Classification of honeys by principal component analysis on the basis of chemical and physical parameters

Summary Eighteen chemical and physical parameters of nectar and honeydew honeys were determined and the results were analysed statistically by the method of principal component analysis. On the plots of principal component loadings, the honeys were divided into the following groups: (1) acacia honey; (2) rape honey; (3) linden, floral (nectar coming from various plants) and heather honeys; (4) honeydew honey. The samples which were a blend of nectar and honeydew honeys may be considered as a separate group between 3 and 4. The most important first principal component was strongly associated with the value of electrical conductivity, the contents of ash, free acids and proline, as well as with the pH and the diastase number. The principal component loadings and linear correlation suggested that these parameters contributed much more to the classification of honeys than apparent reducing sugars, apparent sucrose, mono-, di-, and trisaccharides, glucose and fructose. The classification of honeys by the method of principal component analysis may serve as an additional tool in specifying samples on the basis of their chemical composition.

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Klassifizierung von Honigen durch chemische und physikalische Parameter mit Hilfe der Hauptkomponentenanalyse

Zusammenfassung 18 chemische und physikalische Parameter der Nektar- und Honigtauhonige wurden bestimmt und die Ergebnisse statistisch mit Hilfe der Hauptkomponentenanalyse ausgewertet. Danach konnten die Honige in folgende Gruppen unterteilt werden: 1) Akazienhonige, 2) Rapshonige, 3) Linden-, Blüten-und Heidehonige, 4) Honigtauhonige. Zwischen dem Nektarhonig und Honigtauhonig lagen wahrscheinlich die Proben von Mischhonigen aus Blüten- und Waldtracht. Die bedeutendste erste Hauptkomponente war mit folgenden Parametern verbunden: elektrischer Leitfähigkeitswert und Aschegehalt, Gehalt an freien Säuren und Prolin sowie der pH-Wert und Diastasezahl. Aufgrund der Hauptkomponentenladungen und der linearen Korrelation kann angenommen werden, daß diese Parameter für die Honigklassifizierung von größerer Bedeutung sind als der Gehalt an reduzierenden Zuckern, scheinbarer Saccharose, Mono-, Di- und Trisaccharide, Glucose und Fructose. Die Klassifizierung der Honige mit Hilfe der Hauptkomponentenanalyse kann bei der Spezifikation einer Honigprobe aufgrund ihrer chemischen Zusammensetzung von Nutzen sein.

     

Certification of software for real-time safety-critical systems: state of the art

This paper presents an overview and discusses the role of certification in safety-critical computer systems focusing on software, and partially hardware, used in the civil aviation domain. It discusses certification activities according to RTCA DO-178B “Software Considerations in Airborne Systems and Equipment Certification” and touches on tool qualification according to RTCA DO-254 “Design Assurance Guidance for Airborne Electronic Hardware.” Specifically, certification issues as related to real-time operating systems and programming languages are reviewed, as well as software development tools and complex electronic hardware tool qualification processes are discussed. Results of an independent industry survey done by the authors are also presented.     

Worst case bounds on the point-wise discretization error in boundary element method for the elasticity problem

In this work, point-wise discretization error is bounded via interval approach for the elasticity problem using interval boundary element formulation. The formulation allows for computation of the worst case bounds on the boundary values for the elasticity problem. From these bounds the worst case bounds on the true solution at any point in the domain of the system can be computed. Examples are presented to demonstrate the effectiveness of the treatment of local discretization error in elasticity problem via interval methods.     

The influence of caesium-137 distribution in Poland's north-eastern ecosystem on effective dose 10 years after the Chernobyl disaster

A comparison is presented of particular methods of exposure in the first year after the Chernobyl disaster and ten years later. This comparison shows that the population exposure due to the presence of radiocaesium in the environment results from the presence of caesium contained in the soil, which provides 68% of the dose (as compared to 32% in 1987) while the influence of diet has been reduced to 32% (from 68%). The exposure from caesium-137 contained in the air has dropped from 14% to 0. The effective dose from caesium has been 50 times smaller than that from environmental sources of the natural radiation estimated for the region under study to be 1.61 mSv x y(-1).     

Effect of transesterification of lard on stability,antioxidant-synergist efficiency,and rancidity development

Glyceride rearrangement of lard did not affect its resistance to oxidation or alter the efficiency of antioxidants and synergists. Changes in stability were due to the decomposition of tocopherol and the formation of reducing substances. The position of unsaturated fatty acids in the glyceride may influence the free volatile carbonyl compounds present in autoxidized lard and in rancidity development, Interesterification under vacuum produced an odorless and colorless randomized lard with natural stability in the range of the parent lard.     

