Hot corrosion Type II of FeCr‐based model alloys for boiler and heat exchanger applications

The hot corrosion Type II of the alloys FeCr20, FeCr20Ni10, FeCr20Ni20, and FeCr20Co10 is investigated at 700°C in air + 0.5% SO₂ with deposits consisting of Na₂SO₄ and a eutectic mixture of Na₂SO₄ and MgSO₄ for 24, 100, and 300 h. The alloying elements nickel and cobalt have a positive influence when tests are conducted using a MgSO₄‐Na₂SO₄ deposit. In this case, they reduce the metal loss and increase the time to the propagation stage. In contrast, when the alloys are exposed with a Na₂SO₄ deposit, these alloying elements increase the metal loss and allow for the transition to the propagation stage because they can form molten phases with the Na₂SO₄. During the incubation stage an oxide scale forms on the FeCr20 alloy, which is thicker than the one formed during exposure without a deposit, and iron oxides are observed, which precipitate in the deposit. The propagation stage occurs by a dissolution and precipitation mechanism forming localized pitting attack. Iron is the main species that dissolves and precipitates, while chromium remains mainly as an oxide beneath the initial surface. The additional elements are found in the pit and in the salt deposit.     

Synthesis of N,N-diethyl-N-{4-[(E)-(4-nitrophenyl)diazenyl]phenyl}amine via in situ diazotisation and coupling in supercritical carbon dioxide

The synthesis of azo dyes via a conventional aqueous-based diazotisation and coupling reaction requires the use of relatively high concentrations of mineral acids, which leads to high electrolyte concentrations in wastewater. Reported in this paper is an environmentally benign one-pot method for the synthesis of a nonionic azo dye, N,N -diethyl- N -{4-[( E )-(4-nitrophenyl)diazenyl]phenyl}amine, in supercritical carbon dioxide without using a mineral acid. The product yield increased significantly with temperature, with 91% theoretical yield afforded at 80 °C. The pressure of the system had little influence on product yield.     

Dynamics of [Ca2+] in the endoplasmic reticulum and cytoplasm of intact HeLa cells. A comparative study

We have measured the [Ca2+] in the endoplasmic reticulum ([Ca2+]er) of intact HeLa cells at both 22 degrees C and 37 degrees C using endoplamsic reticulum-targeted, low Ca2+ affinity aequorin reconstituted with coelenterazine n. Aequorin consumption was much slower at 22 degrees C, and this allowed performing a much longer study of the dynamics of [Ca2+]er. The steady-state [Ca2+]er (500-600 microM) was not modified by the temperature, although both the rates of pumping and leak were decreased at 22 degrees C. The behavior of both [Ca2+]er and cytoplasmic [Ca2+] ([Ca2+]c) after the addition of increasing concentrations of agonists and/or Ca2+-ATPase inhibitors, or following incubation in Ca2+-free medium were compared. We show that agonists induce a fast but relatively small decrease in [Ca2+]er, which is enough to produce a sharp increase in [Ca2+]c. Termination of Ca2+ release is controlled by feedback inhibition of the inositol 1,4,5-trisphosphate receptors by [Ca2+]c, a mechanism that appears to be designed to release the minimum amount of Ca2+ necessary to produced the required [Ca2+]c signal. We also show that Ca2+ release is inhibited progressively when [Ca2+]er decreases below a threshold of about 150 microM, even in the absence of Ca2+ pumping or -Ca2+-c increase. This effect is consistent with a regulation of the inositol 1,4,5-trisphosphate-gated channels by [Ca2+]er.     

