全文获取类型
收费全文 | 4709篇 |
免费 | 167篇 |
国内免费 | 13篇 |
专业分类
电工技术 | 49篇 |
综合类 | 7篇 |
化学工业 | 1052篇 |
金属工艺 | 94篇 |
机械仪表 | 93篇 |
建筑科学 | 313篇 |
矿业工程 | 7篇 |
能源动力 | 110篇 |
轻工业 | 461篇 |
水利工程 | 28篇 |
石油天然气 | 24篇 |
无线电 | 262篇 |
一般工业技术 | 733篇 |
冶金工业 | 1056篇 |
原子能技术 | 70篇 |
自动化技术 | 530篇 |
出版年
2021年 | 45篇 |
2020年 | 42篇 |
2019年 | 55篇 |
2018年 | 62篇 |
2017年 | 80篇 |
2016年 | 91篇 |
2015年 | 60篇 |
2014年 | 112篇 |
2013年 | 297篇 |
2012年 | 154篇 |
2011年 | 212篇 |
2010年 | 189篇 |
2009年 | 176篇 |
2008年 | 197篇 |
2007年 | 195篇 |
2006年 | 184篇 |
2005年 | 158篇 |
2004年 | 141篇 |
2003年 | 127篇 |
2002年 | 108篇 |
2001年 | 92篇 |
2000年 | 78篇 |
1999年 | 78篇 |
1998年 | 149篇 |
1997年 | 114篇 |
1996年 | 95篇 |
1995年 | 80篇 |
1994年 | 83篇 |
1993年 | 82篇 |
1992年 | 63篇 |
1991年 | 57篇 |
1990年 | 70篇 |
1989年 | 73篇 |
1988年 | 67篇 |
1987年 | 46篇 |
1986年 | 59篇 |
1985年 | 66篇 |
1984年 | 61篇 |
1983年 | 59篇 |
1982年 | 56篇 |
1981年 | 61篇 |
1980年 | 53篇 |
1979年 | 62篇 |
1978年 | 63篇 |
1977年 | 57篇 |
1976年 | 62篇 |
1975年 | 37篇 |
1974年 | 33篇 |
1973年 | 42篇 |
1970年 | 27篇 |
排序方式: 共有4889条查询结果,搜索用时 15 毫秒
1.
In this work was investigated the effect of the addition of barium titanate (BaTiO3) on electrical properties of two chemically recyclable thermosets, polyhemiaminal (PHA) and polyhexahydro‐s‐triazine (PHT), both fabricated from 4,4′‐oxydianiline (ODA), an ether derivative of aniline and paraformaldehyde. Thermal and mechanical properties as well as chemical recyclability of the two polymers and their nanocomposites/nanodielectrics were also investigated. In addition, a quantitative analysis was conducted of the nanoparticle dispersion in the PHA‐/PHT‐based BaTiO3‐containing nanocomposites using transmission electron microscopy imaging and the nearest‐neighbor distance index and this index was used to analyze the investigated properties in connection with the proper mechanisms. Regarding the electrical properties for both neat polymers, conductivity values of the order of 10?8 S m?1 at 100 Hz were observed and dielectric constant values close to 2.80 for both polymers at 1 kHz. The addition of 0.5 wt% of BaTiO3 ferroelectric nanoparticles increased by about 44% the dielectric constant (1 kHz) and conductivity (102 Hz) of the PHA‐based nanocomposite. PHA and PHT exhibited glass transition temperature (Tg) values in the range 125–180 °C. An increase of 7 °C in Tg was observed after the incorporation of 0.5 wt% of BaTiO3 into PHA. Concerning the mechanical properties, values in the range 4.00–4.45 GPa for reduced modulus and 0.30–0.43 GPa for nanohardness for PHA and PHT polymers were observed. Independently of filler content or polymer matrix, both mechanical properties were enhanced after the addition of BaTiO3. The chemical recycling of PHA/PHT and all nanocomposites in the initial ODA reagent after sulfuric acid treatment was successfully characterized using the NMR and Fourier transform infrared spectroscopic techniques. © 2018 Society of Chemical Industry 相似文献
2.
3.
Maimaitiaili Tayier Yunfeng Zhao Dengle Duan Rongge Zou Yunpu Wang Roger Ruan 《木材化学与工艺学杂志》2020,40(3):190-199
AbstractLignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the SBET, Vt, and Vmec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni2+ or Fe3+). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%. 相似文献
4.
5.
This work examines the correlation between the 1H‐NMR T2 relaxation constant and the mechanical properties of aged crosslinked polyolefin cable insulation. T2 experiments on unswollen samples could not differentiate between unaged and highly aged materials; all exhibited 1H T2 constants of approximately 0.5 ms. To accentuate the effects of aging, samples were swollen in various solvents. Unaged samples had T2 values of approximately 15 ms in good solvents. With thermal aging, T2 values decreased as the ultimate tensile elongation decreased. However, the correlation between T2 and elongation differed for samples irradiated with high‐energy radiation and for materials aged above versus below the crystalline melting temperature. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2578–2582, 2003 相似文献
6.
