Facile construction of composition-tuned ruthenium-nickel nanoparticles on g-C3N4 for enhanced hydrolysis of ammonia borane without base additives

Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C₃N₄) as a NP support without additional stabilizing ligands. The optimized Ru₁Ni_7.5/g-C₃N₄ catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min^?1 and an activation energy of 28.46 kJ mol^?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru₁Ni_7.5/g-C₃N₄ is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru₁Ni_7.5/g-C₃N₄ has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru₁Ni_7.5/g-C₃N₄ should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen.     

Cu-Mg/Al_2O_3催化乙醇和乙二胺合成N-乙基乙二胺

在固定床反应器内,乙醇和乙二胺经分子间催化胺化反应合成了N-乙基乙二胺(NEED),考察了一系列铜系催化剂的活性,并筛选出催化性能较好的Cu-Mg/A l2O3催化剂;通过X射线衍射和透射扫描电子显微镜方法表征了助剂Mg对Cu/A l2O3催化剂的改性作用;考察了助催化剂Mg含量、反应温度、反应压力、进料量和乙二胺含量等对Cu-Mg/A l2O3催化剂性能的影响。实验结果表明,Cu-Mg/A l2O3催化剂具有很好的活性和选择性;在200℃、3.0MPa、质量分数20%的乙二胺乙醇溶液、进料量1.0mL/m in的条件下,乙二胺的转化率为71.56%,产物NEED的选择性和收率分别为92.62%和69.86%;经过20 d的连续使用表明,Cu-Mg/A l2O3催化剂具有良好的稳定性。     

用JHS-3胶合砂防粉细砂

针对孤东油田大量油井出现粉细砂甚至粘土砂而严重影响生产的问题,研制了用JHS-3胶合砂防粉细砂方法。介绍了胶合砂的基本配方、主要技术指标及防砂机理。适应性分析结果表明,施工井的层数、处理半径和施工压力升幅3个因素直接影响着胶合砂的防砂堵水效果。现场20井次的应用情况可看出,胶合砂能有效地防住粉细砂和粘土砂,明显地改善产液剖面,并有显著的降水增油效果。     

检测骨架图形特征点的新方法

端点、折点、歧点和交点是骨架图形的重要特点是，提出用快速查表法检测侯选特征点，再进行侯选特征点聚集，用局部结构分析，去除假特征点，判别真特征点的类型，并对折点给以大致的定量描述。实验结果表明，该方法能快速有效地找出骨架图形的特征点，在目标识别、字符识别等应用中起着关键作用。     

提高压力过滤器滤套使用寿命的途径

佳木斯造纸厂从芬兰奥斯龙公司引进了一套新型、高效、低碱流失的压力过滤、洗涤苛化系统。本文就如何延长该系统主体元件──滤套的使用寿命这一技术问题，进行系统的阐述。     

2#板坯连铸机振动台故障分析及改造

论述了银山型钢有限公司炼钢厂2#板坯连铸机自投产以来其振动台存在的问题，根据实际情况分析论证并进行改造实施，实施后效果明显。     

稠油注汽井用高温调剖封窜剂的研制与应用

随着单井蒸汽吞吐周期的增加，加剧了油层纵向和平面上的非均质性。汽驱井组油层存在高渗透带或孔道，注入蒸汽上升，从稠油顶部跨越，会出现越顶现象，造成提早汽窜，注蒸汽驱的波及效率进一步降低。针对此问题，开发了稠油注汽井用高温调剖封窜剂。室内研究结果表明，研制的高温调副封窜剂HD、HT具有较好的高温成胶性能和强度。现场应用孤东油田的9口井，有效8口，有效率88．9％，累计增油726．8t。