Uranium measurements using laser-induced breakdown spectroscopy in lithium chloride-potassium chloride salt of pyroprocessing

In pyroprocessing,uranium(U) is recovered from molten LiCl-KCl salt,and,for safeguard purposes,it is important to analyze the U and Plutonium(Pu) concentrations in a timely manner.In the present work,salt samples containing U were fabricated.The laser used in the present work was an Nd:YAG laser with a wavelength of 532 nm,a laser energy on the sample of11.5 mJ,and a pulse repetition rate of 10 Hz.The plasma emission light was measured with an Echelle spectrometer.A total of 100 points on the sample surface were measured as the laser incident position was changed.The U and potassium(K) peaks in the spectrum were identified.Univariate and multivariate analyzes were conducted to determine the accuracy and limit of detection(LOD) of the laser-induced breakdown spectroscopy.     

Simple reactor for the synthesis of silver nanoparticles with the assistance of ethanol by gas–liquid discharge plasma

Atmospheric pressure plasma technology is gaining increasing importance because it is a simple and tunable synthesis process for the production of metallic nanoparticles. In addition to the development of the power supply, improving the reactor is also one of the main strategies to enhance the utility. In this study, a simple reactor for the gas–liquid discharge plasma induced by argon gas was applied to synthesize silver nanoparticles from silver nitrate (AgNO₃) in solution. An AC power supply with a peak voltage of 3.5 kV was used. The frequency and on-time were set to 50 kHz and 2.5 μs, respectively. The oscilloscope showed that the rising time was approximately 2 μs. The ethanol was used as the source for the reactive reducing agent. No more additional components existed in the solution during the discharge and neither of the electrodes was in contact with the treated solution. The temperature increased by 10 °C within 1min without a cooling system. Carbon was the main impurity and was expected to be produced from the decomposition of the organics under the plasma. The elevated temperature decreased the organic by-products by evaporation and could also decrease the production of carbon. Transmission electron microscopy showed that the spherical silver nanoparticles with a size of approximately 10 nm were synthesized with a crystal structure and that a low concentration of ethanol prefers the production of the mono-dispersed colloid.     

从日、韩低碳型生态城市探讨相关生态城规划实践

随着全球对气候变化和生态环境的重视,最近国内外的城市发展政策都将焦点集中到低碳生态城市的规划建设上.于是,实现现有城市发展模式向低碳生态城市空间结构的转变就成为城市领域共同探讨的新课题.目前,我国正在积极与新加坡和欧洲国家共同对生态城规划建设进行实践研究,在此背景下,首先对生态规划建设起步较早的日本和韩国的典型低碳型生态城市进行案例分析,然后利用归纳总结的规划要素构想出适合低碳生态城市建设的紧凑型城市空间结构,最后针对中新天津生态城与日本和韩国的低碳生态城市比较分析中得出的问题提出相应的改善建议.     

Optimal number of minor failures before replacement

This paper extends a replacement model based on failure number to include a repair-cost limit for general failure distributions. The stochastic behaviour of failures and repair costs are modelled by a non-homogeneous Poisson process. An efficient marginal analysis algorithm is presented for finding the optimal failure number for replacement that minimizes the average cost rate.     

A Modification of the Coates Gain Formula for the Analysis of Linear Systems

In this paper, the Coates flow-graph gain formula is modified by the introduction of the loop-set and the two-loop-set, baaed on the concepts of the tree and the two-tree in network topology. The analogy is evident by observing that the two-trees T _ij of a given graph G can be obtained by coalescing vertices i and j of G and thon removing the self-loops. In a similar manner, the two-loop-sets can be obtained from the flow graph by first modifying the graph and then obtaining the loop-sets of tho modified graph. Because of such modification, the derivation of tho gain formula is considerably simplified. Consequently, the evaluation of the terms in the formula becomes easier. Finally, a simple method of determining the number of terms in the formula is derived as a check against possible omission of terms due to carelessness.     

Design of class-based storage racks for minimizing travel time in a three-dimensional storage system

This paper deals with a new storage structure layout method called ‘cubic-in-time’, for minimizing the travel time of selected handling equipment in a three-dimensional palletized storage system. Storage-system design algorithms for minimizing travel times are described, the results are analysed, and some general conclusions are drawn.     

Optimal control of economic growth with application to Korean economy

This paper is concerned with the application of optimal control theory to the dual growth of the Korean economy. A closed two sector economic growth model is formulated by dividing the economy into agriculture and non-agriculture in order to represent the transitional phenomena between the two sectors. Taking capital and saving as state and control variables, respectively, the model governing the economic growth becomes a non-linear simultaneous differential equations with coupling terms of state and control variables. Assuming the Cobb-Douglas production function and the exponential form of the social welfare function, the necessary and sufficient conditions of the optimal control have been derived for the case of finite planning horizon by using the Pontryagin's maximum principle. Since deriving the optimal trajectories of state and control variables analytically is impossible, a numerical procedure based on the variation of extremals is used to obtain the optimal paths of the aggregate investment and consumption of the Korean economy.     

Fabrication of cast carbon steel with ultrafine TiC particles

The carbon steels dispersed with ultrafine TiC particles were fabricated by conventional casting method. The casting process is more economical than other available routes for metal matrix composite production, and the large sized components to be fabricated in short processing time. However, it is extremely difficult to obtain uniform dispersion of ultrafine ceramic particles in liquid metals due to the poor wettability and the specific gravity difference between the ceramic particle and metal matrix. In order to solve these problems, the mechanical milling (MM) and surface-active processes were introduced. As a result, Cu coated ultrafine TiC powders made by MM process using high energy ball milling machine were mixed with Sn powders as a surfactant to get better wettability by lowering the surface tension of carbon steel melt. The microstructural investigations by OM show that ultrafine TiC particles are distributed uniformly in carbon steel matrix. The grain sizes of the cast matrix with ultrafine TiC particles are much smaller than those without ultrafine TiC particles. This is probably due to the fact that TiC particles act as nucleation sites during solidification. The wear resistance of cast carbon steel composites added with MMed TiC/Cu-Sn powders is improved due to grain size refinement.     

Evaluation of microstructure and mechanical properties of Mg-xCe-0.5Zn alloys by nano-indentation

The microstructure and mechanical properties of Mg-xCe-0.5Zn(x=0.5,1.5,2.5,molar fraction,%) alloys were examined using a nano-indentation technique.The alloys were fabricated using a vacuum induction melting method under an argon atmosphere. The microstructures of Mg-xCe-0.5Zn alloys mainly consist ofα-Mg and eutectic Mg12Ce phase.The volume fraction and size of the eutectic Mg12Ce phase increase with increasing Ce contents.Nano-indentation test results show that the indentation hardness and elastic modulus of the eutectic Mg12Ce phase are higher than those of theα-Mg matrix.In addition,the mean indentation hardness and elastic modulus of the Mg-xCe-0.5Zn alloys increase with the Ce addition amount increasing.