb titanium aluminide alloy. Macrostructure, porosity, microstructure and tensile properties have been characterized over a range of casting processing conditions. Local solidification times and subsequent solid-state cooling rates during casting have been characterized via local thermal measurements in combination with solidification modeling. Large variations in cooling rate during casting dramatically influence the initial cast structure as well as the distribution of defects such as porosity. Variations in as-cast structure persist through subsequent thermal and hot isostatic pressing cycles and contribute to the variability of tensile ductility. The current understanding of the relationship of tensile ductility to processing-induced changes in structure will be briefly discussed.     

Designing long reach optical access networks

The long reach optical access concept promises to reduce the cost of a future BT network through simplification. This is achieved by extending the reach and split of today’s passive optical network systems (PONs) to 100 km and 1024 respectively, thus eliminating the need for separate backhaul equipment. Compact, low-power optical amplifiers are used at exchange locations requiring very low electrical power consumption. Ultimately this could effectively eliminate local exchange buildings and consolidate BT’s network to around a hundred metro nodes, drastically reducing operational costs. In this paper we describe research to date on the techniques to overcome physical layer impairments at costs appropriate for residential access. We also highlight from an operator’s point of view the protocol requirements of the LR-PON concept, point out the necessary changes to the GPON protocol, and describe an experiment to show its suitability to work over 100 km distances at 10 Gbit/s.     

Near‐infrared spectroscopy for analysis of oil content and fatty acid profile in almond flour

Almond kernels show large variability for oil content and fatty acid profile. The objective of this research was to evaluate the potential of near infrared (NIR) reflectance spectroscopy (NIRS) for the analysis of these traits in almond flour. Ground kernels of 181 accessions collected in 2009 were used for developing calibration equations for oil content and concentrations of individual fatty acids. Calibration equations were developed using second derivative transformation and modified partial least squares regression. They were validated with samples from 179 accessions collected in 2010. The accuracy of calibration equations was measured through the coefficient of determination (r²) in external validation and the ratio of the SD in the validation set to the standard error of prediction (RPD). Both r² and RPD were high for oil content (r² = 0.99; RPD = 9.24) and concentrations of oleic (r² = 0.97; RPD = 5.37) and linoleic acids (r² = 0.98; RPD = 7.35), revealing that calibration equations for these traits are highly accurate. Conversely, the accuracy of the calibration equations for palmitic (r² = 0.54; RPD = 1.41) and stearic acids (r² = 0.52; RPD = 1.44) was too low for allowing their application in practice. NIRS discrimination of oil content and concentrations of oleic and linoleic acids was mainly based on the spectral region from 2240 to 2380 nm. Practical applications : NIRS is a high‐throughput analytical technique that allows fast measurement of several traits in a single analysis without using chemical reagents. We evaluated the feasibility of analyzing oil content and concentrations of palmitic, stearic, oleic, and linoleic acids in almond flour using fruits collected during 2 years from a world germplasm collection. The fruits collected in 2009 were used for NIRS calibration, whereas the fruits collected in 2010 were used for validation. NIRS equations were highly accurate for measuring oil content and concentrations of oleic and linoleic acids, which are important traits defining the quality of almond flour for specific uses in the food industry. These results have applications both in the research laboratory and the food industry, where NIRS is becoming a widely used technique for quality control.     

The evolution of data science and big data research: A bibliometric analysis

Scientometrics - In this study the evolution of Big Data (BD) and Data Science (DS) literatures and the relationship between the two are analyzed by bibliometric indicators that help establish the...     

Pauses and Response Latencies: A Chronemic Analysis of Asynchronous CMC

This study examines the chronemics of response latencies in asynchronous computer‐mediated communication (CMC) by analyzing three datasets comprising a total of more than 150,000 responses: email responses created by corporate employees, responses created by university students in course discussion groups, and responses to questions posted in a public, commercial online information market. Mathematical analysis of response latencies reveals a normative pattern common to all three datasets: The response latencies yielded a power‐law distribution, such that most of the responses (at least 70%) were created within the average response latency of the responders, while very few (at most 4%) of the responses were created after a period longer than 10 times the average response latency. These patterns persist across diverse user populations, contexts, technologies, and average response latencies. Moreover, it is shown that the same pattern appears in traditional, spoken communication and in other forms of online media such as online surveys. The implications of this uniformity are discussed, and three normative chronemic zones are identified.     

Conversation as a source of satisfaction and continuance in a question-and-answer site

Generating sustainable business value from information services is challenging on the web where free information and zero-switching costs are the norm. This study examines the role of free comments given in a commercial information service through the lens of the expectation-confirmation theory and continuance. Data from a question and answer web site are analyzed by structural equations modeling to test the theoretical model whereby customer satisfaction is key to continuance and is predicted largely by social interaction that takes place on the site. The model is supported by the field data retrieved from the site. The data show that people came with equal expectations, received equal service, and continued to use the system if they were satisfied with it. Satisfaction was predicted by conversation. Free activity emerges as an integral part of the service in a fee-based information market, improving satisfaction and continuance, and thereby leading to measurable outcomes for the commercial owners of the site. The findings, based on unobtrusive field data rather than self-report questionnaires, extend expectation confirmation theory by adding a social dimension to it.