Reflectance-based calibration of SeaWiFS. I. Calibration coefficients

We present a calibration approach for the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) based on the reflectance properties of the instrument's onboard diffuser. This technique uses SeaWiFS as a reflectometer, measuring the reflected solar irradiance from the Earth and from the onboard diffuser. Because the Sun is the common source of light for both measurements, the ratio of the SeaWiFS-measured radiances from the Earth and the diffuser provide the ratio for the reflectances of the two samples. The reflectance characterization of the onboard diffuser is the calibration reference for this approach. Knowledge of the value of the solar irradiance is not required for these measurements because it falls out of the ratio. Knowledge of the absolute calibration coefficient for the SeaWiFS measurements of each of the two samples is not required either. Instead, the result of the ratioing technique is based on the linearity of the instrument's response to the intensity of the input light. The calibration requires knowledge, however, of the reflectance of the onboard diffuser at the start of the SeaWiFS mission and the response of the instrument bands, in digital numbers, for measurements of the diffuser at that time.     

Optimization of evaporative fluid coolersOptimisation des refroidisseurs de liquide évaporatifs

In the paper the optimization of geometrical and operating parameters for evaporative fluid coolers has been presented. The algorithm of optimizational calculations contains:

• the mathematical model of heat and mass transfer in evaporative fluid coolers;

• model of operating costs based, among others, on the Zalewski–Gryglaszewski relations developed by the authors for evaluation of air pressure drops in the heat exchanger;

• model of evaporative heat exchangers production costs.

Optimization problem formulated for non-linear objective functions with inequality and equality constraints has been solved using Schittkowski's method based on quadratic programming. Two optimization problems have been considered. A solution to the first problem consists in the design of a heat exchanger with such geometrical parameters which ensure its maximum heat capacity at minimal total costs. A result to the second optimization problem are such thermal and flow parameters which will ensure minimum operating costs.The results of optimization calculations presented in the paper are accompanied by their experimental verification.     

Experimental and numerical investigation of a phase change material: Thermal-energy storage and release

The application of phase change materials (PCMs) for solar thermal-energy storage capacities has received considerable attention in recent years due to their large storage capacity and isothermal nature of the storage process. This study deals with the comparison of numerical and experimental results for a PCM conditioned in a parallelepipedic polyefin envelope to be used in passive solar walls. The experimental results were obtained by use of a genuine set-up involving heat flux sensors and thermocouples mounted on two vertical aluminium exchanger plates squeezing the samples. Numerical predictions were obtained with a custom one-dimensional Fortran code and a two-dimensional use of Fluent. Both methods showed a very good agreement with experimental observations for the melting process (?5%). However during solidification, both numerical codes failed to predict the phase change process accurately, the maximal relative error was as high as 57% (with an average of 8%).     

White Electroluminescence by Supramolecular Control of Energy Transfer in Blends of Organic‐Soluble Encapsulated Polyfluorenes

Here, it is demonstrated that energy transfer in a blend of semiconducting polymers can be strongly reduced by non‐covalent encapsulation of one constituent, ensured by threading of the conjugated strands into functionalized cyclodextrins. Such macrocycles control the minimum intermolecular distance of chromophores with similar alignment, at the nanoscale, and therefore the relevant energy transfer rates, thus enabling fabrication of white‐light‐emitting diodes (CIE coordinates: x = 0.282, y = 0.336). In particular, white electroluminescence in a binary blend of a blue‐emitting, organic‐soluble rotaxane based on a polyfluorene derivative and the green‐emitting poly(9,9‐dioctylfluorene‐alt‐benzothiadiazole ( F8BT ) is achieved. Morphological and structural analyses by atomic force microscopy, fluorescence mapping, µ‐Raman, and fluorescence lifetime microscopy are used to complement optical and electroluminescence characterization, and to enable a deeper insight into the properties of the novel blend.     

(Hu)man versus mean revisited: MMPI group data and psychiatric diagnosis.

Used a meta-analysis of Minnesota Multiphasic Personality Inventory (MMPI) data from 403 control and psychiatric samples to (1) examine demographics associated with previously published MMPI studies, (2) test L. R. Goldberg's (1972) indexes for predicting normal versus deviant and neurotic versus psychotic group membership, (3) compare multiple regression, discriminant function, and logistic regression analyses commonly used to study the relation between the MMPI and diagnostic group membership, and (4) examine the signal within the MMPI as it related to current psychiatric diagnosis. Group data were found to be efficient indicators of the relation between the MMPI and diagnosis, although efficiency is compromised by within-sample heterogeneity. The 3 statistical methods examined obtained equivalent results. Regression models related to group prediction are presented. (PsycINFO Database Record (c) 2010 APA, all rights reserved)