Authenticity green coffee bean species and geographical origin using near-infrared spectroscopy combined with chemometrics

To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.     

Effect of Supports and Promoters on the Performance of Ni-Based Catalysts in Ethanol Steam Reforming

Ethanol steam reforming (ESR) is one of the potential processes to convert ethanol into valuable products. Hydrogen produced from ESR is considered as green energy for the future and can be an excellent alternative to fossil fuels with the aim of mitigating the greenhouse gas effect. The ESR process has been well studied, using transition metals as catalysts coupled with both acidic and basic oxides as supports. Among various reported transition metals, Ni is an inexpensive material with activity comparable to that of noble metals, showing promising ethanol conversion and hydrogen yields. Additionally, different promoters and supports were utilized to enhance the hydrogen yield and the catalyst stability. This review summarizes and discusses the influences of the supports and promoters of Ni-based catalysts on the ESR process.     

Aspects of oligonucleotide and peptide sequencing with MALDI and electrospray mass spectrometry

Biopolymer sequencing with mass spectrometry has become increasingly important and accessible with the development of matrix-assisted laser desorption/ionization (MALDI) and electrospray ionization (ESI). Here we examine the use of sequential digestion for the rapid identification of proteolytic fragments, in turn highlighting the general utility of enzymatic MALDI ladder sequencing and ESI tandem mass spectrometry. Analyses were performed on oligonucleotides ranging in size from 2 to 50 residues, on peptides ranging in size from 7 to 44 residues and on viral coat proteins. MALDI ladder sequencing using exonuclease digestion generated a uniform distribution of ions and provided complete sequence information on the oligonucleotides 2-30 nucleic acid residues long. Only partial sequence information was obtained on the longer oligonucleotides. C-terminal peptide ladder sequencing typically provided information from 4 to 7 amino acids into the peptide. Sequential digestion, or endoprotease followed by exoprotease exposure, was also successfully applied to a trypsin digest of viral proteins. Analysis of ladder sequenced peptides by LCMS generated less information than in the MALDI-MS analysis and ESI-MS2 normally provided partial sequence information on both the small oligonucleotides and peptides. In general, MALDI ladder sequencing offered information on a broader mass range of biopolymers than ESI-MS2 and was relatively straightforward to interpret, especially for oligonucleotides.     

A Stream X-Machine Tool for Modelling and Generating Test Cases for Chronic Diseases Based on State-Counting Approach

Programming and Computer Software - In the biomedical domain, diagrammatical models have been extensively used to describe and understand the behaviour of biological organisms (biological agents)...     

Mood sensing from social media texts and its applications

We present a large-scale mood analysis in social media texts. We organise the paper in three parts: (1) addressing the problem of feature selection and classification of mood in blogosphere, (2) we extract global mood patterns at different level of aggregation from a large-scale data set of approximately 18 millions documents (3) and finally, we extract mood trajectory for an egocentric user and study how it can be used to detect subtle emotion signals in a user-centric manner, supporting discovery of hyper-groups of communities based on sentiment information. For mood classification, two feature sets proposed in psychology are used, showing that these features are efficient, do not require a training phase and yield classification results comparable to state of the art, supervised feature selection schemes; on mood patterns, empirical results for mood organisation in the blogosphere are provided, analogous to the structure of human emotion proposed independently in the psychology literature; and on community structure discovery, sentiment-based approach can yield useful insights into community formation.     

Social reader: towards browsing the social web

We describe Social Reader, a feed-reader-plus-social-network aggregator that mines comments from social media in order to display a user’s relational neighborhood as a navigable social network. Social Reader’s network visualization enhances mutual awareness of blogger communities, facilitates their exploration and growth with a fully dragn- drop interface, and provides novel ways to filter and summarize people, groups, blogs and comments. We discuss the architecture behind the reader, highlight tasks it adds to the workflow of a typical reader, and assess their cost. We also explore the potential of mood-based features in social media applications. Mood is particularly relevant to social media, reflecting the personal nature of the medium. We explore two prototype mood-based features: colour coding the mood of recent posts according to a valence/arousal map, and a mood-based abstract of recent activity using image media. A six week study of the software involving 20 users confirmed the usefulness of the novel visual display, via a quantitative analysis of use logs, and an exit survey.     

