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M. Ganschow C. Hellriegel E. Kneuper M. Wark C. Thiel G. Schulz‐Ekloff C. Bruchle D. Whrle 《Advanced functional materials》2004,14(3):269-276
Dye‐loaded AlPO4‐5 single crystals were prepared by microwave‐assisted hydrothermal synthesis from a batch, containing a mixture of three chromophores (Coumarin 40, Rhodamine BE50, and Oxazine 1) differing in their absorption range, molecular dimensions, and solubilities. Confocal fluorescence images reveal a spatial separation effect of the dye molecules, where the slimmer, more‐soluble dye molecule (Coumarin 40) is uniformly distributed in the body of the single crystal, and the bulky and/or less‐soluble ones (Rhodamine BE50, Oxazine 1) are situated in distinct domains. Visible spectra show good panchromatic absorption of visible light. Fluorescence lifetime measurements indicate the presence of an energy transfer cascade of the entirely fixed dye molecules from Coumarin 40 to Oxazine 1. The transfer mechanism is predominantly radiative. 相似文献
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Christina Dirk‐Faitakis D Grant Allen 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(7):737-745
This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically‐operated biofilters and compares it with experimental results obtained from three, parallel, bench‐scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an α‐pinene‐laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non‐loading: the longer the period of non‐loading, the poorer the biofilter's performance at the re‐commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of α‐pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically‐operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, Cg, max/Cg, relative value of the half‐saturation constant in the Monod expression, Ks, and effective diffusivity of α‐pinene in the biofilm, De. Copyright © 2005 Society of Chemical Industry 相似文献
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J. C. Schulz 《International journal for numerical methods in engineering》1985,21(6):1039-1048
A new hourglassing control technique for quadrilateral and hexahedral elements used in dynamic finite element codes is presented. Based on expansion of the strees in a Taylor series and retention of additional terms beyond the usual constant stress term, this technique has the advantage that actual rather than artificial material properties are used. Simplifications that render this technique competitive with artificial viscosity and stiffness procedures in terms of additional storage and computation requirements are described. 相似文献
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Sven Beyer Christian Jacobi Daniel Kröning Dirk Leinenbach Wolfgang J. Paul 《International Journal on Software Tools for Technology Transfer (STTT)》2006,8(4-5):411-430
In the verified architecture microprocessor (VAMP) project we have designed, functionally verified, and synthesized a processor
with full DLX instruction set, delayed branch, Tomasulo scheduler, maskable nested precise interrupts, pipelined fully IEEE
compatible dual precision floating point unit with variable latency, and separate instruction and data caches. The verification
has been carried out in the theorem proving system PVS. The processor has been implemented on a Xilinx FPGA.
A shorter version of this article with the title “Instantiating uninterpreted functional units and memory system: functional
verification of the VAMP” appeared in [8]. The work reported here was done while all the authors were with Saarland University. 相似文献
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RM Bionta G Blewitt CB Bratton D Casper A Ciocio R Claus M Crouch ST Dye S Errede GW Foster W Gajewski KS Ganezer M Goldhaber TJ Haines TW Jones D Kielczewska WR Kropp JG Learned JM LoSecco J Matthews HS Park LR Price F Reines J Schulz S Seidel E Shumard D Sinclair HW Sobel JL Stone L Sulak R Svoboda G Thornton van der Velde JC C Wuest 《Canadian Metallurgical Quarterly》1987,36(1):30-36