Large macro-dipoles generated in a supramolecular polymer of N,N′,N″-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide in n-decane

A supramolecular polymer formed by N,N′,N″-tris(3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide (DO₃B) in n-decane (C₁₀) possesses large macro-dipoles naturally generated by three-fold inter-molecular hydrogen bonding aligned along its helical columnar structure connected by defective portions, which are DO₃B molecules containing failure in the hydrogen bond formation, in the order of head to tail arrangement without dipole inversion like type-A polymers.     

Upper and lower critical solution temperatures in poly (ethylene glycol) solutions

Upper and lower critical solution temperatures have been determined for solutions of poly(ethylene glycol) in t-butyl acetate and water over the molecular weight range of M_η = 2.18 × 10³ to ～1020 × 10³. The phase diagram for solutions of poly(ethylene glycol) (M_η = 719 × 10³) in t-butyl acetate was expressed as the ‘hour glass’ type, while the phase diagram for solution of poly(ethylene glycol) (M_η = 2.18 × 10³ to ～2.29 × 10³) in water was expressed as the ‘closed loop’ type. The value of the pressure dependence of the lower critical solution temperature $\text{(}\text{d}\text{T}\text{d}\text{P}\text{)}{}_{\mathrm{c}}$ in the poly(ethylene glycol) (M_η = 1020 × 10³)/water system over the pressure range of 0 to ～50 atm was negligibly small and positive.     

Control of three-link underactuated manipulators using a switching method of fuzzy energy regions

In general, manipulators used for industry and in academic laboratories have actuators to drive each joint. On the other hand, underactuated manipulators handled by our research have some passive or free joints without actuators and brakes. We recently developed a switching method of fuzzy energy regions to control such manipulators. In such a method, it is necessary to design parameters related to energy regions and the gains of some partly stable controllers based on the computed torque method. Here, the switching method is applied for a three-link underactuated manipulator. We optimize such design parameters related to fuzzy energy regions by a genetic algorithm. The effectiveness of the present method is illustrated with some simulations. This work was presented in part at the 12th International Symposium on Artificial Life and Robotics, Oita, Japan, January 25–27, 2007     

Microstructure evolution during thermomechanical processing in 3Mn-0.1C medium-Mn steel

ABSTRACT

Medium-Mn steels are energetically investigated as a candidate of the third generation advanced high strength steels (AHSSs). However, their phase transformation and microstructaure evolution during various heat treatments and thermomechanical processing are still unclear. The present study first confirmed the kinetics of static phase transformation behaviour in a 3Mn-0.1C medium-Mn steel. Hot compression tests were also carried out to investigate the influence of high-temperature deformation of austenite on subsequent microstructure evolution. It was found that static ferrite transformation was quite slow in this steel, but ferrite transformation was greatly accelerated by the hot deformation in austenite and ferrite two-phase regions. Characteristic dual-phase microstructures composed of martensite and fine-grained ferrite were obtained, which exhibited superior mechanical properties.

This paper is part of a Thematic Issue on Medium Manganese Steels.     

Evaluation of thermal spike due to exothermic reaction in curing process of carbon fiber-reinforced plastic pressure accumulators for hydrogen stations

In the curing process of fiber-reinforced plastic accumulators, a thermal spike appears due to the exothermic reaction of the resin. It is necessary to accurately evaluate this thermal spike to guarantee quality and avoid using a trial and error approach to control the temperature. Thus, we developed a curing process simulator that is able to accurately evaluate the thermal spike of the thermosetting resin. A simplified mesoscale finite element model with the definite separation of fiber and resin is used in the simulation. In this study, the newly developed simulation system was examined by comparing its results with the experimental results from the curing process of fiber-reinforced plastic accumulators.     

Friction Powder Compaction for Fabrication of Open-Cell Aluminum Foam by the Sintering and Dissolution Process Route

A new friction powder compaction (FPC) process by the sintering and dissolution process (SDP) route for fabricating open-cell aluminum (Al) foam, which requires no external heat sources, was developed. Foams with porosities of 74 and 83 pct were successfully fabricated and their compressive responses were investigated. The sintered mixture during the removal process was observed nondestructively by X-ray computed tomography (CT) to reveal the progress of the removal of soluble particles and to confirm that they were completely dissolved.     

Fabrication of Functionally Graded SiO2‐Mo Material by Centrifugation and Floc‐Casting of Highly Concentrated Slurry

To fabricate functionally graded materials, a highly concentrated slurry of SiO₂‐Mo system was prepared and centrifugal force was applied in an attempt to achieve a graded composition. Subsequently, we formed a homogeneous green body with compositional gradation by floc‐casting at 80°C, which was then fired at 1750°C for 10 min in Ar. The sintered body had compositional ratios of SiO₂ and Mo as well as electrical conductivities that changed gradually along the direction of centrifugal force. The results demonstrate that centrifugation and control of slurry characteristics such as flocculation are effective in fabricating functionally graded SiO₂‐Mo materials.     

Reaction stoichiometry between TiCl3 and NaAlH4 in Ti-doped alanate for hydrogen storage: The fate of the titanium species

In order to understand the final state of the TiCl₃ dopant during the dehydrogenation and rehydrogenation cycles of NaAlH₄, we determined the reaction stoichiometry between TiCl₃ and NaAlH₄ by measuring the amount of hydrogen evolution from NaAlH₄ with the varying TiCl₃ -load. We found that: (i) TiCl₃ reacted with 3 M equivalents of NaAlH₄ during the doping process of ball-milling, (ii) the Ti dopant continued to react with NaAlH₄ during the first dehydrogenation process until total six equivalents of NaAlH₄ were consumed, and (iii) Ti fixed Al, not NaH, so that Al became insufficient during the rehydrogenation process. These findings lead to the conclusion that the reaction stoichiometry between Ti and Al is 1:6, which probably yields TiAl₆ and plays a catalytic role in the hydrogen storage reactions of Ti-doped NaAlH₄.     

Ultra-high-precision time control system over any long time delay for laser pump and synchrotron x-ray probe experiment

An ultra-high-precision clock system for long time delay has been developed for picosecond time-resolved x-ray diffraction measurements using synchrotron radiation (SR) pulses and synchronized femtosecond laser pulses. The time delay control between pump laser pulse and the probe SR pulse was achieved by combining an in-phase quadrature modulator and a synchronous counter. This method allowed us to change the delay time by a nearly infinite amount while maintaining the precision of +/-8.40 ps. Time-resolved diffraction measurements using the delay control system were demonstrated for precise measurement of an acoustic velocity in a single crystal of gallium arsenide.