Magnetic porous nano-carbon catalysts supported silver nanoparticles derived from chitin and their application in catalytic reduction reactions

The exploitation of recycled carbonaceous catalysts from renewable biomass resources such as chitin is a crucial issue for the development of the sustainable society. In this article, the chitin-based N and O doped carbon microspheres (ChC) were fabricated by a simple dissolution, sol–gel transformation, and the carbonization methods. Subsequently, the novel magnetic Ag-Fe₃O₄@chitin-based carbon microspheres catalyst (MChC) was successfully constructed through the in situ redox reaction. The as-prepared MChC possessed rich micropores with high-surface area, and a narrow size distribution (50–120 μm). The Ag-Fe₃O₄ nanoparticles were immobilized through the interaction with C, N, and O atoms in the pores of MChC. The reduction of 4-nitrophenol was applied to evaluate the catalytic activity of MChC. 4-Nitrophenol (4-NP) could be fully reduced to 4-aminophenol (4-AP) in 5 min with the catalyst MChC-45. Moreover, MChC could be collected in solution with an external magnet in 8 s and remained relatively high-catalytic activity after 10 cycle times. This work provided novel ideas for the fabrication of doped carbon material from biomass and promoted its utilization in nanocatalytic applications.     

Study on the Height of the Mining-Induced Water-Conducting Fracture Zone Under the Q 2l Loess Cover of the Jurassic Coal Seam in Northern Shaanxi,China

A method to calculate the height of a water-conducting fractured zone (HWCFZ) was developed based on the plate and shell theory, and the development of the HWCFZ in bedrock and Q2l loess strata is discussed in detail. First, the subsidence-deflection curve equation of the overlying stratum is theoretically derived, and then the ultimate deflection and free space height of rock strata are calculated. Moreover, the strata tensile strain is calculated by using integral calculus. In addition, the failure state of the rock is analyzed by comparing the theoretically calculated tensile strain with the experimentally measured yield tensile strain, allowing one to attain the maximum value of HWCFZ. This approach was tested at the Jinjitan coal mine; the theoretically predicted, experimentally measured, and numerically computed maximum HWCFZ values were 189.5, 187.3, and 188.5 m, respectively, demonstrating the accuracy of the proposed method. These results are highly significant for safe and environment-friendly coal mining in northwest Shaanxi, China.     

Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.     

油气管道完整性评价与管理软件

作为保障油气管道安全运行的重大举措，管道的完整性管理已经受到了国内外油气管道业界的高度重视，并处在不断地推广应用之中。为方便管道完整性管理技术的实际应用，研制开发了适用于工程实用目的的油气管道完整性评价与管理软件(PIAMS)， 并包含了管道风险评价与剩余强度评价的功能模块。为此，介绍了该软件的结构、模块、特点、主要功能和用户界面；该软件由数据库、管道风险分析、腐蚀缺陷评价、用户管理4个模块组成；可以运用该软件管理油气管道的完整性数据信息，进行管道的风险计算、风险分析以及对含缺陷管道的剩余强度评价；此外，该软件还具有可扩展性强的特点。     

GALILEO频率结构和信号设计的分析

描述并分析了由欧盟GALILEO信号特别工作组提出的GALILEO全球卫星导航定位系统的频率结构和信号设计。     

尿素解吸废液及甲醇残液联合处理工艺的应用

安阳化学工业集团公司(以下简称安化集团)现有2套200 kt/a尿素装置及1套60 kt/a甲醇装置.尿素及甲醇装置在生产过程中会产生大量的尿素解吸废液和甲醇残液,废液中的氨氮(NH3-N)含量和化学需氧量(CODCr)较高,给该公司废水的达标排放带来很大压力.     

鸡冠咀金矿废水污染预测及控制标准的探讨

本文以鸡冠咀金矿废水污染为例,论述了复杂水环境的预测模式选择和参数确定;并对水质标准进行了探讨;提出了鸡冠咀金矿废水排放的控制标准。     

半导体元件清洗技术浅谈

随着社会的进步和科学技术的迅猛发展,对洗净技术的要求也越来越高。清洗方式多种多样,但最主要的是突出在喷射清洗和超声波清洗两大方面,应用于全国各行各业,并且也得到了明显进步。     

真空膜蒸馏-反渗透联用技术处理尿液废水试验

在载人航天任务中,水的回收与净化处理是再生生保系统的重要组成部分.其中,尿液废水的净化处理是空间站废水处理的难点.文中采用真空膜蒸馏-反渗透联用技术处理模拟尿液废水,考察了真空膜蒸馏单元和反渗透单元分别处理尿液废水的处理效果,以及膜蒸馏单元产水的水量和水质情况,并考察了联用技术运行方式对水回收率的影响.结果显示,真空膜蒸馏-反渗透联用技术的产水量和产水水质稳定性好,在较低温度下运行时,最终的反渗透产水电导率小于1μs/cm,TOC含量小于5 mg/L.当采用全回流的方式运行,产水回收率可提高到96％,有望作为空间站尿液废水处理单元的替代技术.