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排序方式: 共有199条查询结果,搜索用时 18 毫秒
1.
Peter Horn Peter Schaaf Brigitte Holbach Stefan Hölzl Heinz Eschnauer 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1993,196(5):407-409
For provenance assignments of wines strontium isotope ratios can be used because soils from different wine-growing regions, and hence the wines grown there, each show specific ratios. Some successful applications are demonstrated.
87Sr/86Sr aus Gestein und Boden in Rebe und Wein
Zusammenfassung Zur Herkunftsbestimmung von Weinen können Strontium-Isotopenverhältnisse herangezogen werden, da die Böden verschiedener Weinbaugebiete, und damit die dort gezogenen Weine, jeweils spezifische Verhältnisse aufweisen. Einige erfolgreiche Anwendungen werden demonstriert.相似文献
2.
In addition to the C21 steroid 15α-hydroxypregna-4,6-dien-3,20-dione, four 1- or 2-acylated polyunsaturated monoglycerides, 1- or 2-(cis-5,8,11,14-eicosatetraenoyl)-glycerol and 1- or 2-(cis-5,8,11,14,17-eicosapentaenoyl)glycerol were identified as constituents of the prothoracic defensive gland secretion of the
dytiscid beetle Agabus affinis by gas chromatography-mass spectrometry of trimethylsilylated gland extracts. In a feeding assay with minnows, synthetic
samples of the two 2-acylated monoglycerides showed only a weak activity as a feeding deterrent. For that reason, other possible
functions of the monoglycerides are discussed, such as roles as emulsifiers of cannabimimetics. 相似文献
3.
Stéphane J. C. Weusten Luc C. E. M. Murrer Matheus T. de Groot John van der Schaaf 《American Institute of Chemical Engineers》2021,67(6):e17263
This article investigates the effect of inlet shape, entrance length, and turbulence promoters on mass transfer by using 3D-printed electrolyzers. Our results show that the inlet design can promote turbulence and lead to an earlier transition to turbulent flow. The Reynolds number at which the transition occurs can be predicted by the ratio of the cross-sectional area of the inlet to the cross-sectional area of the electrolyzer channel. A longer entrance length results in more laminar behavior and a later transition to turbulent flow. With an entrance length of 550 mm, the inlet design did no longer affect the mass transfer performance significantly. The addition of gyroid type turbulence promoters resulted in a factor of 2 to 4 increase in mass transfer depending on inlet design, entrance length, and the type of promoter. From one configuration to another, there was a minimal variation in pressure drop (<1600 Pa). 相似文献
4.
Approaching Gas Phase Electrodeposition: Process and Optimization to Enable the Self‐Aligned Growth of 3D Nanobridge‐Based Interconnects 下载免费PDF全文
5.
The Teniente Converter (TC) is an important technology for smelting and converting copper concentrates. Due to the complexities of its autogenous operation, which combines continuous input flows with intermittent product extraction, efforts to model and control this dynamic have only been partially successful. This work presents a model of TC operation that combines phenomenological equations with empirical expressions and includes both continuous and discrete variables. Six different operating modes are described. To improve predictive capabilities, an adaptive compensation technique takes account of changes in concentrate mix characteristics. The model predicts five important variables: white metal copper concentration, slag magnetite concentration, white metal temperature, and white metal and slag levels. It is calibrated and validated with real operating data from Codelco’s Potrerillos smelter. Once the model is implemented, it delivers online estimates of process variables that are measured intermittently.Based on the model, a hybrid predictive controller is developed to control the quantities and characteristics of the TC products as a function of the number of dependent units such as Peirce-Smith converters and slag-cleaning furnaces. The controller’s performance is evaluated via simulation under a variety of operating conditions. It is currently employed in an open-loop configuration to provide suggestions on set points for the local flow controllers and on the product extraction sequences. 相似文献
6.
S. R. A. de Loos J. van der Schaaf R. M. Tiggelaar T. A. Nijhuis M. H. J. M. de Croon J. C. Schouten 《Microfluidics and nanofluidics》2010,9(1):131-144
Most heterogeneously catalyzed gas–liquid reactions in micro channels are chemically/kinetically limited because of the high
gas–liquid and liquid–solid mass transfer rates that can be achieved. This motivates the design of systems with a larger surface
area, which can be expected to offer higher reaction rates per unit volume of reactor. This increase in surface area can be
realized by using structured micro channels. In this work, rectangular micro channels containing round pillars of 3 μm in
diameter and 50 μm in height are studied. The flow regimes, gas hold-up, and pressure drop are determined for pillar pitches
of 7, 12, 17, and 27 μm. Flow maps are presented and compared with flow maps of rectangular and round micro channels without
pillars. The Armand correlation predicts the gas hold-up in the pillared micro channel within 3% error. Three models are derived
which give the single-phase and the two-phase pressure drop as a function of the gas and liquid superficial velocities and
the pillar pitches. For a pillar pitch of 27 μm, the Darcy-Brinkman equation predicts the single-phase pressure drop within
2% error. For pillar pitches of 7, 12, and 17 μm, the Blake-Kozeny equation predicts the single-phase pressure drop within
20%. The two-phase pressure drop model predicts the experimental data within 30% error for channels containing pillars with
a pitch of 17 μm, whereas the Lockhart–Martinelli correlation is proven to be non-applicable for the system used in this work.
