Sp3/sp2 character of the carbon and hydrogen configuration in micro- and nanocrystalline diamond

Hot filament and microwave plasma CVD micro- nanocrystalline diamond films are analysed by visible and ultra-violet excitation source Raman spectroscopy. The sample grain size varies from 20 nm to 2 μm. The hydrogen concentration in samples is measured by SIMS and compared to the grain size, and to the ratio of sp² carbon bonds determined by Raman spectroscopy from the 1332 cm^− 1 diamond peak and the sp² 1550 cm^− 1 G band. Hydrogen concentration appears to be proportional to the sp² bonds ratio. The 3000 cm^− 1 CH_x stretching mode band intensity observed on the Raman spectra is decreasing with the G band intensity. Thermal annealing modifies the sp² phase structure and concentration, as hydrogen outdiffuses.     

An Optimal Algorithm for Resource Allocation in D2D Communication

The number of mobile devices accessing wireless networks is skyrocketing due to the rapid advancement of sensors and wireless communication technology. In the upcoming years, it is anticipated that mobile data traffic would rise even more. The development of a new cellular network paradigm is being driven by the Internet of Things, smart homes, and more sophisticated applications with greater data rates and latency requirements. Resources are being used up quickly due to the steady growth of smartphone devices and multimedia apps. Computation offloading to either several distant clouds or close mobile devices has consistently improved the performance of mobile devices. The computation latency can also be decreased by offloading computing duties to edge servers with a specific level of computing power. Device-to-device (D2D) collaboration can assist in processing small-scale activities that are time-sensitive in order to further reduce task delays. The task offloading performance is drastically reduced due to the variation of different performance capabilities of edge nodes. Therefore, this paper addressed this problem and proposed a new method for D2D communication. In this method, the time delay is reduced by enabling the edge nodes to exchange data samples. Simulation results show that the proposed algorithm has better performance than traditional algorithm.     

Set-valued Lyapunov functions for difference inclusions

The paper relates set-valued Lyapunov functions to pointwise asymptotic stability in systems described by a difference inclusion. Pointwise asymptotic stability of a set is a property which requires that each point of the set be Lyapunov stable and that every solution to the inclusion, from a neighborhood of the set, be convergent and have the limit in the set. Weak set-valued Lyapunov functions are shown, via an argument resembling an invariance principle, to imply this property. Strict set-valued Lyapunov functions are shown, in the spirit of converse Lyapunov results, to always exist for closed sets that are pointwise asymptotically stable.     

Autonomic information flow improves prognostic impact of task force HRV monitoring

Heart rate variability (HRV) represents the cardiovascular control mediated by the autonomic nervous system and other mechanisms. In the established task force HRV monitoring different cardiovascular control mechanisms can approximately be identified at typical frequencies of heart rate oscillations by power spectral analysis. HRV measures assessing complex and fractal behavior partly improved clinical risk stratification. However, their relationship to (patho-)physiology is not sufficiently explored. Objective of the present work is the introduction of complexity measures of different physiologically relevant time scales. This is achieved by a new concept of the autonomic information flow (AIF) analysis which was designed according to task force HRV. First applications show that different time scales of AIF improve the risk stratification of patients with multiple organ dysfunction syndrome and cardiac arrest patients in comparison to standard HRV. Each group's significant time scales correspond to their respective pathomechanisms.     

Competition Between Endogenous and Exogenous Orienting of Visual Attention.

The relation between reflexive and voluntary orienting of visual attention was investigated with 4 experiments: a simple detection task, a localization task, a saccade toward the target task, and a target identification task in which discrimination difficulty was manipulated. Endogenous and exogenous orienting cues were presented in each trial and their validity was manipulated orthogonally to examine whether attention mechanisms are mediated by separate systems and whether they have additive and independent effects on visual detection and discrimination. The results showed that each orienting mechanism developed its typical and independent effect in every case except for the difficult identification task. A theoretical framework for understanding the relationship between endogenous and exogenous orienting of attention is proposed, tested, and confirmed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Regional training supply and employees’ training participation

Using data from the National Educational Panel Study of 2009/2010, this paper investigates the correlation between regional training supply and employees’ training participation. Controlling for other regional factors such as the local unemployment rate, the educational level, the population density and the regional industry composition, the results indicate that training participation is significantly higher in regions with many firms in the training supply market. The predictive power of the other regional factors is rather minor.     

Too Low to Kill: Concentration of the Secondary Metabolite Ranunculin in Buttercup Pollen does not Affect Bee Larval Survival

Growing evidence suggests that the freely accessible pollen of some plants is chemically protected against pollen-feeding flower visitors. For example, a diet of pollen from buttercup plants (Ranunculus) recently was shown to have a deleterious effect on developing larvae of several bee species not specialized on Ranunculus. Numerous Ranunculus species contain ranunculin, the glucosyl hydrate form of the highly reactive and toxic lactone protoanemonin, that causes the toxicity of these plants. We tested whether the presence of ranunculin is responsible for the lethal effects of R. acris pollen on the larvae of two bee species that are not Ranunculus specialists. To investigate the effect on bee larval development, we added ranunculin to the pollen provisions of the Campanula specialist bee Chelostoma rapunculi and the Asteraceae specialist bee Heriades truncorum, and allowed the larvae to feed on these provisions. We quantified ranunculin in pollen of R. acris and in brood cell provisions collected by the Ranunculus specialist bee Chelostoma florisomne. We demonstrated that although ranunculin was lethal to both tested bee species in high concentrations, the concentration in the pollen of R. acris was at least fourfold lower than that tolerated by the larvae of C. rapunculi and H. truncorum in the feeding experiments. Ranunculin concentration in the brood cells of C. florisomne was on average even twentyfold lower than that in Ranunculus pollen, suggesting that a mechanism different from ranunculin intoxication accounts for the larval mortality reported for bees not specialized on Ranunculus pollen.