Design of a Web Based Underwater Acoustic Communication Testbed and Simulation Platform

Wireless Personal Communications - Underwater Wireless Sensor Networks (UWSNs) are playing a vital role in exploring the unseen underwater (UW) natural resources. However, performance evaluation of...     

The coating of cadmium compounds with copper compounds

Fine particles of cadmium carbonate (CdCO₃) were prepared by heating aqueous solutions containing dissolved urea and cadmium sulfate at 85°C for 1 h. Effect of the composition of the reactant mixture on the morphology of the precipitated particles was investigated. It was found that the cadmium sulfate content of the reactant mixture significantly affected the shape and size of the precipitated particles. At certain range of reactant mixture composition, cauliflower-shaped uniform particles were obtained. The later particles were coated with basic copper carbonate (Cu₂(OH)₂CO₃) by heating aqueous dispersions, containing CdCO₃ particles, copper (II) nitrate, and urea at 85°C for various periods of time with constant stirring. The coating process was found sensitive to the experimental conditions and in most of the trials; mixtures of the coated and coating precursor particles were obtained. As such, extensive optimizations were carried out and conditions were established for the production of uniformly coated particles.On calcination at 700°C for 1 h, the CdCO₃ particles converted into CdO, whereas the coated particles (CdCO_{3 (core)}/Cu₂(OH)₂CO_{3 (coating)} transformed into CdO_(core)/CuO_(coating)) without sintering. In the coated particles, the core and coating materials stayed mutually inert during the calcination reaction and independently converted into their respective oxides.All the calcined and uncalcined products were characterized by various physical and chemical methods.     

Making combination drawing methods more efficient by controlling tool microroughness

Results are presented from extensive comparison studies of drawing operations performed with the use of drawplates whose working surfaces have an irregular or regular microroughness. Regularizing the microroughness of the working part of the drawplate makes it possible to control the dimensional accuracy of the resulting products within broad ranges of values.     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

An open-source multi-DOF articulated robotic educational platform for autonomous object manipulation

This research presents an autonomous robotic framework for academic, vocational and training purpose. The platform is centred on a 6 Degree Of Freedom (DOF) serial robotic arm. The kinematic and dynamic models of the robot have been derived to facilitate controller design. An on-board camera to scan the arm workspace permits autonomous applications development. The sensory system consists of position feedback from each joint of the robot and a force sensor mounted at the arm gripper. External devices can be interfaced with the platform through digital and analog I/O ports of the robot controller. To enhance the learning outcome for beginners, higher level commands have been provided. Advanced users can tailor the platform by exploiting the open-source custom-developed hardware and software architectures. The efficacy of the proposed platform has been demonstrated by implementing two experiments; autonomous sorting of objects and controller design. The proposed platform finds its potential to teach technical courses (like Robotics, Control, Electronics, Image-processing and Computer vision) and to implement and validate advanced algorithms for object manipulation and grasping, trajectory generation, path planning, etc. It can also be employed in an industrial environment to test various strategies prior to their execution on actual manipulators.     

Alkaline fuel cells: contemporary advancement and limitations

ZeTek Power recently introduced mass manufacturable and cost effective alkaline fuel cells on the market. Today's research is focused on further improvement both in terms of performance increase and cost reduction. This research is classically performed using small (4 cm²) experimental electrodes in the half-cell configuration. This allows the primary electrochemical losses in an anode or cathode to be determined independently. Additional performance losses occur when one integrates large electrodes into a module of 24 cells and in a stack comprised of many modules. By comparing the performance of half-cell experiments to that of modules, these losses can be distinguished and addressed. The information thus obtained, both for the small electrodes and in up-scaling is vital if one is to identify the key areas in which improvement is possible and where to focus future research. Furthermore, the identification of the losses in a module and system allows us to predict the final performance from half-cell measurements of a new laboratory scale experimental electrode.     

