Acoustic study of nano-crystal embedded PbO-P2O5 glass

Nano-crystal embedded PbO-P₂O₅ glass has been prepared and characterized by XRD and TEM measurements. The ultrasonic velocity and attenuation measured within the temperature range 80–300 K show significant structure and interesting feature with the presence of nano-crystalline region. The glass samples were prepared by melt-quench method and nano-crystals of different sizes were produced by heat treatment of the glasses for different durations of heating. All the processes were carried out at or above glass transition temperature. A theoretical model that takes account of the effects of thermally activated relaxation, anharmonicity as well as microscopic elastic inhomogeneities arising out of fluctuations has been successfully applied to interpret the variation of ultrasonic velocity and attenuation data. An interesting outcome of this application has been to propose a method for the determination of the size of nano-crystals from the ultrasonic attenuation data.     

The role of pressure on thin amorphous carbon films deposited using microwave surface wave plasma CVD

We report the effects of gas composition pressure (GCP) on the optical, structural and electrical properties of thin amorphous carbon (a-C) films grown on p-type silicon and quartz substrates by microwave surface wave plasma chemical vapor deposition (MW SWP CVD). The films, deposited at various GCPs ranging from 50 to 110 Pa, were studied by UV/VIS/NIR spectroscopy, atomic force microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and current–voltage characteristics. The optical band gap of the a-C film was tailored to a relatively high range, 2.3–2.6 eV by manipulating GCPs from 50 to 110 Pa. Also, spin density strongly depended on the band gap of the a-C films. Raman spectra showed qualitative structured changes due to sp³/sp² carbon bonding network. The surfaces of the films are found to be very smooth and uniform (RMS roughness < 0.5 nm). The photovoltaic measurements under light illumination (AM 1.5, 100 mW/cm²) show that short-circuit current density, open-circuit voltage, fill factor and photo-conversion efficiency of the film deposited at 50 Pa were 6.4 μA/cm², 126 mV, 0.164 and 1.4 × 10^− 4% respectively.     

Synthesis of nitrogen incorporated diamond-like carbon thin films using microwave surface-wave plasma CVD

Nitrogenated diamond-like (DLC:N) carbon thin films have been deposited by microwave surface wave plasma chemical vapor deposition on silicon and quartz substrates, using argon gas, camphor dissolved in ethyl alcohol composition and nitrogen as plasma source. The deposited DLC:N films were characterized for their chemical, optical, structural and electrical properties through X-ray photoelectron spectroscopy, UV/VIS/NIR spectroscopy, Raman spectroscopy, atomic force microscope and current–voltage characteristics. Optical band gap decreased (2.7 to 2.4 eV) with increasing Ar gas flow rate. The photovoltaic measurements of DLC:N / p-Si structure show that the open-circuit voltage (V_oc) of 168.8 mV and a short-circuit current density (J_sc) of 8.4 μA/cm² under light illumination (AM 1.5 100 mW/cm²). The energy conversion efficiency and fill factor were found to be 3.4 × 10^{− 4}% and 0.238 respectively.     

Influence of untreated and novel electron‐beam‐modified surface‐coated silica filler on the thermorheological properties of ethylene–octene copolymer

We developed surface‐modified silica fillers by coating these with an acrylate monomer, trimethylolpropane triacrylate, or a silane coupling agent, triethoxyvinyl silane, followed by electron‐beam irradiation at room temperature. These were incorporated in an ethylene–octene copolymer rubber. Thermorheological studies of the unvulcanized ethylene–octene copolymer and its untreated and modified silica‐filled composites were done with a shear dynamic oscillating rheometer. Modification of the silica filler, especially via the silanization process followed by electron beam treatment, significantly reduced filler–filler networking as revealed from the log–log plots of storage modulus and complex shear viscosity, and its real component. The rheological complexity of the compositions was analyzed from a double logarithmic plot of the storage modulus and loss modulus. The results obtained from the master curves constructed on the basis of the time–temperature superposition principle and the activation energy calculated from the Arrhenius equation for the flow of above these compounds further supported these findings. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2453–2459, 2003     

Using honeynodes for defense against jamming attacks in wireless infrastructure-based networks

The advent of wireless networks has brought a new set of security issues with it. One of the most feared of these is the jamming-based attacks. In this paper, we propose a pre-emptive detection strategy using honeynodes and a response mechanism based on the existing Channel Surfing Algorithm [Xu W, Trappe W, Zhang Y, Wood T. Channel surfing and spatial retreats: defenses against wireless denial of service. ACM Wireless Security 2004;80-9] to protect wireless nodes from a jammer. Honeynodes generate dummy communication at a frequency close to the actual frequency of operation, and pre-emptively alert authentic nodes of imminent attacks, so that the authentic nodes can jump to another frequency even before a jammer starts scanning that frequency. The next frequency is selected using a novel approach which uses a hybrid of reactive and proactive channel selection procedures. We have simulated the proposed approach using NS-2. The experimental results further prove a marked improvement in the performance of the proposed system over the Channel Surfing Algorithm in terms of the packet delivery ratio, the jammed duration, control message overhead and the number of channel re-configurations.     

