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排序方式: 共有281条查询结果,搜索用时 16 毫秒
1.
Jonas Maximilian Müller Nicolas Rozo Lopez Enzo Alexander Klein Christian Hopmann 《Polymer Engineering and Science》2020,60(6):1324-1332
For fiber-reinforced plastics, the strain-rate dependent response is governed by the matrix behavior. In this work, the Goldberg model is considered for the epoxy matrix constitutive material model. Moreover, the strain-rate dependency is achieved by direct influence on the elastic modulus, the inelastic strain, and the material strain to failure. In addition, an anisotropic damage response is implemented and extended through a strain-rate dependent definition. Since the constitutive model relies on nonphysical parameters, a parameter study is further performed. Additional numerical investigations using a micro-mechanical model are performed. Tension and shear loading conditions are evaluated and the influence of different strain rates is explored. Furthermore, the implemented anisotropic damage model is compared and discussed against an isotropic damage model. 相似文献
2.
Silvia Tabasso Silvia Berto Roberta Rosato Janeth Alicia Tafur Marinos Marco Ginepro Vincenzo Zelano Pier Giuseppe Daniele Enzo Montoneri 《International journal of molecular sciences》2015,16(2):3405-3418
This work reports a study of the proton-binding capacity of biopolymers obtained from different materials supplied by a municipal biowaste treatment plant located in Northern Italy. One material was the anaerobic fermentation digestate of the urban wastes organic humid fraction. The others were the compost of home and public gardening residues and the compost of the mix of the above residues, digestate and sewage sludge. These materials were hydrolyzed under alkaline conditions to yield the biopolymers by saponification. The biopolymers were characterized by 13C NMR spectroscopy, elemental analysis and potentiometric titration. The titration data were elaborated to attain chemical models for interpretation of the proton-binding capacity of the biopolymers obtaining the acidic sites concentrations and their protonation constants. The results obtained with the models and by NMR spectroscopy were elaborated together in order to better characterize the nature of the macromolecules. The chemical nature of the biopolymers was found dependent upon the nature of the sourcing materials. 相似文献
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Enzo Mangano Daniel Friedrich Stefano Brandani 《American Institute of Chemical Engineers》2015,61(3):981-991
The ideal adsorbed solution (IAS) theory has been shown to predict reliably multicomponent adsorption for both gas and liquid systems. There is a lack of understanding of the conditions which guarantee convergence for various algorithms used to solve the IAS theory equations and inconsistencies are present in the reported computational effort required for the different approaches. The original nested loop and the FastIAS technique are revisited. The resulting system of equations is highly nonlinear but both methods are shown to be robust if appropriate choices are made for the starting values of the unknown variables. New initial conditions are proposed and the resulting algorithms are compared in a consistent manner with the main methods available to solve the IAS theory equations. The algorithms are extended for the first time to all nontype I isotherms. © 2014 American Institute of Chemical Engineers AIChE J, 61: 981–991, 2015 相似文献
5.
Kuwanon‐L as a New Allosteric HIV‐1 Integrase Inhibitor: Molecular Modeling and Biological Evaluation 下载免费PDF全文
Dr. Francesca Esposito Dr. Cristina Tintori Dr. Riccardo Martini Dr. Frauke Christ Prof. Zeger Debyser Roberto Ferrarese Dr. Gianluigi Cabiddu Dr. Angela Corona Dr. Elisa Rita Ceresola Dr. Andrea Calcaterra Dr. Valentina Iovine Prof. Bruno Botta Dr. Massimo Clementi Dr. Filippo Canducci Prof. Maurizio Botta Prof. Enzo Tramontano 《Chembiochem : a European journal of chemical biology》2015,16(17):2507-2512
HIV‐1 integrase (IN) active site inhibitors are the latest class of drugs approved for HIV treatment. The selection of IN strand‐transfer drug‐resistant HIV strains in patients supports the development of new agents that are active as allosteric IN inhibitors. Here, a docking‐based virtual screening has been applied to a small library of natural ligands to identify new allosteric IN inhibitors that target the sucrose binding pocket. From theoretical studies, kuwanon‐L emerged as the most promising binder and was thus selected for biological studies. Biochemical studies showed that kuwanon‐L is able to inhibit the HIV‐1 IN catalytic activity in the absence and in the presence of LEDGF/p75 protein, the IN dimerization, and the IN/LEDGF binding. Kuwanon‐L also inhibited HIV‐1 replication in cell cultures. Overall, docking and biochemical results suggest that kuwanon‐L binds to an allosteric binding pocket and can be considered an attractive lead for the development of new allosteric IN antiviral agents. 相似文献
6.
