Geological Engineering,Civil Engineering,Traffic and Transportation Engineering Electrical capacitance volume tomography for measurement soil water infiltration in vessel experiments简

Electrical capacitance volume tomography （ECVT） is a recently-developed technique for real-time, non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity. This work is first application of the method to visualization of water flow in soil. We describe the principles behind the method, and then demonstrate its use with a simple laboratory infiltration experiment. 32 ECVT sensors were installed on the sides of an empty PVC column. Water was poured into the column at a constant rate, and ECVT data were collected every second. The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second. Data were analyzed to give bulk average water contents, which proved consistent with the water supply rates. Data were also analyzed to give 3D images （216 voxels） allowing visualization of the water distribution during the experiments. Result of this work shows that water infiltration into the soil, wall flow, progress of the unstable wetting front and the final water distribution are clearly visible.     

Engineering behavior of the Lisan Marl as a dyke foundation material: Dead Sea,Jordan

Problems have occurred with dykes constructed on the Lisan Marl to retain brine pumped from the Dead Sea, which is chemically processed to produce potash. In this study the engineering behavior, collapse potential and compressibility of the Lisan Marl were assessed by undertaking laboratory tests with both natural, distilled water and brine as the media. The results showed that the liquid limit and fine particles increased when the soil was mixed with fresh/distilled water compared with brine water. The soil can be classified as highly compressible with a low undrained shear strength. In terms of collapsibility, the soil could be classified as slightly collapsible upon inundation with distilled water and moderately collapsible when soaked in Dead Sea brine. The results are important when determining the height and nature of the dykes.      

Physical,microstructure and leaching assessments for pavement road base containing mixed steel slag and cathode ray tube glass

Clean Technologies and Environmental Policy - Use of by-product materials, such as steel slag and cathode ray tube glass, as alternative recycled materials in the construction of roads, could...     

Engineering Catalytically Active Sites by Sculpting Artificial Edges on MoS2 Basal Plane for Dinitrogen Reduction at a Low Overpotential

Engineering catalytically active sites have been a challenge so far and often relies on optimization of synthesis routes, which can at most provide quantitative enhancement of active facets, however, cannot provide control over choosing orientation, geometry and spatial distribution of the active sites. Artificially sculpting catalytically active sites via laser-etching technique can provide a new prospect in this field and offer a new species of nanocatalyst for achieving superior selectivity and attaining maximum yield via absolute control over defining their location and geometry of every active site at a nanoscale precision. In this work, a controlled protocol of artificial surface engineering is shown by focused laser irradiation on pristine MoS₂ flakes, which are confirmed as catalytic sites by electrodeposition of AuNPs. The preferential Au deposited catalytic sites are found to be electrochemically active for nitrogen adsorption and its subsequent reduction due to the S-vacancies rather than Mo-vacancy, as advocated by DFT analysis. The catalytic performance of Au-NR/MoS₂ shows a high yield rate of ammonia (11.43 × 10⁻⁸ mol s⁻¹ cm⁻²) at a potential as low as −0.1 V versus RHE and a notable Faradaic efficiency of 13.79% during the electrochemical nitrogen reduction in 0.1 m HCl.     

Supervisory routing control for dynamic load balancing in low data rate wireless sensor networks

Routing protocols for Wireless Sensor Networks (WSN) are designed to select parent nodes so that data packets can reach their destination in a timely and efficient manner. Typically neighboring nodes with strongest connectivity are more selected as parents. This Greedy Routing approach can lead to unbalanced routing loads in the network. Consequently, the network experiences the early death of overloaded nodes causing permanent network partition. Herein, we propose a framework for load balancing of routing in WSN. In-network path tagging is used to monitor network traffic load of nodes. Based on this, nodes are identified as being relatively overloaded, balanced or underloaded. A mitigation algorithm finds suitable new parents for switching from overloaded nodes. The routing engine of the child of the overloaded node is then instructed to switch parent. A key future of the proposed framework is that it is primarily implemented at the Sink and so requires few changes to existing routing protocols. The framework was implemented in TinyOS on TelosB motes and its performance was assessed in a testbed network and in TOSSIM simulation. The algorithm increased the lifetime of the network by 41 % as recorded in the testbed experiment. The Packet Delivery Ratio was also improved from 85.97 to 99.47 %. Finally a comparative study was performed using the proposed framework with various existing routing protocols.     