Purified cell-envelope polyphosphatase as well as polyphoshatase activities of cytosol and isolated vacuoles, of nuclei and mitochondria of the yeast Saccharomyces cerevisiae were compared. The polyphosphatases of cell envelope and cytosol are similar, the polyphosphatases of nuclei, vacuoles and mitochondria differ in their kinetic properties, substrate specificity, requirements in divalent cations and in some effector actions both from these and from each other. 相似文献
7.
Increased concentrations of octachlorodibenzo-p-dioxin in cases with breast cancer--results from a case-control study 总被引:1,自引:0,他引:1
L Hardell G Lindstr?m G Liljegren P Dahl A Magnuson 《Canadian Metallurgical Quarterly》1996,5(5):351-357
Organochlorines are persistent and highly lipophilic environmental contaminants which bioaccumulate in the food chain. Some of these chemicals, 2,2-bis(p-chlorophenyl)-1,1,1-trichloroethane (DDT) and polychlorinated biphenyls (PCBs), have been suggested to be of significance in the aetiology of breast cancer. 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is an anti-oestrogen in animal studies and should be thus lower the risk of breast cancer. The other isomers of polychlorinated dibenzo-p-dioxins (PCDDs) or the chemically related polychlorinated dibenzofurans (PCDFs) have not been tested regarding carcinogenesis of the breast. The purpose of this study was to investigate whether PCDDs or PCDFs influence the risk for breast cancer. Consecutive patients who underwent surgery for a breast disease between 1993 and 1995 were recruited for the study. Cases were 22 patients with infiltrative breast cancer and controls were 19 patients operated for a benign breast disease during the same time period. Approximately 10 g of breast tissue free from tumour was taken from the specimen and frozen until analysis. Fat was extracted, cleaned and analysed with a high-resolution gas chromatograph coupled to a high-resolution mass spectrometer. Median concentrations of octachlorinated dibenzo-p-dioxin (OCDD) were 598 (170-14,880) and 396 (103-1,847) pg/g lipid in the cases and in the controls, respectively. In a multivariate logistic regression analysis controlling for other risk factors for breast cancer increased odds ratio (OR) was obtained for OCDD: 401-1000 pg/g lipid yielded OR 3.8, 95% confidence interval (CI) 0.4-39, > 1000 pg/g lipid gave OR 5.2, CI 0.4-72. When the lipid OCDD variable was examined as a continuous risk factor there was a 1.09 (9%), CI 0.95-1.25, increase in the adjusted OR for breast cancer per 100 unit (pg/g lipid) increase in OCDD. No differences were found between cases and controls for the other six tested PCDDs. Mean concentration of TCDD was in the cases 3.6 (1.0-7.9) and in the controls 3.3 (1.1-6.3) pg/g lipid. For PCDFs no significant differences were found between cases and controls. The results were not changed if oestrogen or progesterone receptor status, S-phase fraction and DNA ploidy were considered. Breast tissue concentration of OCDD was increased in cancer patients, whereas the concentrations of other PCDDs and PCDFs were equal in cases and controls. 相似文献
8.
Marginal costs of electricity vary by time and location. In the past, researchers attributed the variations to factors related to electricity generation and transmission. These authors, however, have not analyzed possible variations in marginal distribution capacity costs (MDCC). The objectives of this paper are:
- 1. (i) to show that large MDCC variations are due to the dispersion in distribution capital expenditures by time and space,
- 2. (ii) to propose a method for quantifying the area- and time-specific MDCC in the presence of lumpy investments, and
- 3. (iii) to compare our MDCC estimates to those commonly used in the electric utility industry.
9.
10.
Carlos E. Esparza Martha P. Guerrero-Mata Roger Z. Ríos-Mercado 《Computational Materials Science》2006,36(4):457-467
A numerical optimization technique based on gradient-search is applied to obtain an optimal design of a typical gating system used for the gravity process to produce aluminum parts. This represents a novel application of coupling nonlinear optimization techniques with a foundry process simulator, and it is motivated by the fact that a scientifically guided search for better designs based on techniques that take into account the mathematical structure of the problem is preferred to commonly found trial-and-error approaches. The simulator applies the finite volume method and the VOF algorithm for CFD analysis. The direct gradient optimization algorithm, sequential quadratic programming (SQP), was used to solve both a 2D and a 3D gating system design problems using two design variables. The results clearly show the effectiveness of the proposed approach for finding high quality castings when compared with current industry practices. 相似文献