Current variability in a wide and open lacustrine embayment in Lake Geneva (Switzerland)

Field measurements and numerical simulations were used to determine the effects of dominant meteorological conditions on the hydrodynamics of a wide (aspect ratio ~ 2), relatively deep (seasonally stratified) and open lake embayment (Vidy Bay, Lake Geneva). A three-dimensional hydrodynamic model (Delft3D-FLOW) was employed to simulate flow in the lake. High-resolution maps of wind, temperature and humidity (over the lake) were applied as input to drive the model. Because wind was the main force driving flow in the lake, currents in the embayment were investigated systematically for different wind conditions and seasonal stratification. Satisfactory model validation was achieved using drifter and moored measurements within the embayment. Markedly different circulation patterns were measured within the embayment, with the transition from one pattern to another occurring abruptly for small changes in wind direction. These distinct patterns resulted from relatively small changes in the large gyre of Lake Geneva's main basin, especially the angle between the current in front of the embayment and the embayment shoreline. The boundary between the embayment and the pelagic zone was defined by the largest gyre within the embayment. This study shows that, (i) in a large lake, complex current patterns can occur even within a minor embayment, and (ii) that these patterns can transition rapidly over a small range of wind directions. Near-shore gyre can occur for lengthy periods, which has implications for flushing of discharges within the embayment.     

Assessment on the mechanical,structural, and thermal attributes of green graphene-based water soluble polymer electrolyte composites

In the current study, graphene oxide (GO) was prepared using green chemistry with modified Hummer's method without incorporating sodium nitrate (NaNO₃). Solvent casting was employed to fabricate GO-doped poly(ethylene oxide) (PEO), that is, PEO/GO composites with various proportion of Na₂SO₄ and were then subjected to characterization via advanced spectroscopic techniques for different physicochemical aspects to estimate their potential applications as marketable products. XRD analysis explored that fabricated composites are more crystalline than neat PEO. PEO/GO/Na₂SO₄ composite films offered maximum crystallinity. SEM displayed the same trend. TG/DTA thermogram exposed better thermal stability than pristine polymer. FTIR studies confirmed complexation among hybrid's components. Elongation-at-break and Young's modulus displayed an enhancing behavior with an incremental loading of salt and filler. In terms of mechanical performance, composite of PEO with 0.37 wt % GO and 0.08 g salt was found to be an ideal composition during the course of study. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48376.     

Feedback reactivity coefficients and their coupling

Coupled reactivity feedback coefficients which accounts for variation in fuel temperature and moderator void simultaneously, have been determined for swimming pool type research reactor namely Pakistan Research Reactor PARR-1. The state of art is core criticality calculations, employing lattice cell code WIMS-D/4 and application of Taylor series expansion for core reactivity up to third order, involving two variables, i.e. fuel temperature and coolant void. The spectral effects in one region due to change of parameter in other region have also been studied. When spectral changes in moderator region due to 20 K change in fuel temperature have been incorporated in the calculation of fuel temperature coefficient, the results seems to be improved by 4.12%. Further, the results of void coefficient of reactivity show the improvement of 0.1% when the spectral effect in fuel region due to 5% change in void in moderator region is taken into account. These differences seem to be an improvement in the results, as physically any change in one region is accompanied by change in the other region.     

Effect of cloisite 30B on the thermal and tensile behavior of poly(butylene adipate-co-terephthalate)/poly(vinyl chloride) nanoblends

