Comparison of 80-keV D+ Ion Implantation with Thermal D2 Doping in Silica by FTIR and ESR Spectroscopy

Behavior of deuterium atoms in fused silica, which were implanted by 80-keV D⁺ (D₂⁺, D₃⁺) ions or doped thermally by D₂ (or D₂O), was studied by infrared Fourier transform spectroscopy (FTIR) and by ESR spectroscopy. When 80-keV deuteron ions are implanted into fused silica, OD bonds are formed. The OD bonds are also formed by thermal doping with D₂ or D₂O. When the deuterated silica is γ-ray irradiated at 77 K, D atoms are formed by rupture of the OD bonds. The efficiency of the OD bond rupture in the deuteron-implanted silica is much less than that in the D₂-doped silica. It is concluded from the results of thermal annealing that the low efficiency of the OD bond rupture in the deuteron-implanted silica is due to the radiation damage accompanying the implantation process. However, the decay rate and detrapping energy of deuterium atoms, once formed in the silica, are similar in both cases.     

OSAKA CITY'S EARTHQUAKE PREPAREDNESS IMPROVEMENT MEASURES

In the early morning of January 17, 1995, an earthquake of magnitude 7.2 occurred, with its epicenter in Awaji Island, to the south of Kobe City located near Osaka City. It was later named the Hanshin-Awaji Earthquake.

The earthquake left over 6,400 people dead and about 40,000 injured, completely destroying over 100,000 houses and buildings, causing about 300 fires, resulting in the suspension of such “lifelines” as city water, electricity, and gas supply, and halting transportation systems including road and railway traffic. It inflicted extensive damage not only on Kobe, but also on Osaka and other cities.

In the light of destruction caused by the earthquake, in 1997, the Osaka Municipal Government, the Osaka City Regional Preparedness Plan, which includes citizen evacuation in the event of earthquake, construction of seismic-resistant facilities, and fire-fighting and other emergency activities. The original plan was prepared, on the basis of an inter-plate earthquake occurring beneath the Pacific Ocean. In addition to this hypothesis, the new plan also incorporates the assumption that an earthquake with its epicenter under Osaka could occur due to movement of the Uemachi Faults running under the central part of the City in the north-south direction. Estimated damage that could be incurred through this potential earthquake were used for the latter plan.     

Effect of Maillard Reaction on Some Physical Properties of Ovalbumin

Ovalbumin freeze-dried with or without the addition of glucose was stored at 50°C and 65% relative humidity to study the effect of the Maillard reaction on some physical properties of ovalbumin. In the early stage of the reaction in which ovalbumin-glucose complexes were formed, there were soluble types of monomer and aggregates of which α-helix and available lysine contents were gradually decreased with length of storage and degree of aggregation. These compounds were characterized by properties possessing a marked resistance towards destruction of conformation and coagulation. With progress of the reaction, ovalbumin-glucose complexes changed to insoluble forms having higher particle weight and breakdown products.     

Distributed parameter identification by regularization and its application to prediction of air pollution

An identification algorithm is considered for unknown spatially varying diffusivities in the diffusion equation by using the regularization method. The diffusion equation is expressed by a parabolic partial differential equation and the identification for the system possesses ill-posedness. To solve this problem we use the regularization method which was proposed by Kravaris (1984) and Kravaris and Seinfeld (1985). The diffusivities for air pollution problems are identified under the assumption that the diffusivities are affected by the wind velocity, Using this algorithm, the NO, concentrations caused by motor vehicles near a roadway in Tokushima, Japan are estimated.     

Solution to the inverse regulator problem for discrete-time systems

A complete solution is given for the inverse problem of LQ optimal regulators for the discrete-time multi-input case. The Kalman equation for discrete-time systems is derived to characterize the optimal regulators. It is then shown that this equation holds for some quadratic weighting if and only if the feedback satisfies a condition corresponding to the circle criterion for continuous-time systems. The optimality criterion given here consists of this condition and an additional condition to ensure detectability. An example is given to illustrate the results.     

Selective O–H Bond Cleavage in the Radiolysis of Quartz

Cleavage of the O–H bond in quartz was studied by Fourier transform infrared spectroscopy and ESR spectroscopy. When quartz single crystals and fused silica glass are γ-irradiated at 77 K, hydrogen atoms are produced by rupture of O–H bonds. The initial efficiency of O–H bond cleavage in quartz single crystals, i.e. the initial yield of H atoms, was three times as great as that in fused silica glass, although the concentration of O–H bonds in quartz single crystals (70 ppm) is much lower than that in fused silica glass (4000 ppm). The efficiency of O–H bond cleavage in quartz single crystals indicates that energy transfer from the irradiated single crystal to the O–H bonds takes place effectively at 77 K. The efficiency of O–H bond cleavage decreases with increasing γ-ray dose, i.e. with increasing amounts of radiation-induced defects in quartz single crystals. When the radiation-induced defects are removed by annealing the irradiated quartz single crystal at 773 K, the O–H bonds are ruptured again as effectively as for a fresh quartz single crystal. The distance of the energy transfer, estimated by a target model, is ∼15 nm.     

Novel Measurement of Hypoxanthine in Fish Using Direct Measurement Probe and Chemiluminescence Flow Injection Analysis

Direct measurements of hypoxanthine (Hx) in fish flesh were carried out using a sardine and a grunt twice with the same fish, and the average of 10 successive measurements (from 120 sec to 480 sec after pressing the probe against fish tissue) was taken as the Hx concentration by direct measurement. Results with two nearby tissues of one sample were 42.9 ± 4.9 μM and 42.6 ± 2.6 μM for the sardine, and 639 ± 33 μM and 598 ± 29 μM for the grunt. For sardine, Hx results from this direct method did not agree well with perchloric acid extraction measurements, but they were much better for grunt.     

Testing Composite Hypotheses for Locally Stationary Processes

For a class of locally stationary processes introduced by Dahlhaus, this paper discusses the problem of testing composite hypotheses. First, for the Gaussian likelihood ratio test (GLR), Wald test (W) and Lagrange multiplier test (LM), we derive the limiting distribution under a composite hypothesis in parametric form. It is shown that the distribution of GLR, W and LM tends to a χ² distribution under the hypothesis. We also evaluate their local powers under a sequence of local alternatives, and discuss their asymptotic optimality. The results can be applied to testing for stationarity. Some examples are given. They illuminate the local power property via simulation. On the other hand, we provide a nonparametric LAN theorem. Based on this result, we obtain the limiting distribution of the GLR under both null and alternative hypotheses described in nonparametric form. Finally, the numerical studies are given.     

Kinetic Behavior of H and D Atoms in γ-Irradiated SiO2 as Studied by ESR Spectroscopy

The decay of hydrogen atoms, produced by γ irradiation of fused silica and quartz, was studied by ESR spectroscopy. The decay of H atoms in silica cannot be explained by a secondorder kinetics nor by a simple first-order kinetics. Also, the decay is not composed of several first-order processes with different activation energies. The data for the decay of H atoms can be described by a first-order kinetic equation with a timedependent rate constant of the form k(t) = Bt ^α−1, where B and α are constants. The decay kinetics of D atoms in deuterated fused silica and H atoms in a single crystal of quartz are also explained by use of the time-dependent rate constant. The apparent activation energies for the decay of H and D atoms in the silica are 15 to 16 kJ/mol and 14 to 15 kJ/mol, respectively. The decay rates for D and H atoms in the silica are similar.