树枝状聚丙烯亚胺氰端基的催化还原研究

研究了几类常用催化剂在催化氢化低代数氰端基树枝状聚丙烯基亚胺(PPI)的催化性能。漆原钴的催化选择性好，催化氢化过程中发生的副反应较少，还原产物1．0G PPI的产率为95％，伯胺值高达90％，比用Raney Ni催化氢化生成的产物的伯胺值提高了约10％。     

基于声学测温技术的电站锅炉水冷壁灰污监测方法

用声学高温计直接测量炉膛出口烟温,通过计算得到炉膛清洁因子,实现炉膛整体灰污监测。分析了水冷壁结渣厚度与渣层表面温度的关系,提出以炉膛平均温度为基准,沿炉膛高度布置声学测点监测水冷壁向火侧表面温度,选择动态灰污特征参数,实现了炉膛局部结渣在线监测。     

600MW直冷机组空冷凝汽器冷却管束污垢热阻对热经济性的影响

直接空冷汽轮机组(直冷机组)运行一段时问后,其空冷凝汽器(空凝器)冷却管束内、外污垢热阻对机组热经济性有明显影响.以600 MW直冷机组为例,限定空凝器冷却管内、外污垢热阻均在0～001(m2·K)/W范围内变化,用η(效率)-NTU(传热单元数)法建立直冷机组排汽压力的冷却管内、外污垢热阻特性数学模型,并编程计算绘制出特性曲线,分析了直冷机组空凝器冷却管污垢热阻以及迎风面风速和环境温度对排汽压力的影响.     

300MW直接空冷机组变工况特性

以300MW直接空冷机组为例，考虑了排汽管道的压损，排汽口至空冷凝汽器入口间水蒸汽柱高度压力及排汽管对环境散热量，建立直接空冷机组冷端系统变工况数学模型，编程计算做出直接空冷机组冷端系统特性曲线，同时分析了空冷凝汽器压力及管道压损的变工况特性。计算验证了排汽热负荷、排汽管道压损、迎面风速和环境温度是影响直接空冷机组排汽压力的主要因素，且在迎面风速和环境温度一定时，排汽管道压损在热负荷范围内存在一最不利最大值，对于空冷机组的管道设计及经济运行提供参考。     

Design and Fabrication of Drug Delivery Devices with Complex Architectures Based on Three-dimensional Printing Technique

1Introduction Drugdeliverydevices(DDD)playanimportantrole incontrollingthedrugreleaseinadesignedmanner[1].AsanimportantkindofDDD,theimplantableDDDmay beusedtotreatsomedeceases,suchasdiabetes,antibi oticadministration,immunization,andtheboneinfectio ns[2].…     

半纤维素菌株发酵液中单糖及二糖的分析

采用高效液相色谱（HPLC）定量分析了半纤维素发酵液中的单糖及二糖，在Spherisorb NH2柱上用乙腈－水（体积比82：20）为流动相分离，示差析光检测器检测，10min内同时分离并定量测定了六种糖，六种糖的相对偏差均小于2．18％，并从理论上分析了糖的极性与保留时间的关系。     

半纤维素菌株发酵液中单糖及二糖的分析

采用高效液相色谱(HPLC)定量分析了半纤维素发酵液中的单糖及二糖.在Spherisorb NH2柱上用乙腈-水(体积比82∶20)为流动相分离,示差析光检测器检测,10 min内同时分离并定量测定了六种糖.六种糖的相对偏差均小于2.18%.并从理论上分析了糖的极性与保留时间的关系.     

载三氧化二砷的PEG—PLGA隐性纳米粒的制备及体外研究

The aim of this study was to prepare arsenic trioxide （ATO）-loaded stealth PEGylated PLGA nanoparticles （PEG-PLGA-NPs） and to assess the merits of PEG-PLGA-NPs as drug carriers for ATO delivery. PEG-PLGA copolymer was synthesized with methoxypolyethyleneglycol （Mw=5000）, D, L-lactide, and glycolide by the ring-opening polymerization method. Amorphous ATO was transformed into cubic crystal form to increase its solu-bility in the organic solvent. ATO-loaded PEG-PLGA-NPs were prepared by the modified spontaneous emulsification solvent diffusion （SESD） method, and the main experimental factors influencing the characteristics of nanopar- ticles were investigated, to optimize the preparation. To confirm the escape of PEG-PLGA-NPs from phagocytosis by phagocytes, PEG-PLGA-NPs labeled rhodamine B uptake by murine peritoneal macrophages （MPM） were analyzed by flow cytometry. The results showed that the physicochemical characteristics of PEG-PLGA-NPs were affected by the type and concentration of the emulsifiers, polymer concentration, and drug concentration. ATO-loaded PEG-PLGA-NPs, with particle size of 120.8nm, zeta potential of-10.73mV, encapsulation efficiency of 73.6%, and drug loading of 1.36%, were prepared under optimal conditions. The images of transmission electron micros-copy （TEM） indicated that the optimized nanoparticles were near spherical and without aggregation or adhesion. The release experiments in vitro showed the ATO release from PEG-PLGA-NPs exhibited consequently sustained release for more than 26d, which was in accordance with Higuchi equation. The uptake of PEG-PLGA-NPs by MPM was found to decrease markedly compared to PLGA-NPs. The experimental results showed that PEG-PLGA-NPs were potential nano drug delivery carriers for ATO.     

单路径声学高温计实时监测锅炉炉膛烟温的试验研究

为了实现炉膛出口烟气温度的实时在线监测,在前期工作的基础上研发了单路径声学高温计,并首次在国内某300 MW电站锅炉中安装.经过冷态调试、热态试验和长期运行,验证了单路径声学测温系统的稳定性和可靠性.利用特制的K型铠装热电偶对声学高温计进行了标定,结果表明:声学高温计测温与热电偶测温相比,误差在2%以内;声学测温历史曲线与机组负荷历史曲线的变化趋势吻合,说明声学高温计可以完全取代炉膛烟温探针.     

高效液相色谱同时分析测定南瓜中的单糖

采用HPLC定量分析南瓜中的单糖。在Spherisorb NH2柱上用乙腈-水（85:15）为流动相分离，示差折光检测，8min内同时分离并定量测定了五种单糖。糖的相对偏差小于2.20%。