Investigation on jet stability,fiber diameter,and tensile properties of electrospun polyacrylonitrile nanofibrous yarns

Electrospinning is a flexible and efficient method for producing nanofibers by using relatively dilute polymer solution. However, there are many parameters related to material and processing that influence the morphology and property of the nanofibers. This study investigates the influence of electric field and flow rate on diameter and tensile properties of nanofibers produced using polyacrylonitrile (PAN)‐dimethylformamide (DMF) solution. Stability of the spinning jet is investigated via fiber current measurement and an image system at different electric fields and solution flow rates. It is observed that a set of electric field and flow rate conditions favor producing thinnest, strongest, and toughest nanofibers during electrospinning process. Other conditions may lead to instability of the Taylor cone, discontinuous jet, larger diameter fiber, and lower mechanical properties. Finally, a simple dynamic whipping model is adopted to correlate the nanofiber diameter with volumetric charge density and is found to be excellent validating our experimental results. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41918.     

Obtaining expert advice [filter synthesis]

Unlike other filter-synthesis design tools, EXSHOF employs knowledge-based synthesis of a high-order active filter. The package is completely menu driven and extremely user friendly. At the various stages of filter design it asks questions of the user and provides guidelines to these questions; i.e., it gives expert help in making decisions. It assumes that the user has little knowledge of computers and filters. Users have the option of using any of the five approximation functions or directly inputting the transfer function. It can design four types of different high-order filter structures and nine different biquad circuits. The detailed diagram of the designed circuit is presented to the user in a modular form using graphics. The frequency response of the circuit has been simulated using PSpice and it has been found that the response exactly matches the input specifications     

The magnitude of arsenic contamination in groundwater and its health effects to the inhabitants of the Jalangi--one of the 85 arsenic affected blocks in West Bengal, India

To better understand the magnitude of arsenic contamination in groundwater and its effects on human beings, a detailed study was carried out in Jalangi, one of the 85 arsenic affected blocks in West Bengal, India. Jalangi block is approximately 122 km2 in size and has a population of 215538. Of the 1916 water samples analyzed (about 31% of the total hand tubewells) from the Jalangi block, 77.8% were found to have arsenic above 10 microg l(-1) [the World Health Organization (WHO)-recommended level of arsenic in drinking water], 51% had arsenic above 50 microg l(-1) (the Indian standard of permissible limit of arsenic in drinking water) and 17% had arsenic at above 300 microg l(-1) (the concentration predicting overt arsenical skin lesions). From our preliminary medical screening, 1488 of the 7221 people examined in the 44 villages of Jalangi block exhibit definite arsenical skin lesions. An estimation of probable population that may suffer from arsenical skin lesions and cancer in the Jalangi block has been evaluated comparing along with international data. A total of 1600 biologic samples including hair, nail and urine have been analyzed from the affected villages of Jalangi block and on an average 88% of the biologic samples contain arsenic above the normal level. Thus, a vast population of the block may have arsenic body burden. Cases of Bowen's disease and cancer have been identified among adults who also show arsenical skin lesions and children in this block are also seriously affected. Obstetric examinations were also carried out in this block.     

Theory of Seepage into an Auger Hole in a Confined Aquifer

A steady-state theory is presented for predicting flow into an auger hole partially penetrating a homogeneous and anisotropic confined aquifer that is underlain by an impermeable layer. The developed equations can be directly applied (i.e., without resorting to a coordinate transformation) to translate the rate of rise of the water in a pumped auger hole into directional conductivities of soil. The study shows that the conductivity values calculated by neglecting the confining pressure of an artesian aquifer (i.e., by applying the existing unconfined auger-hole seepage theories to experimental auger data obtained from a confined aquifer) may lead to serious error; hence, the confining head of an aquifer must be considered while the conductivity values are computed. Further, the distance of the outer layer also plays an important role in determining the flow to an auger hole penetrating a confined aquifer, and this parameter must therefore be included in the theoretical analysis of the problem. The validity of the proposed theory is checked by comparing a few results obtained from the theory with corresponding results obtained from numerical and analytical works. The developed theory is an addition to already existing auger-hole seepage theories for water-table aquifers; together with the available theories, the proposed solution is expected to cover the most commonly encountered auger hole experimental flow situations in the field.     

A comparison of hardware implementations of the biorthogonal 9/7 DWT: convolution versus lifting

The filter bank approach for computing the discrete wavelet transform (DWT), which we call the convolution method, can employ either a nonpolyphase or polyphase structure. This work compares filter banks with an alternative polyphase structure for calculating the DWT-the lifting method. We look at the traditional lifting structure and a recently proposed "flipping" structure for implementing lifting. All filter bank structures are implemented on an Altera field-programmable gate array. The quantization of the coefficients (for implementation in fixed-point hardware) plays a crucial role in the performance of all structures, affecting both image compression quality and hardware metrics. We design several quantization methods and compare the best design for each approach: the nonpolyphase filter bank, the polyphase filter bank, the lifting and flipping structures. The results indicate that for the same image compression performance, the flipping structure gives the smallest and fastest, low-power hardware.     

Promotion of microcrystallization by argon in moderately hydrogen diluted silane plasma

Using argon as a diluent of SiH₄, undoped hydrogenated microcrystalline silicon (μc-Si:H) films, having σ_D10⁻⁵ S cm⁻¹, were prepared at a very high deposition rate of 36 Å/min. Micrograins were identified with several well-defined crystallographic orientations. The effect of variation of Ar-dilution on the electrical and structural properties of Si:H films were studied systematically. Addition of H₂ to the Ar-diluted SiH₄ plasma improved the network structure by eliminating defects, introducing structural reorientation and grain growth, although, reducing the deposition rate. Accordingly, highly conducting (σ_D10⁻³S cm⁻¹) undoped μc-Si:H film was achieved utilizing energy released by de-excitation of metastable state of Ar (denoted as Ar*), in association with network modulation by atomic hydrogen in the plasma.     

On the SEP of Cooperative Diversity with Opportunistic Relaying

We analyze the exact symbol error probability (SEP) of cooperative diversity with opportunistic amplify-and-forward (AF) relaying. The benefit of this opportunism to the SEP is assessed by comparing with maximal ratio combining of orthogonal multiple AF relay transmissions.