An ant swarm-inspired energy-aware routing protocol for wireless ad-hoc networks

Primitive routing protocols for ad-hoc networks are “power hungry” and can therefore consume considerable amount of the limited amount of battery power resident in the nodes. Thus, routing in ad-hoc networks is very much energy-constrained. Continuous drainage of energy degrades battery performance as well. If a battery is allowed to intermittently remain in an idle state, it recovers some of its lost charge due to the charge recovery effect, which, in turn, results in prolonged battery life.In this paper, we use the ideas of naturally occurring ants’ foraging behavior (Dorigo and Stuetzle, 2004) [1] and based on those ideas, we design an energy-aware routing protocol, which not only incorporates the effect of power consumption in routing a packet, but also exploits the multi-path transmission properties of ant swarms and, hence, increases the battery life of a node. The efficiency of the protocol with respect to some of the existing ones has been established through simulations. It has been observed that the energy consumed in the network, the energy per packet in the case of EAAR are 60% less compared to MMBCR and the packets lost is only around 12% of what we have in AODV, in mobility scenarios.     

Connectivity preserving localized coverage algorithm for area monitoring using wireless sensor networks

Efficient network coverage and connectivity are the requisites for most Wireless Sensor Network (WSN) deployments, particularly those concerned with area monitoring. Due to the resource constraints of the sensor nodes, redundancy of coverage area must be reduced for effective utilization of the available resources. If two nodes have the same coverage area in their active state, and if both the nodes are activated simultaneously, it leads to redundancy in network and wastage of precious sensor resources. In this paper, we address the problem of network coverage and connectivity and propose an efficient solution to maintain coverage, while preserving the connectivity of the network. The proposed solution aims to cover the area of interest (AOI), while minimizing the count of the active sensor nodes. The overlap region of two sensor nodes varies with the distance between the nodes. If the distance between two sensor nodes is maximized, the overall coverage area of these nodes will also be maximized. Also, to preserve the connectivity of the network, each sensor node must be in the communication range of at least one other node. Results of simulation of the proposed solution indicate up to 95% coverage of the area, while consuming very less energy of 9.44 J per unit time in the network, simulated in an area of 2500 m².     

A learning automata-based fault-tolerant routing algorithm for mobile ad hoc networks

Reliable routing of packets in a Mobile Ad Hoc Network (MANET) has always been a major concern. The open medium and the susceptibility of the nodes of being fault-prone make the design of protocols for these networks a challenging task. The faults in these networks, which occur either due to the failure of nodes or due to reorganization, can eventuate to packet loss. Such losses degrade the performance of the routing protocols running on them. In this paper, we propose a routing algorithm, named as learning automata based fault-tolerant routing algorithm (LAFTRA), which is capable of routing in the presence of faulty nodes in MANETs using multipath routing. We have used the theory of Learning Automata (LA) for optimizing the selection of paths, reducing the overhead in the network, and for learning about the faulty nodes present in the network. The proposed algorithm can be juxtaposed to any existing routing protocol in a MANET. The results of simulation of our protocol using network simulator 2 (ns-2) shows the increase in packet delivery ratio and decrease in overhead compared to the existing protocols. The proposed protocol gains an edge over FTAR, E2FT by nearly 2% and by more than 10% when compared with AODV in terms of packet delivery ratio with nearly 30% faulty nodes in the network. The overhead generated by our protocol is lesser by 1% as compared to FTAR and by nearly 17% as compared to E2FT when there are nearly 30% faulty nodes.     

Evaluation of fire performance of organic fire retardant free acrylic based coatings applied on various building materials by cone calorimetric method

Fire performance of water‐based plaster systems containing acrylic copolymer binder and non‐flammable mineral and ceramic fillers intended for decorative coating application was determined by cone calorimetric method. The coatings were applied on common building substrate materials used in construction sector, namely, Medium Density Fibre (MDF) boards, Gypsum Boards (GIB) and Stainless Steel (SS), and the different plaster finishes attempted on these substrates were Tierrafino, Suave and Bone China respectively. Group numbers of the different test samples were also evaluated following the Kokkala method. Based on various measurements, especially heat release, smoke evolution, mass loss data and the Group number estimates, it is evident that these organic fire retardant free coatings can offer good fire safety if applied on appropriate substrates like GIB or SS. Copyright © 2016 John Wiley & Sons, Ltd.