Ternary PBAT/PVC/C30B nanoblends were successfully prepared via melt blending process at 130 °C and characterized by different techniques. The properties of the elaborated PBAT/PVC/C30B nanoblends were compared with those of the nonfilled PBAT/PVC blends to examine the C30B effects on the structure and properties of PBAT/PVC/C30B nanoblends. FTIR spectra revealed the presence of specific interactions between C=O of PBAT and acidic hydrogen of PVC, supporting the formation of miscible nanoblends. The PBAT/PVC/C30B morphology was investigated by both X-ray diffraction and transmission electron microscopy analyses. It was suggested the formation of mixed intercalated/partially exfoliated structures. Differential scanning calorimetry thermograms of PBAT/PVC/C30B nanoblends exhibited a single T _g and a full disappearance of the PBAT melting endotherm, confirming the complete compatibilization between PVC and PBAT. It was found that the T _g of the nanoblends were higher than those of the pristine blends due to their mixed intercalated/partially exfoliated structures. PBAT and PVC chains would be confined in a same C30B gallery causing a reduction of the chain mobility. Nanoblends showed a reduction of their thermal stability compared to their pristine blends, as a result of the catalytic effect of the C30B in the thermal degradation process. Tensile measurements displayed an improvement of mechanical properties for the ternary PBAT/PVC/C30B nanoblends relative to their virgin blends due to the insertion of clay particles into composite matrix.     

Radiological hazards of TENORM in precipitated calcium carbonate generated as waste at nitrophosphate fertilizer plant in Pakistan

The NORM (naturally occurring radioactive material) in phosphate rock is transferred as TENORM (technologically enhanced naturally occurring radioactive material) to phosphatic fertilizers and to the waste generated by the chemical processes. The waste generated at the NP (nitrophosphate) fertilizer plant at Multan in Pakistan is PCC (precipitated calcium carbonate). Thirty samples of the PCC were collected from the heaps of the waste near the fertilizer plant. Activity concentrations of radionuclides in the waste samples were measured by using the technique of gamma ray spectrometry consisting of coaxial type HPGe (high purity germanium) detector coupled with a PC (personal computer) based MCA (multichannel analyzer) through a spectroscopy amplifier. Activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in the waste samples were determined to be 273 ± 23 (173-398), 32 ± 4 (26-39) and 56 ± 5 (46-66) Bq kg⁻¹ respectively. The activity concentration of ²²⁶Ra in the PCC waste was found to be higher than that in naturally occurring calcium carbonate (limestone and marble) and in worldwide soil. Radiological hazard was estimated from indoor and outdoor exposure to gamma rays from the PCC. Indoor annual effective dose was higher than 1 m Sv. Potential radiological pollution in the environment from TENORM in the PCC has also been addressed.     

Synthesis of esters: Development of the rate expression for the Dowex 50 Wx8-400 catalyzed esterification of propionic acid with 1-propanol

The kinetics of the esterification reaction of propionic acid with 1-propanol over the ion-exchange resin Dowex 50Wx8-400 has been studied in this investigation. Kinetic experiments were conducted using a 1 L Lab-Max system at a stirrer speed of 900 rpm over a temperature range of 303.15 -333.15 K. The catalyst loading was varied from 10 to 60 g dry cat/L and acid to alcohol molar ratios of 1:1, 1:2, 1:4, 2:1 and 4:1 were employed. The equilibrium constants for this reaction were determined in separate experiments at 303.15, 313.15 and 323.15 K. The values were equal to 33.18, 30.62 and 28.37, respectively, with a standard enthalpy change of reaction of 6.4 kJ/mol. These values show the reaction to be mildly exothermic. It was found that both external and internal diffusion limitations did not affect the overall reaction rate. The conversion of propionic acid increased with increasing temperature and catalyst loading and decreased with increasing initial mole fraction of acid. The increase in chain length of acid or alcohol or branching had a retarding effect on the conversion. Several kinetic models were tested to correlate the kinetic data, the pseudo-homogeneous (P-H) model, the Eley-Rideal (E-R) model, the Langmuir-Hinshelwood (L-H) model, the modified Eley-Rideal (M-E-R) model and the modified Langmuir-Hinshelwood (M-L-H) model. In all models, the activity coefficients were estimated using UNIFAC to account for the non-ideal thermodynamic behavior of reactants and products. A correction factor for the resin affinity for water (α) was used in both M-E-R and M-L-H models. The above models predicted the kinetic behavior of the studied system with an overall error ranging from 1.65% to 13.32%. Water was found to be more strongly adsorbed than other species present in the system. The M-E-R model between adsorbed 1-propanol and non-adsorbed propionic acid which assumes surface reaction as the rate controlling step, with α equal to 2, was found to be the best model with the least overall error (1.65%). The activation energy for the esterification was estimated to be 67.3 kJ/mol by this model.     