The Oxidation of Hydrophobic Aromatic Substrates by Using a Variant of the P450 Monooxygenase CYP101B1

The cytochrome P450 monooxygenase CYP101B1, from a Novosphingobium bacterium is able to bind and oxidise aromatic substrates but at a lower activity and efficiency than norisoprenoids and monoterpenoid esters. Histidine 85 of CYP101B1 aligns with tyrosine 96 of CYP101A1, which, in the latter enzyme forms the only hydrophilic interaction with its substrate, camphor. The histidine residue of CYP101B1 was mutated to phenylalanine with the aim of improving the activity of the enzyme for hydrophobic substrates. The H85F mutant lowered the binding affinity and activity of the enzyme for β-ionone and altered the oxidation selectivity. This variant also showed enhanced affinity and activity towards alkylbenzenes, styrenes and methylnaphthalenes. For example the rate of product formation for acenaphthene oxidation was improved sixfold to 245 nmol per nmol CYP per min. Certain disubstituted naphthalenes and substrates, such as phenylcyclohexane and biphenyls, were oxidised with lower activity by the H85F variant. Variants at H85 (A and G) designed to introduce additional space into the active site so as to accommodate these larger substrates did not improve the oxidation activity. As the H85F mutant of CYP101B1 improved the oxidation of hydrophobic substrates, this residue is likely to be in the substrate binding pocket or the access channel of the enzyme. The side chain of the histidine might interact with the carbonyl groups of the favoured norisoprenoid substrates of CYP101B1.     

Beta glucan: a valuable functional ingredient in foods

β-Glucan is a valuable functional ingredient and various extraction techniques are available for its extraction. Choice of an appropriate extraction technique is important as it may affect the quality, structure, rheological properties, molecular weight, and other functional properties of the extracted β-glucan. These properties lead to the use of β-glucan into various food systems and have important implications in human health. This review focuses on the extraction, synthesis, structure, molecular weight, and rheology of β-glucan. Furthermore, health implications and utilization of β-glucan in food products is also discussed.     

Gel-like properties of MCM-41 material and its transformation to MCM-50 in a caustic alkaline surround

MCM-41 material, prepared by sol–gel method, reveals gel-like properties in a caustic alkaline environment, i.e., 6 M potassium hydroxide (KOH) electrolyte. The gellation of MCM-41 starts at a KOH weight ratio of 40 wt.%. The structural change of the material is verified with X-Ray diffractograms and supported by observation using Scanning Electron Microscope (SEM). As the KOH weight ratio increases, the MCM-41 hexagonal arrays structure gradually transforms into MCM-50 lamellar structure before disappearing completely at 80 wt.% KOH. The MCM gel phase is further characterized by rotational viscometry and texture analysis. The gel phase shows shear thinning or pseudoplastic behavior and possesses homogeneous matrix structure.     

A flow rule incorporating the fabric and non-coaxiality in granular materials

Deficiencies of constitutive models in prediction of dilatancy are often attributed to simplifications associated with flow rules such as assumptions of isotropy and coaxiality. It is thus proposed here to develop a comprehensive flow rule for granular materials by including the effect of fabric and without the assumption of coaxiality. A second-order tensor is introduced as a fabric for the distribution of contact normals and contact forces. By using the energy principle in micro-mechanical scale and a suitable dissipation mechanism in granular materials, a stress-dilatancy relation is obtained. Fabric plays a “bridge-like” role in the dilatancy and non-coaxiality. Non-coaxialities between stress-strain-fabric are attributed to the non-coaxiality between stress-fabric and strain-fabric. In this formulation the constants for modeling fabric depend on non-coaxiality of the system rather than the history that determines such a state. Ability of this stress-fabric-dilatancy for modeling the non-coaxiality shows that this relation can predict the behavior of granular materials in the presence of the rotation of principal stress axes.     

Stability assessment of earth slope using modified particle swarm optimization

This paper has proposed an effective method to determine the minimum factor of safety (FS) and associated critical failure surface in slope stability analysis. The search for the minimum FS based on limit equilibrium methods is a complex optimization problem as the objective function is non-smooth and non-convex. Recently, particle swarm optimization (PSO) as a meta-heuristic optimization algorithm has been developed with success in treating various types of problems. In the current study, a new approach of PSO is proposed to calculate the safety factor of earth slopes. The safety factors of the general slip surfaces are calculated using Spencer method of slices, and each new slip surface is randomly generated by straight line technique. The reliability and efficiency of the proposed algorithm are examined by considering a number of published cases. The results indicate that the new method can predict a more critical failure mechanism with a lower FS and can outperform the other methods in the literature as well as standard PSO. Finally, the proposed method will be validated by considering an existing slope failure in Ulu Klang, Malaysia.