Incoherent transport in NEMO5: realistic and efficient scattering on phonons

In this work, the coherent and incoherent transport simulation capabilities of the multipurpose nanodevice simulation tool NEMO5 are presented and applied on transport in tunneling field-effect transistors. The comparison with experimental resistivity data confirms the validity of NEMO5’s phonon-scattering models. Common pitfalls of numerical implementations and the applicability of common approximations of scattering self-energies are discussed. The impact of phonon-assisted tunneling on the performance of TFETs is exemplified with a concrete Si nanowire device. The communication-efficient implementation of self-energies in NEMO5 is demonstrated with a scaling comparison of self-energies solved with blocking and nonblocking MPI-communication.     

On the quality of VoIP with DCCP for satellite communications

We present experimental results for the performance of selected voice codecs using Datagram Congestion Control Protocol (DCCP) with CCID4 congestion control over a satellite link. We evaluate the performance of both constant and variable data rate speech codecs for a number of simultaneous calls using the ITU E‐model. We analyse the sources of packet losses and additionally analyse the effect of jitter, which is one of the crucial parameters contributing to Voice over IP (VoIP) quality and has, to the best of our knowledge, not been considered previously in the published DCCP performance results. We propose modifications to the CCID4 algorithm and demonstrate how these improve the VoIP performance, without the need for additional link information other than what is already monitored by CCID4. We also demonstrate the fairness of the proposed modifications to other flows. Although the recently adopted changes to TCP‐Friendly Rate Control specification alleviate some of the performance issues for VoIP on satellite links, we argue that the characteristics of commercial satellite links necessitate consideration of further improvements. We identify the additional benefit of DCCP when used in VoIP admission control mechanisms and draw conclusions about the advantages and disadvantages of the proposed DCCP/CCID4 congestion control mechanism for use with VoIP applications. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of Alkyl Chain Length on Thermal Properties,Structure, and Self-Diffusion Coefficients of Alkyltriethylammonium-Based Ionic Liquids

The application of ionic liquids (ILs) has grown enormously, from their use as simple solvents, catalysts, media in separation science, or electrolytes to that as task-specific, tunable molecular machines with appropriate properties. A thorough understanding of these properties and structure–property relationships is needed to fully exploit their potential, open new directions in IL-based research and, finally, properly implement the appropriate applications. In this work, we investigated the structure–properties relationships of a series of alkyltriethylammonium bis(trifluoromethanesulfonyl)imide [TEA-R][TFSI] ionic liquids in relation to their thermal behavior, structure organization, and self-diffusion coefficients in the bulk state using DSC, FT-IR, SAXS, and NMR diffusometry techniques. The phase transition temperatures were determined, indicating alkyl chain dependency. Fourier-transformed infrared spectroscopy studies revealed the structuration of the ionic liquids along with alkyl chain elongation. SAXS experiments clearly demonstrated the existence of polar/non-polar domains. The alkyl chain length influenced the expansion of the non-polar domains, leading to the expansion between cation heads in polar regions of the structured IL. ¹H NMR self-diffusion coefficients indicated that alkyl chain elongation generally caused the lowering of the self-diffusion coefficients. Moreover, we show that the diffusion of anions and cations of ILs is similar, even though they vary in their size.     

Scalable Nanowire Photonic Crystals: Molding the Light Emission of InGaN

To date, there have been no efficient semiconductor light emitters operating in the green and amber wavelengths. This study reports on the synthesis of InGaN nanowire photonic crystals, including dot‐in‐nanowires, nanotriangles, and nanorectangles with precisely controlled size, spacing, and morphology, and further demonstrates that bottom‐up InGaN photonic crystals can exhibit highly efficient and stable emission. The formation of stable and scalable band edge modes in defect‐free InGaN nanowire photonic crystals is directly measured by cathodoluminescence studies. The luminescence emission, in terms of both the peak position (λ ≈ 505 nm) and spectral linewidths (full‐width‐half‐maximum ≈ 12 nm), remains virtually invariant in the temperature range of 5–300 K and under excitation densities of 29 W cm^?2 to 17.5 kW cm^?2. To the best of our knowledge, this is the first demonstration of the absence of Varshni and quantum‐confined Stark effects in wurtzite InGaN light emitters—factors that contribute significantly to the efficiency droop and device instability under high‐power operation. Such distinct emission properties of InGaN photonic crystals stem directly from the strong Purcell effect, due to efficient coupling of the spontaneous emission to the highly stable and scalable band‐edge modes of InGaN photonic crystals, and are ideally suited for uncooled, high‐efficiency light‐emitting‐diode operation.     