Time Dependent Ambient Oxidation of AA6061-T6 Alloy at the Temperature of 580°C

Protection of Metals and Physical Chemistry of Surfaces - The AA6061-T6 alloy is used in many industrial applications such as hydraulic pistons, aerospace and marine vehicle fittings, including the...     

Surfaces modification of methylcellulose: Cobalt nitrate polymer electrolyte by sulfurated hydrogen gas treatment

This article discusses the surface modification of methylcellulose:nitrate cobalt [MC:Co(NO₃)₂] through the sulfurated hydrogen (H₂S) gas treatment. Solution cast technique has been used to fabricate MC:Co(NO₃)₂‐based solid polymer electrolytes. The results achieved for structural, morphological and optical properties indicate that H₂S gas treatment is crucial for modification of polymer electrolytes to polymer composites. The morphological appearance revealed that the H₂S gas treatment produced cobalt sulfide (CoS) nanoparticles on the surface of the films. The results of X‐ray diffraction indicate the disruption of the crystalline phase of the MC polymer upon addition of various amounts of Co(NO₃)₂ salt. The optical absorption spectra of the electrolyte samples shifted to higher wavelengths with increasing the cobalt nitrate salt concentration. The optical band gap of MC incorporated with 40 wt % Co(NO₃)₂ concentration was 4.69 and reduced to 4.52 eV after H₂S surface treatment. The linear relationship between the refractive index and salt concentration supports the uniform distribution of the developed nanoparticles appeared in STM images. The significant change in intensity and position of Fourier transform infrared transmittance bands is an evidence for the formation of charge transfer complex between the added salt and the MC host polymer. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46676.     

Microtube Array Membrane Encapsulated Cell Therapy: A Novel Platform Technology Solution for Treatment of Alzheimer’s Disease

Alzheimer’s disease is the most frequent form of dementia in aging population and is presently the world’s sixth largest cause of mortality. With the advancement of therapies, several solutions have been developed such as passive immunotherapy against these misfolded proteins, thereby resulting in the clearance. Within this segment, encapsulated cell therapy (ECT) solutions that utilize antibody releasing cells have been proposed with a multitude of techniques under development. Hence, in this study, we utilized our novel and patented Microtube Array Membranes (MTAMs) as an encapsulating platform system with anti-pTau antibody-secreting hybridoma cells to study the impact of it on Alzheimer’s disease. In vivo results revealed that in the water maze, the mice implanted with hybridoma cell MTAMs intracranially (IN) and subcutaneously (SC) showed improvement in the time spent the goal quadrant and escape latency. In passive avoidance, hybridoma cell loaded MTAMs (IN and SC) performed significantly well in step-through latency. At the end of treatment, animals with hybridoma cell loaded MTAMs had lower phosphorylated tau (pTau) expression than empty MTAMs had. Combining both experimental results unveiled that the clearance of phosphorylated tau might rescue the cognitive impairment associated with AD.     

Interactive movie elements in a pervasive game

This paper presents our research initiatives around new user experiences in the area of pervasive mixed reality crossmedia gaming. In a prototypical game, The Epidemic Menace, we combined static and interactive story telling elements to create a mixed reality experience. As part of this research initiative we also investigated how elements of the real world and virtual worlds could produce a new environment where physical and digital objects can co-exist and interact with each other, we wanted to evaluate how linear stories could be integrated into a game flow and how they could be used to extend game experiences. A new form of interactive entertainment that is not limited to hardware based games or linear storylines but includes a truly interactive TV experience was one of our goals.