Transport of phosphorus forms and of nitrate through a clay soil under grass and cereal production

Many nutrients are lost from soil to water viatile drains. However, there are very few reliable studies of such phosphorus(P)losses under Swedish agriculture practices, especially in connection tofertiliser and slurry applications and related to nutrient balances. Tile drainlosses were measured from nine experimental plots in south-west Sweden; fourplots were measured for 7 years and five plots for 2–3 years. Cereals,mainly spring barley (Hordeum vulgare, L.) and oats(Avena sativa, L.), were grown in six plots, while oneplotwas cultivated with grass, timothy (Phleum pratense L.)andmeadow fescue (Festuca pratensis, L.), one with lucerne(Medicago sativa, L.) and meadow fescue (F.pratensis, L.), and the last one was a set-aside withgrass (Lolium perenne, L. and Trifoliumrepens, L.) that was neither fertilised nor used for crop removal.Attention was paid to the forms in which P was transported to water since thishas important ecological implications. Average losses of particulate P (PP)fromthe set-aside land was significantly lower than from the cerealproduction, but the average losses of soluble reactive P (SRP) and dissolvednonreactive P (DUP) were the same. Average loss of PP from the grass ley during 3years (0.09 kg per ha^–1 y^–1) wassignificantly less than the losses from cereal production. Total P loss of 0.3kg per ha^–1 y^–1 was equal to the averagelossfrom the Swedish monitoring network of observation fields. Compared to theaverage nitrate-nitrogen (NO₃-N) leaching, which was 7 kg perha^–1 y^–1 from cereals, the NO₃-Nleaching was very low from the plots with lucerne-grass and set-aside.After applying and directly ploughing in 80 kg ha^–1 ofsuperphosphate for cereal production in November 1998, 0.6–1.8 kgSRP ha^–1 y^–1 was lost through the drain tiles.Surface application of cattle slurry in spring 1999 to the grass ley alsoresulted in a very pronounced increased base level of SRP. This paper documentsthe importance of applying slurry during dry conditions and of placingfertiliser into the soil according to crop requirements in the time perspectiveof one year.     

Semi- and fully interpenetrating polymer networks based on polyurethane–polyacrylate systems. VI. Polyurethane–poly(methyl acrylate-co-ethyl acrylate) semi-1-interpenetrating polymer networks

Dynamic mechanical and longitudinal sonic velocity measurements have been made on a series of semi-1-IPNs in which the network component is a polyurethane and the linear constituent a copolymer of methyl acrylate and ethyl acrylate. Dynamic mechanical analysis reveals phase separation. The shifting of the polyurethane glass transition in both the tan δ? and the E″–temperature plots indicates that some mixing occurs. The longitudinal sonic velocity results indicate that the polyurethane is present as a continuous phase in all the materials investigated.     

Direct analysis of annealing of nodular crystals in isotactic polypropylene by atomic force microscopy, and its correlation with calorimetric data

The process of isothermal annealing of nodular monoclinic crystals of isotactic polypropylene (iPP) was analyzed by atomic force microscopy (AFM) and temperature-modulated differential scanning calorimetry (TMDSC). Initially nodular and mesomorphic domains were obtained by controlled melt-crystallization at high cooling rate. Subsequent heating triggers transition from mesomorphic to monoclinic structure, and melting of unstable nodules. Annealing allows re-crystallization, which is recognized by enlargement of domains from initially about 20 nm to about 35 and 55 nm after annealing at 393 and 433 K, respectively. Furthermore, the re-crystallization process is connected with a slight change of the aspect ratio of crystals. The isothermal re-crystallization of the liquid is superimposed by aggregation of crystals, to yield blocky, and string-like objects. The direct analysis of structure on isothermal annealing by AFM is for the first time compared with the isothermal decrease of the apparent specific heat capacity, or change of enthalpy, monitored by TMDSC. The apparent specific heat capacity decreases during annealing with an identical non-linear time dependence as the directly observed growth of the crystal size. Analysis of the annealing processes at different temperatures yields proportionality between the increase of the crystal size and the reduction of the apparent specific heat capacity.     

An efficient recommender system algorithm using trust data

The Journal of Supercomputing - Smart services are a concept that provides services to the citizens in an efficient manner. The online shopping and recommender system can play an important role for...