Unsupervised context detection using wireless signals

The sensing context plays an important role in many pervasive and mobile computing applications. Continuing from previous work [D. Phung, B. Adams, S. Venkatesh, Computable social patterns from sparse sensor data, in: Proceedings of First International Workshop on Location Web, World Wide Web Conference (WWW), New York, NY, USA, 2008, ACM 69–72.], we present an unsupervised framework for extracting user context in indoor environments with existing wireless infrastructures. Our novel approach casts context detection into an incremental, unsupervised clustering setting. Using WiFi observations consisting of access point identification and signal strengths freely available in office or public spaces, we adapt a density-based clustering technique to recover basic forms of user contexts that include user motion state and significant places the user visits from time to time. High-level user context, termed rhythms, comprising sequences of significant places are derived from the above low-level context by employing probabilistic clustering techniques, latent Dirichlet allocation and its n-gram temporal extension. These user contexts can enable a wide range of context-ware application services. Experimental results with real data in comparison with existing methods are presented to validate the proposed approach. Our motion classification algorithm operates in real-time, and achieves a 10% improvement over an existing method; significant locations are detected with over 90% accuracy and near perfect cluster purity. Richer indoor context and meaningful rhythms, such as typical daily routines or meeting patterns, are also inferred automatically from collected raw WiFi signals.     

Picture-Neutrosophic Trusted Safe Semi-Supervised Fuzzy Clustering for Noisy Data

Clustering is a crucial method for deciphering data structure and producing new information. Due to its significance in revealing fundamental connections between the human brain and events, it is essential to utilize clustering for cognitive research. Dealing with noisy data caused by inaccurate synthesis from several sources or misleading data production processes is one of the most intriguing clustering difficulties. Noisy data can lead to incorrect object recognition and inference. This research aims to innovate a novel clustering approach, named Picture-Neutrosophic Trusted Safe Semi-Supervised Fuzzy Clustering (PNTS3FCM), to solve the clustering problem with noisy data using neutral and refusal degrees in the definition of Picture Fuzzy Set (PFS) and Neutrosophic Set (NS). Our contribution is to propose a new optimization model with four essential components: clustering, outlier removal, safe semi-supervised fuzzy clustering and partitioning with labeled and unlabeled data. The effectiveness and flexibility of the proposed technique are estimated and compared with the state-of-art methods, standard Picture fuzzy clustering (FC-PFS) and Confidence-weighted safe semi-supervised clustering (CS3FCM) on benchmark UCI datasets. The experimental results show that our method is better at least 10/15 datasets than the compared methods in terms of clustering quality and computational time.     

Efficient duration and hierarchical modeling for human activity recognition

A challenge in building pervasive and smart spaces is to learn and recognize human activities of daily living (ADLs). In this paper, we address this problem and argue that in dealing with ADLs, it is beneficial to exploit both their typical duration patterns and inherent hierarchical structures. We exploit efficient duration modeling using the novel Coxian distribution to form the Coxian hidden semi-Markov model (CxHSMM) and apply it to the problem of learning and recognizing ADLs with complex temporal dependencies. The Coxian duration model has several advantages over existing duration parameterization using multinomial or exponential family distributions, including its denseness in the space of nonnegative distributions, low number of parameters, computational efficiency and the existence of closed-form estimation solutions. Further we combine both hierarchical and duration extensions of the hidden Markov model (HMM) to form the novel switching hidden semi-Markov model (SHSMM), and empirically compare its performance with existing models. The model can learn what an occupant normally does during the day from unsegmented training data and then perform online activity classification, segmentation and abnormality detection. Experimental results show that Coxian modeling outperforms a range of baseline models for the task of activity segmentation. We also achieve a recognition accuracy competitive to the current state-of-the-art multinomial duration model, while gaining a significant reduction in computation. Furthermore, cross-validation model selection on the number of phases K in the Coxian indicates that only a small K is required to achieve the optimal performance. Finally, our models are further tested in a more challenging setting in which the tracking is often lost and the activities considerably overlap. With a small amount of labels supplied during training in a partially supervised learning mode, our models are again able to deliver reliable performance, again with a small number of phases, making our proposed framework an attractive choice for activity modeling.