Plasmonic photothermal therapy of colon cancer cells utilising gold nanoshells: an in vitro study

In this study, gold nanoshell (GNS) were synthesised utilising the Halas method. The obtained nanoparticles (NPs) were characterised by Fourier‐transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis spectroscopy and dynamic light scattering. FTIR spectra demonstrated the successful functionalisation of silica NP with 3‐aminopropyl trimethoxysilane. SEM and TEM images showed the morphology and diameter of the synthesised silica NPs (137 ± 26 nm) and GNS. UV–Vis spectrum illustrated the maximum absorbance of the resultant GNS and their average hydrodynamic diameter was 159 nm. For in vitro study, HCT‐116 cells were exposed to gold nanoshells and intense pulsed light in different experiment groups. The results showed that exposing the cells to nanoshells and 30 s irradiation would efficiently decrease the viability percentage of the cells to about 30% compared with the control. A continued exposure of 4 min decreased the viability of the cancer cells to 20%. The results demonstrated that photothermal therapy would be promising in treatment of colon cancer cells utilising gold nanoshells.Inspec keywords: gold, silicon compounds, nanomedicine, plasmonics, radiation therapy, bio‐optics, cancer, cellular biophysics, nanoparticles, Fourier transform spectra, infrared spectra, scanning electron microscopy, transmission electron microscopy, ultraviolet spectra, visible spectraOther keywords: plasmonic photothermal therapy, colon cancer cells, gold‐silica nanoshells, GNS, Halas method, Fourier transform infrared spectroscopy, FTIR, scanning electron microscopy, SEM, transmission electron microscopy, TEM, UV‐vis spectroscopy, dynamic light scattering, FTIR spectra, 3‐aminopropyl trimethoxysilane, morphology, in vitro study, HCT‐116 cells, cell viability, nanoparticles, time 30 s, time 4 min, Au     

Correlated Dynamics in Ionic Liquids by Means of NMR Relaxometry: Butyltriethylammonium bis(Trifluoromethanesulfonyl)imide as an Example

¹H and ¹⁹F spin-lattice relaxation experiments have been performed for butyltriethylammonium bis(trifluoromethanesulfonyl)imide in the temperature range from 258 to 298 K and the frequency range from 10 kHz to 10 MHz. The results have thoroughly been analysed in terms of a relaxation model taking into account relaxation pathways associated with ¹H–¹H, ¹⁹F–¹⁹F and ¹H–¹⁹F dipole–dipole interactions, rendering relative translational diffusion coefficients for the pairs of ions: cation–cation, anion–anion and cation–anion, as well as the rotational correlation time of the cation. The relevance of the ¹H–¹⁹F relaxation contribution to the ¹H and ¹⁹F relaxation has been demonstrated. A comparison of the diffusion coefficients has revealed correlation effects in the relative cation–anion translational movement. It has also turned out that the translational movement of the anions is faster than of cations, especially at high temperatures. Moreover, the relative cation–cation diffusion coefficients have been compared with self-diffusion coefficients obtained by means of NMR (Nuclear Magnetic Resonance) gradient diffusometry. The comparison indicates correlation effects in the relative cation–cation translational dynamics—the effects become more pronounced with decreasing temperature.     

Privacy in targeted advertising on mobile devices: a survey

Targeted advertising has transformed the marketing landscape for a wide variety of businesses, by creating new opportunities for advertisers to reach prospective customers by delivering personalised ads, using an infrastructure of a number of intermediary entities and technologies. The advertising and analytics companies collect, aggregate, process, and trade a vast amount of users’ personal data, which has prompted serious privacy concerns among both individuals and organisations. This article presents a comprehensive survey of the privacy risks and proposed solutions for targeted advertising in a mobile environment. We outline details of the information flow between the advertising platform and ad/analytics networks, the profiling process, the measurement analysis of targeted advertising based on user’s interests and profiling context, and the ads delivery process, for both in-app and in-browser targeted ads; we also include an overview of data sharing and tracking technologies. We discuss challenges in preserving the mobile user’s privacy that include threats related to private information extraction and exchange among various advertising entities, privacy threats from third-party tracking, re-identification of private information and associated privacy risks. Subsequently, we present various techniques for preserving user privacy and a comprehensive analysis of the proposals based on such techniques; we compare the proposals based on the underlying architectures, privacy mechanisms, and deployment scenarios. Finally, we discuss the potential research challenges and open research issues.