掺铕稀土配合物的光学树脂荧光光谱研究

报道了将多种稀土铕配合物复合于苯乙烯(ST)／甲基丙烯酸(HMA)的共聚体系,研究了含稀土配合物透明光学树脂的光学性能。发现其具有发光效率高,光谱呈现尖锐的线状谱带及相对于纯稀土配合物粉末来说掺有稀土配合物的光学树脂的发射产生光谱红移等特点。特别是用电子云重排效应(当中心稀土离子与不同配体结合时,其相同的J能级间的跃迁谱带位置略有移动的现象)解释了掺有稀土配合物的光学树脂发射光谱红移现象。并推断出在含稀土配合物复合于光学树脂后。稀土中心离子和配位原子间距离有所减小。     

Kinetics of Fluorescence Decay in Er~(3+)∶YAG under 408.6 nm Excitation

Because trivalent erbium ion doped in opticalhosts has abundant energy structure ,ultraviolet ,visi-ble and infrared fluorescences can be performed .Andmany Er3 +-doped materials have been extensivelystudied on energy levels ,energy transfer , upconver-sionluminescence andlaser actions[1 ~7].Among Er3 +-doped materials ,Er3 +∶YAGis an excellent laser crys-tal for a solid state laser due to its remarkable virtuessuch as chemical stability , durability , UVresistanceas well as good thermal c…     

Kinetics of Fluorescence Decay in Er^3＋ ：YAG under 408.6 nm Excitation

The violet and green fluorescence spectra and the kinetics of fluorescence decay in Er^3＋ ：YAG crystal under 408.6 nm excitation were investigated by the time-resolved laser-induced fluorescence technique. The influence of multiphonon and energy transfer on the fluorescence decay of the ^4S3/2 rnultiplet were theoretically analyzed. A good agreement of the measured and the simulated decay curves was achieved. The continuous profile variety of the decay curves in the region from 548 to 561.2 nrn is found and it originates from the fluorescence overlap of ^2G9/2 and ^4S3/2 and the intensity ratio dominates the profile.     

基于1S0能级的Pr3+:ZBLAN光纤上转换紫外激光的数值模拟

在Pr3 ∶ZBLAN光纤中,运用粒子数速率方程理论,研究用586 nm和335 nm连续激光双光子激发4f组态最高能级1S0,以1S0和3F4为激光上下能级实现250 nm上转换紫外激光的动力学行为,得到阈值抽运功率、激光输出功率、斜率效率和最佳光纤长度等激光参数。结果表明,阈值抽运功率随光纤长度增加而增大,斜率效率随光纤长度增加而减小,光纤较短时,无法获得较高输出功率。掺杂浓度越大则阈值抽运功率越小,斜率效率越大。在选取的特定条件下,斜率效率最高可达16.7%。     

低能Xe离子辐照在Al表面上的光辐射研究

本文测量了200~550 keV的Xe10+离子轰击高纯度（9999%）Al表面诱发的溅射Al原子的光发射,研究了Al Ⅰ 30810、30914、39452、39628 nm光谱线强度比值和光子产额随入射离子能量的变化趋势。在本实验能量范围内,辐射光谱线强度比值随入射离子能量增加几乎不变,而发射谱线的光子产额随入射离子能量的增加呈现出不同趋势：入射离子能量为450 keV时,光子产额出现极大值,入射离子能量超过450 keV时,光子产额随能量的增加而减少,其变化趋势与核阻止本领随能量增加的变化没有出现类同的变化特征。结合核阻止和电子阻止效应对实验结果进行了讨论,结果表明：入射离子能量低于450 keV时,核阻止在碰撞中起主导作用,入射离子能量高于450 keV时,电子阻止在碰撞中起主导作用。