Writing and Functionalisation of Suspended DNA Nanowires on Superhydrophobic Pillar Arrays 下载免费PDF全文
Ermanno Miele Angelo Accardo Andrea Falqui Monica Marini Andrea Giugni Marco Leoncini Francesco De Angelis Roman Krahne Enzo Di Fabrizio 《Small (Weinheim an der Bergstrasse, Germany)》2015,11(1):134-140
Nanowire arrays and networks with precisely controlled patterns are very interesting for innovative device concepts in mesoscopic physics. In particular, DNA templates have proven to be versatile for the fabrication of complex structures that obtained functionality via combinations with other materials, for example by functionalisation with molecules or nanoparticles, or by coating with metals. Here, the controlled motion of the a three‐phase contact line (TCL) of DNA‐loaded drops on superhydrophobic substrates is used to fabricate suspended nanowire arrays. In particular, the deposition of DNA wires is imaged in situ, and different patterns are obtained on hexagonal pillar arrays by controlling the TCL velocity and direction. Robust conductive wires and networks are achieved by coating the wires with a thin layer of gold, and as proof of concept conductivity measurements are performed on single suspended wires. The plastic material of the superhydrophobic pillars ensures electrical isolation from the substrate. The more general versatility of these suspended nanowire networks as functional templates is outlined by fabricating hybrid organic–metal–semiconductor nanowires by growing ZnO nanocrystals onto the metal‐coated nanowires. 相似文献
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In this paper, we develop the optimal minimum-energy scheduler for the dynamic online joint allocation of the task sizes, computing rates, communication rates and communication powers in virtualized Networked Data Centers (NetDCs) that operates under hard per-job delay-constraints. The referred NetDC’s infrastructure is composed by multiple frequency-scalable Virtual Machines (VMs), that are interconnected by a bandwidth and power-limited switched Local Area Network (LAN). Due to the nonlinear power-vs.-communication rate relationship, the resulting Computing-Communication Optimization Problem (CCOP) is inherently nonconvex. In order to analytically compute the exact solution of the CCOP, we develop a solving approach that relies on the following two main steps: (i) we prove that the CCOP retains a loosely coupled structure, that allows us to perform the lossless decomposition of the CCOP into the cascade of two simpler sub-problems; and, (ii) we prove that the coupling between the aforementioned sub-problems is provided by a (scalar) constraint, that is linear in the offered workload. The resulting optimal scheduler is amenable of scalable and distributed online implementation and its analytical characterization is in closed-form. After numerically testing its actual performance under randomly time-varying synthetically generated and real-world measured workload traces, we compare the obtained performance with the corresponding ones of some state-of-the-art static and sequential schedulers. 相似文献
9.
Ecofriendly manure anaerobic digestion assisted by soluble bio‐based substances obtained from anaerobic digestion,composting and chemical hydrolysis of urban bio‐wastes. A step toward the integration of urban and agriculture waste management 下载免费PDF全文
10.
Enzo Castellan Gloria Ischia Alberto Molinari Rishi Raj 《Metallurgical and Materials Transactions A》2013,44(10):4734-4742
We apply an in situ approach, whereby a polymer is incorporated into copper and evolves within the metal into the ceramic phase, to create a dispersion of hard particles in a metal. All constituents for the ceramic phase are contained within the organic polymer. The temperature for this polymer to ceramic conversion lies in the 1073 K to 1273 K (800 °C to 1000 °C) range. The process produces a nanoscale dispersion of the ceramic, which leads to high microhardness that remains unaltered at temperatures up to 1223 K (950 °C) (0.9T M). Apparently, the introduction of the ceramic phase leads to the retention of copper crystallite size of a few hundred nm, despite exposure to heat treatments at these very high temperatures. We call these materials polymer-derived metal-matrix composites. 相似文献