Strain hardening due to deformation twinning in α-titanium: Mechanisms

Novel experiments were conducted to elucidate the effect of deformation twinning on the mechanical response of high-purity α-titanium deformed at room temperature. Orientation-imaging microscopy (OIM), microhardness, and nanohardness evaluations were employed in conjunction with optical microscopy and quasi-static compression testing to obtain insight into the deformation mechanisms. Hardness measurements revealed that the newly formed deformation twins were harder than the matrix. This observation is perhaps the first experimental evidence for the Basinski mechanism for hardening associated with twinning, arising from the transition of glissile dislocations to a sessile configuration upon the lattice reorientation by twinning shear. This work also provided direct evidence for two competing effects of deformation twinning on the overall stress-strain response: (1) hardening via both a reduction of the effective slip length (Hall-Petch effect) and an increase in the hardness of twinned regions (Basinski mechanism) and (2) softening due to the lattice reorientation of the twinned regions.     

A systematic approach to preliminary polymer process development: modeling and design

A general and complete methodology is presented to facilitate systematic modeling and design of polymer processes during the early development period. To capture and handle the subjective type of uncertainty, embedded in the preliminary process development, fuzzy theories are used as a basis to model and design the process in the presence of ambiguity and vagueness. Physical membership functions are developed for mapping the relation between process variables and the associated fuzzy uncertainties. Based on the qualitative results generated using our previously proposed “linguistic based preliminary design method,” the process modeling can be followed even in the absence of any process governing equations. The modeling is carried out by establishing an appropriate fuzzy reasoning system which provides a specific functional mapping that relates input process variables to one (or more than one) output performance parameter(s). A reduced yet feasible domain is generated by our qualitative design scheme to constrain the process variables. Now, any optimization routine can then be employed to search for a proper process design. We demonstrate the effectiveness of the proposed methodology by its application to a typical compression molding process.     

Electrical Insulation Characteristics of Silicone and EPDM Polymeric Blends. I

The typical parts of a polymeric insulator are core, metal end fittings and polymeric housing material. The housing is intended to protect the fibre glass rod from the environment and electrical surface discharges. Since the housing materials are made of organic polymeric material, its insulation characteristics need to be studied. Amongst the many different polymers available, this work focuses on silicone rubber and ethylene propylene diene monomer (EPDM). Blends of EPDM and silicone rubber are prepared in a two roll mixing mill. Dicumyl peroxide is used as vulcanizing agent. The blends consisting of various proportions of component polymers are prepared, compression moulded into sheets, and post cured. The blends are tested for their insulation characteristics as per IEC and ASTM standards. Volume and surface resistivity, dielectric strength, dielectric constant, tan delta, tracking resistance, arc resistance, comparative tracking index, tensile strength, and percentage elongation at break of the blends are studied and discussed. The test results show that the increasing proportion of silicone enhances the electrical insulation properties whereas increasing weight percentage of EPDM improves the mechanical strength of the blends.     

Product mix determination in the presence of alternate process plans and stochastic demand

The product mix problem in the presence of alternate process plans under uncertain demand is formulated as a non-linear programming model. A heuristic solution procedure based on lagrangean relaxation technique is also presented.     

APPLICATION OF RESPONSE SURFACE METHODOLOGY FOR THE MAXIMIZATION OF CONCORA CRUSH RESISTANCE OF PAPERBOARD

Response surface methodology is often used by researchers in different fields to determine the optimum values for controlled variables to maximize or minimize the response variables. Either maximization or minimization might be necessary depending on the response property. For example, if the response variable represents the yield of a process, maximization could be necessary; on the other hand, if the response variable is the biological oxygen demand (BOD) of an effluent the aim would definitely be minimization

Response surface methodology can be used two ways. It can be applied to the full-scale production or it can be scaled to a laboratory or the pilot plant. When applied to the full-scale production, the method is known as evolutionary operation (EVOP). EVOP is the continuous optimization of a process. The optimum conditions in a production plant can change depending on many factors such as raw material, ambient temperature, and equipment wear. Therefore, controlled variables should be optimized continuously to keep the response variable as close as possible to the maximum or minimum value. Hence, controlled variables are systematically changed around a center point to depict any shift of the response variable from the extreme. A thorough discussion of EVOP is given by Box, Evolutionary Operation: A Method for Increasing Industrial Productivity, Appl. Statist., 6, 81-101 (1957).     

Dyes from the leaves of deciduous plants with a high tannin content for wool

The aqueous leaf extracts of five different deciduous plants, namely, silver oak, flame of the forest, tanner’s senna, wattle and serviceberry, were used on their own and in combination with aluminium sulphate, stannous chloride and ferrous sulphate to dye wool by a simultaneous mordanting technique. The washing and light fastness properties of the developed shades were moderate to good. Based on the CIE 2000 spectral colour coordinate values (K/S, ΔL, Δa, Δb and ΔE), the developed shades were classified into four groups: yellow/brown, yellow, orange and dark grey. The use of aluminium sulphate gave medium shades (K/S = 8.24), while the stannous chloride and ferrous sulphate mordants provided deep shades (K/S = 30.5). Statistical analyses have shown that only the type of mordant and not the dye source significantly influenced the development of colour on wool. Hence, it was theoretically possible to use five selected leaves as a single mixture to produce four different colours on wool.     

Soil–conduit interaction: an artificial intelligence application for reinforced concrete and corrugated steel conduits

Neural Computing and Applications - Marston’s load theory is commonly used for understanding the soil–conduit interaction. However, there are no practical methods available which can...     

Scanning Auger electron spectroscopy study of the oxide film formed on dendritic and interdendritic regions of C containing Fe3Al intermetallic

The oxide films formed during early stage of oxidation at 800 °C on dendritic and interdendritic regions of the cast Fe–16Al–1C (wt.%) alloy were studied using scanning Auger electron spectroscopy. Microhardness measurement and elemental depth profiles by Auger spectroscopy reveal that the carbide, Fe₃AlC_0.69, is the major constituent of the interdendritic region, while dendrites are predominantly Fe₃Al phase. Between the two, the interdendritic region is found to be more prone to oxidation than the dendritic region, which was attributed to presence of carbides with low-Al content. In spite of the difference in oxide film thickness exhibited by both the phases, they consist of an inner aluminium oxide layer and an outer iron oxide layer.     

Compositional trend analysis on poly(phenylene ether) based thermoplastic elastomers

Detailed statistical trend analysis of thermoplastic elastomers based on poly (phenylene ether) (PPE), polystyrene (PS), ethylene vinyl acetate (EVA) and styrene‐ethylene‐butylene‐styrene (SEBS) was done through Design Expert software by Stat‐Ease. D optimal crossed design was followed to capture the interaction with the parameters. Effect of blend ratio, vinyl acetate (VA) content of EVA, molecular weight (MW) of SEBS and intrinsic viscosity (IV) of PPE on the blend performance (response) was studied in detail. Design of Experiment (DOE) analysis showed the “optimized formulation” of the blend. Increase in PPE‐polystyrene (PS) content increased tensile strength and modulus of the blend, followed by a decrease in strain at break. However, EVA had a reverse effect on tensile strength and modulus. Strain at break increased significantly with increasing SEBS content in the blend. Graphical and numerical optimization showed that superior mechanical properties (tensile strength, strain at break and modulus) could be achieved at VA content ～ 50% at a particular loading of EVA. Low MW SEBS was found to be more compatible with the other components of the blend. Mechanical properties of the quaternary blend were marginally affected with change in IV of PPE in the range of 0.33 to 0.46. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007