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排序方式: 共有566条查询结果,搜索用时 468 毫秒
1.
G. Murali Dhar B. N. Srinivas M. S. Rana Manoj Kumar S. K. Maity 《Catalysis Today》2003,86(1-4):45-60
Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al2O3 containing mixed oxide supports, TiO2 containing mixed oxide supports, ZrO2 containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO2 containing mixed oxides received maximum attention, especially TiO2–Al2O3 supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication. 相似文献
2.
Structural and electrical properties of brush plated ZnTe films 总被引:1,自引:0,他引:1
Zinc telluride thin films were deposited by the brush plating technique at a potential of −0.90 V (SCE) on conducting glass and titanium substrates at different temperatures in the range 30–90 °C. The films were polycrystalline in nature with peaks corresponding to the cubic phase. Direct band gap of 2.30 eV was observed. XPS studiers indicated the formation of ZnTe. Depth profiling studies indicated a uniform distribution of Zn and Te throughout the entire thickness. EDAX measurements were made on the films and it was found that there was a slight excess of Te. The carrier concentration was found to vary from 1014–1015 cm−3 with increase of substrate temperature. The mobility was found to vary from 5 to 60 cm2 V−1 s−1. 相似文献
3.
Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios
G. Muthu Kumaran Shelu Garg Kapil Soni Manoj Kumar J.K. Gupta L.D. Sharma K.S. Rama Rao G. Murali Dhar 《Microporous and mesoporous materials》2008,114(1-3):103-109
Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, 27Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH3. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH3 adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities. 相似文献
4.
Chandrasekharam N. Nagineni Sarwat Naz Rajani Choudhuri Gadisetti V. R. Chandramouli Murali C. Krishna Jeffrey R. Brender John A. Cook James B. Mitchell 《International journal of molecular sciences》2021,22(9)
Understanding the global metabolic changes during the senescence of tumor cells can have implications for developing effective anti-cancer treatment strategies. Ionizing radiation (IR) was used to induce senescence in a human colon cancer cell line HCT-116 to examine secretome and metabolome profiles. Control proliferating and senescent cancer cells (SCC) exhibited distinct morphological differences and expression of senescent markers. Enhanced secretion of pro-inflammatory chemokines and IL-1, anti-inflammatory IL-27, and TGF-β1 was observed in SCC. Significantly reduced levels of VEGF-A indicated anti-angiogenic activities of SCC. Elevated levels of tissue inhibitors of matrix metalloproteinases from SCC support the maintenance of the extracellular matrix. Adenylate and guanylate energy charge levels and redox components NAD and NADP and glutathione were maintained at near optimal levels indicating the viability of SCC. Significant accumulation of pyruvate, lactate, and suppression of the TCA cycle in SCC indicated aerobic glycolysis as the predominant energy source for SCC. Levels of several key amino acids decreased significantly, suggesting augmented utilization for protein synthesis and for use as intermediates for energy metabolism in SCC. These observations may provide a better understanding of cellular senescence basic mechanisms in tumor tissues and provide opportunities to improve cancer treatment. 相似文献
5.
Effect of sintering on physico-chemical and catalytic properties of Mo, Co-Mo, Ni-Mosupported on -Al2O3 is reported. Such effects on hydrodesulfurization (HDS), hydrogenation (HYD) and hydrodeoxygenation (HDO) are investigated as a function of sintering temperature. The results indicated that HDS and HYD have different optimum calcination temperatures and these functionalities originate from different sites. The results are discussed in the light of molybdenum sulfide dispersion, promotional effects and phase transformations of active component, promoters and support. 相似文献
6.
A differentiation between free carboxyl and various lactone groups in different types of oxycelluloses was carried out based on the variation in their reaction rate with KI/KIO3 solution. For oxycelluloses prepared under acidic conditions, a large proportion of carboxyl groups are present in free form. Each oxycellulose was also studied after cation freeing as well as after blocking the free carboxyl groups by treatment with sodium chloride. Cation freeing was found to cause considerable lactonization of carboxyl groups; sodium chloride treatment blocked them only partially. 相似文献
7.