The open structure and the higher production rate per unit of reactor volume make the pillared micro channel an efficient
system for performing heterogeneously catalyzed gas–liquid reactions. 相似文献
7.
Larry Schaaf 《History of Photography》2013,37(3):181-204
Abstract The rich, productive, and enthusiastic interaction between Henry Talbot and John Herschel is a fascinating microcosm of early photographic research. An isolated experiment, shared by them in 1831, is a typical example of the tantalizing near-misses that pervade the chronicles of the pre-history of photography. Their correspondence in early 1839, before Herschel saw Daguerre's then superior productions, is a window for us today to learn from the initial thoughts of the excited pioneers. We face contemporary reports of discovery and hope, unedited and unrefined by the influence of time and later events. 相似文献
8.
Christian Worsch Peter Schaaf Ruzha Harizanova Christian Rüssel 《Journal of Materials Science》2012,47(15):5886-5890
Magnetic multicore nanoparticles were produced by crystallisation of a glass with the composition Na2O·Al2O3·B2O3·SiO2·Fe2O3. During cooling of the melt, in a first step, phase separation occurred and droplets enriched in boron and iron oxide were formed. These droplets crystallised spontaneously during cooling. The phase-separated droplets had sizes in the range from 200 to 800 nm. Inside the droplets, magnetite crystals with a mean size of 33 nm occurred. Magnetometer measurements showed the occurrence of a small hysteresis which indicates predominantly superparamagnetic behaviour of the magnetite crystals. The magnetic domains of the phase-separated droplets were studied by magnetic force microscopy. In this article, a glass which is exposed to a magnetic field shows droplet-shape phase separations where the single-domain magnetite crystals do not have a preferred orientation of the magnetic dipoles. By contrast, the whole droplet shows one magnetic dipole parallel to the external field if the glass is exposed to a magnetic field during measurement. 相似文献
9.
Kevin M. P. van Eeten Dennis H. J. Hülsman John van der Schaaf Jaap C. Schouten 《American Institute of Chemical Engineers》2015,61(11):3656-3665
A novel type of rotor‐stator spinning disk device is proposed which allows for the entrapment of solid particles solely by hydrodynamic means. In this new configuration, the solid rotating disk is replaced with two conjoined rotors with a variable gap spacing. Liquid is fed through the top stator and can flow out again through the rotor‐rotor interior and the hollow rotation axis. Moreover, the volume between the two rotors is optionally filled with a highly porous reticulated carbon foam. It was found that particle containment was strongly improved by the presence of this reticulated foam as it hinders the buildup of centripetal boundary layer flow near the disks in the interior of the rotor‐rotor assembly. These centripetal boundary layers drag along particles resulting in a loss of containment. Experiments utilizing glass beads showed that particles with a diameter down to 17.8 µm can be completely entrapped when a carbon foam is placed between the two conjoined disks at rotor speeds up to the maximum investigated value of 178 rad s?1. Additionally, the rotor‐rotor gap did not have an effect on the particle entrapment level when the reticulated carbon foam was omitted and can be ascribed to the build‐up of boundary layers, which is independent of rotor‐rotor distance. © 2015 American Institute of Chemical Engineers AIChE J, 61: 3656–3665, 2015 相似文献
10.
Michiel M. de Beer Jos T. F. Keurentjes Jaap C. Schouten John van der Schaaf 《American Institute of Chemical Engineers》2016,62(10):3784-3796
Centrifugal intensification of condensation heat transfer in the rotor–stator cavities of a stator–rotor–stator spinning disc reactor (srs‐SDR) is studied, as a function of rotational velocity ω, volumetric throughflow rate , and average temperature driving force . For the current range of ω, heat transfer from the vapor bubbles to the condensate liquid is limiting, due to a relatively low gas–liquid interfacial area aGL. For rad s?1, a strong increase of aGL, results in increasing the reactor‐average condensation heat transfer coefficient hc from 1600 to 5600 W m?2 K?1, for condensation of pure dichloromethane vapor. Condensation heat transfer in the srs‐SDR is enhanced by rotation, independent of the vapor velocity. The intensified condensation comes at the cost of relatively high energy dissipation rates, indicating condensation in the srs‐SDR is more suited as a means to supply heat (e.g. in an intensified reactor‐heat exchanger), rather than for bulk cooling purposes. © 2016 American Institute of Chemical Engineers AIChE J, 62: 3784–3796, 2016 相似文献