On the use of tapered linearly chirped gratings asdispersion-induced distortion equalizers in SCM systems

We report on the use of tapered linearly chirped fiber gratings to equalize dispersion-induced distortion in long distance/broad-band subcarrier multiplexed (SCM) systems. Different apodization functions for the coupling factor of the fiber grating have been considered and their equalizing capability of fiber-induced distortion in a subcarrier system have been compared. The results of the theoretical analysis show that both harmonic and intermodulation distortions are significantly reduced when the equalizer parameters have been properly designed. Higher reduction of the nonlinear distortion is obtained when the length of the filter increases, even though a saturation effect on this reduction figure appears when the equalizer length is about four or five times its minimum value to achieve equalization, which is derived theoretically based on the SCM optical system parameters. The performance of a Tanh-type tapered linearly chirped grating equalizer on a realistic broadband SCM system is also considered. The results reveal that the dispersion-induced distortion can be neglected when the equalizer is employed     

Natural and induced tolerance in an immune network model

It has been proposed that the immune system can be partitioned into central and peripheral immune systems. Recently, Carneiro et al. (1996a, b) proposed a network, model incorporating B and T lymphocytes that explicitly accounts for that partition. This model however, had some limitations that are tackled here. Two main changes were introduced: the average idiotypic connectivity is now an explicit function of time based on empirical evidence; and the activation of T lymphocytes by antigen is described by a log-bell shaped dose response curve. The new model, which also accounts for the CIS and PIS distinction, shows more reasonable results since the frequencies of tolerant, immune or autoimmune responses to an antigen are now correct. The model provides a new interpretation for tolerance induction during the neonatal period, and for the adult tolerance by low or high doses of antigen. It predicts that natural tolerance for antigens available during the neonatal period can be kept indefinitely upon their removal, while tolerance induced in the adult stages is rapidly lost upon transient removal of the antigen. A semiquantitative analysis of the model provides a simple explanation for the different results in terms of the frequency at which a limited set of canonical connectivity structures emerge during ontogenesis.     

The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction

An alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the variation of the polarization resistance in a tubular platinum electrode with a laminar flow of electrolyte as a function of the activity of protons of the electrolyte solution. A theoretical expression that relates the experimental variables and the equilibrium polarization resistance is developed, which takes into account the current distribution along the electrode surface. The results are compared with others obtained previously, contributing to the verification of the kinetic mechanism through a completely different experimental procedure.     

Enzyme‐catalyzed hydrolysis of poly(ethylene terephthalate) cyclic trimer

Oligoesters present in poly(ethylene terephthalate) fibers are commonly extracted from the fiber during processing, such as aqueous‐based dyeing. Aqueous, insoluble oligoesters, particularly cyclic trimers that precipitate on processing machinery and on the fiber surface are difficult to remove under benign conditions. Reported is a new method for the efficient removal of cyclic trimer by enzyme‐catalyzed hydrolysis. Almost complete hydrolysis of trimer was accomplished at pH 8 and 60°C. Effects of time, agitation, surfactant, and enzyme and trimer concentrations on the efficiency of hydrolysis are reported. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2545–2552, 2003     

A comparison of vapour pressure measurements of quinizarin and leuco-quinizarin via transpiration and thermogravimetry

The vapour pressure of solids can be obtained using a number of methods, including the Knudsen effusion method, the Knudsen torque-effusion method and a transpiration method. Each method has benefits and disadvantages. Reported is a comparison of vapour pressure data for two compounds, quinizarin and leuco -quinizarin, using a transpiration method and a recently developed method based on thermogravimetry. Thermogravimetry provided vapour pressure–temperature dependence data for each compound with expediency and in agreement with the transpiration method.     

Ultra-low noise front-end electronics for air-coupled ultrasonic non-destructive evaluation

Air-coupled ultrasonic inspection has been demonstrated to be a non-contact method of great interest in non-destructive evaluation (NDE) applications. The absence of direct contact or a liquid couplant provides this technique very attractive benefits in front of the well-known and well-developed liquid-coupled ultrasonic inspection systems. A wide range of defects can be detected by means of ultrasound coupled to and harvested from the specimen in absence of contact when using appropriate transducers designed for their operation in air.This paper presents an easy way to integrate air-coupled piezoelectric transducers in conventional ultrasonic NDE equipment. The design of a specific front-end electronics by using an ultra-low noise amplifier enables existing inspection systems to be used for the dry-coupled ultrasonic test of materials and structures. The amplifier provides the receiver with a signal-to-noise ratio large enough for good quality signal processing and imaging. System dynamic ranges of more than 100 dB are achieved.