A series of novel copolymer superabsorbents based on monomer acrylamide (AM), potassium methacrylate (KMA), and 2‐hydroxyethyl methacrylate (HEMA) were prepared by copolymerization using ammonium persulfate (APS) as an initiator and N,N‐methylenebisacrylamide (MBA) as a crosslinking agent. The synthetic variables (the monomer concentration, crosslinker concentration, and initiator concentration) were also studied. The experimental results of superabsorbent polymers (SAPs) show a better absorbency in both water and NaCl solutions. The copolymers were characterized by IR spectroscopy. The water retention in the soil was enhanced using the above superabsorbents. The use of SAPs for the growth of groundnut plants was also investigated. SAPs can be considered for water‐managing materials for agriculture and horticulture purposes in desert and drought‐prone areas. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1795–1801, 2002 相似文献
8.
Creaser E.H.; Murali C.; Britt K.A. 《Protein engineering, design & selection : PEDS》1990,3(6):523-526
By protein engineering we have investigated changes to two aminoacid residues (Trp93 and Ser48) in the substrate pocket of yeastalcohol dehydrogenase 1. Upon changing Thr48 to serine we producedan enzyme which has markedly greater activity towards aliphaticalcohols with chain length up to 8, together with a generalincrease in catalytic activity (V/K). Changes at position 93were less pronounced, with the Phe enzyme being more activethan the parent towards the range of alcohols but with the alanineenzyme showing very little difference from the wild-type. Enzymeswith the double changes at 48 and 93 showed increased activitytowards alcohols with 38 carbons but the increases werenot additive over the single changes. The enzymes with changesat the two positions would metabolize both stereoisomers of2-octanol whereas the parent ADH would attack only one of them.None of the engineered enzymes would attack cyclohexanol oraromatic alcohols. The results are in general agreement withthe prediction that reducing the size of amino acids in thesubstrate pocket would enhance the ability to oxidize alcoholslarger than ethanol. 相似文献
9.
We consider a structural approach to the consensus building problem in multi‐group multi‐layer (MGML) distributed sensor networks (DSNs) common in many natural and engineering applications. From among the possible network structures, we focus on bipartite graph structure as it represents a typical MGML structure and has a wide applicability in the real world. We establish exact conditions for consensus and derive a precise relationship between the consensus value and the degree distribution of nodes in a bipartite MGML DSN. We also demonstrate that for subclasses of connectivity patterns, convergence time and simple characteristics of network topology can be captured by explicit algebra. Direct inference of the convergence behavior of consensus strategies from MGML DSN structure is the main contribution of this paper. The insights gained from our analysis facilitate the design and development of large‐scale DSNs that meet specific performance criteria. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
10.
Aishani Mazumder Chung Kim Nguyen Thiha Aung Mei Xian Low Md. Ataur Rahman Salvy P. Russo Sherif Abdulkader Tawfik Shifan Wang James Bullock Vaishnavi Krishnamurthi Nitu Syed Abhishek Ranjan Ali Zavabeti Irfan H. Abidi Xiangyang Guo Yongxiang Li Taimur Ahmed Torben Daeneke Akram Al-Hourani Sivacarendran Balendhran Sumeet Walia 《Advanced functional materials》2023,33(36):2303641
Miniaturization and energy consumption by computational systems remain major challenges to address. Optoelectronics based synaptic and light sensing provide an exciting platform for neuromorphic processing and vision applications offering several advantages. It is highly desirable to achieve single-element image sensors that allow reception of information and execution of in-memory computing processes while maintaining memory for much longer durations without the need for frequent electrical or optical rehearsals. In this work, ultra-thin (<3 nm) doped indium oxide (In2O3) layers are engineered to demonstrate a monolithic two-terminal ultraviolet (UV) sensing and processing system with long optical state retention operating at 50 mV. This endows features of several conductance states within the persistent photocurrent window that are harnessed to show learning capabilities and significantly reduce the number of rehearsals. The atomically thin sheets are implemented as a focal plane array (FPA) for UV spectrum based proof-of-concept vision system capable of pattern recognition and memorization required for imaging and detection applications. This integrated light sensing and memory system is deployed to illustrate capabilities for real-time, in-sensor memorization, and recognition tasks. This study provides an important template to engineer miniaturized and low operating voltage neuromorphic platforms across the light spectrum based on application demand. 相似文献