Mechanism of displacement of electrolyte solutions from metal surface by inhibited oils

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, 11–13, May, 1991.     

A method of determining the levels of deoxynivalenol (vomitoxin) and its metabolites]

A method has been developed for assay of deoxynivalenol (DON) and its metabolite desepoxideoxynivalenol (DOM-1) in animal excrements with the use of reversed-phase high-performance liquid chromatography with UV-detection (218 nm). The method includes purification in the mini-column with activated carbon and aluminium oxide. The detection limit was 50 ng/g, relative standard deviation--0.05-0.1, the degree of toxin isolation--76-89%. DON isolated from Fusarium macroceras, strain 579a, cultivated in rice under laboratory conditions, and DOM-1 obtained as a result of DON incubation with the contents of the beef first stomach, were used in the study. The structure of toxins isolated has been proved by the mass-spectrometry method. The method developed by the authors was used in the study of DON metabolism in vivo in monkeys.     

Radiation–Thermal Decomposition of Nitric and Acetic Acids in a Aqueous Nitrate Solution

The kinetics of radiation, thermal, and radiation–thermal decomposition of a mixture of nitric and acetic acids in water solutions of sodium nitrate is investigated under homogeneous conditions and with a solid phase introduced in the form of sandstone. The experimental data are used to calculate the temperature dependences of the rate of radiation, thermal, and radiation–thermal decomposition of the acids. The results obtained make it possible to calculate the dynamics of decomposition of acids for the conditions of deep burial of liquid radioactive wastes.     

Factors affecting the quality of low- and medium-level solidified wastes

Main Science Center of the Russian Federation, A. A. Bochvara All-Russia Scientific-Research Institute of Standardization in Machine Engineering. Atomnaya énergiya, Vol. 79, No. 3, pp. 197–200, September, 1995.     

Structural changes in polycaproamide during thermal drawing of industrial fibres

It was shown that in going from the mesomorphic γ-modification of PA-6 to the stable α-form, formation of intermediate structures can play an important role. It was found that the formation of the polymorphous α-modification in conditions of heat treatment at 180°_C takes place due to the amorphous regions of the polymer. __________ Translated from Khimicheskie Volokna, No. 6, pp. 15–17, November–December, 2007.     

Mechanical properties of high-temperature alloy ZhS32 at 1150–1250°C

The mechanical properties of single crystals of alloy ZhS32 at a temperature of 1150–1250°C and deformation rates of 3 × 10⁻⁵, 10⁻⁴, and 10⁻³ sec⁻¹ are studied. The characteristics of true ductility in tests for long-term strength in a temperature range of 1150–1250°C are determined. __________ Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 1, pp. 38–40, January, 2006.     

Oxidation of CO on the Cu–Co–Fe oxide system applied on carbon nanotubes synthesized on Co<Subscript>2</Subscript>O<Subscript>3</Subscript>

Physicochemical characteristics of carbon nanotubes synthesized on Co₂O₃ and oxide Cu–Co–Fe catalysts on their base applied in the CO oxidation reaction have been investigated. It is shown that the deposition technology of the active mass, which, according to the X-ray phase analysis, is a mixture of the Cu₂(OH)₃NO₃ and CuO phases, strongly influences the activity of the Cu–Co–Fe/CNT catalysts. The greatest amount of the Cu₂(OH)₃NO₃ phase is observed in the catalysts produced by a single deposition of the active component on carbon nanotubes, which according to the thermodesorption mass spectroscopy, contributes to the formation of active centers with the lower activation energy of the CO₂ desorption and the reaction of the CO oxidation proceeds at a considerably lower temperatures. The TEMdata indicate that at the step-by-step deposition of the active mass in the surface layer the formation of the massive agglomerates, which are inhomogeneously located on the disordered structures of nanotubes, and this unfavourably affects the catalytic properties of Cu–Co–Fe/CNT catalysts.