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排序方式: 共有504条查询结果,搜索用时 15 毫秒
1.
Control of the 1D self‐assembly pattern of colloidal quantum dots (QDs) on PbSO4 nanoribbon (NRb) templates is achieved. The internal structure of the NRbs is investigated by X‐ray diffraction, revealing the isotropic packing of the PbSO4 nanoclusters in the NRbs. Colloidal QDs in a chloroform/hexane mixture are adsorbed onto the region close to the edges of the NRbs and form a 1D assembly of straight single line or double lines by controlling the amount of OAm. This is the first demonstration of a densely packed 1D self‐assembly of colloidal QDs with a straight line pattern without the use of any molecular bridge or adhesive. Atomic force microscopy measurements of the NRbs show depressions in the phase profile along the width of the NRbs, corresponding to the position of the 1D QD chain. The amount of adsorbed QDs on the NRbs in solution decreases as the addition of OAm increases, suggesting that additional OAm prevents interaction between the QDs and NRbs but facilitates the uniform adsorption of the 1D assembly. The low‐dimensional self‐assembly of colloidal QDs in this study opens up the possibility for the creation of anisotropically assembled QD superstructures. 相似文献
2.
Kazushi Shibutani Jun Nakai Ketkanok Aphichartsuphapkhajorn Yoshihito Kayaki Shigeki Kuwata Yoshihiko Arao Masatoshi Kubouchi 《应用聚合物科学杂志》2021,138(17):50311
The effect of oxygen and additional oxygen providers on furfuryl alcohol polymerization was investigated through chemical analyses and mechanical evaluation. NMR, UV–vis, Fourier transform infrared, and gas chromatography–mass spectrometry (GC–MS) results suggested that atmospheric oxygen and the further addition of an oxygen source functioned as an activator for the entire network polymerization. Interestingly, the construction of a conjugated structure on the furan linear chain, which is key to three-dimensional cross-linking, also appears to be accelerated in the presence of oxygen. Furthermore, the introduction of oxygen providers into the curing system successfully enhanced the mechanical properties of the cured furan resin. 相似文献
3.
Nishanth Koganti Tomohiro Shibata Tomoya Tamei Kazushi Ikeda 《Advanced Robotics》2019,33(15-16):800-814
ABSTRACTMotor-skill learning for complex robotic tasks is a challenging problem due to the high task variability. Robotic clothing assistance is one such challenging problem that can greatly improve the quality-of-life for the elderly and disabled. In this study, we propose a data-efficient representation to encode task-specific motor-skills of the robot using Bayesian nonparametric latent variable models. The effectivity of the proposed motor-skill representation is demonstrated in two ways: (1) through a real-time controller that can be used as a tool for learning from demonstration to impart novel skills to the robot and (2) by demonstrating that policy search reinforcement learning in such a task-specific latent space outperforms learning in the high-dimensional joint configuration space of the robot. We implement our proposed framework in a practical setting with a dual-arm robot performing clothing assistance tasks. 相似文献
4.
Tetsuji Yano Hayato Tateno Tetsuo Kishi Shuichi Shibata Kanae Matsuyama Takeshi Okita Shinya Miyamoto Hirohide Kofuji Munetaka Myochin 《Journal of the American Ceramic Society》2014,97(2):457-464
Surface structures of iron–phosphate glasses were examined using X‐ray photoelectron spectroscopy (XPS). Cr2O3, CoO, and Al2O3 were introduced to the glass by the replacement of a part of Fe2O3, and the simulated fission products are also added. The obtained glasses showed high chemical durabilities by MCC‐1 test. In situ high‐temperature and room‐temperature XPS measurements were conducted on the polished sample surfaces and also those after 1‐week chemical durability test. Unique trends were observed in XPS spectra on heating and after the chemical durability test, respectively. Nature of the glass surface of iron–phosphate glasses was explained from the point of view of surface energy, and the origin of high chemical durability and the effect of chromium ions were discussed based on the changes on surface composition and valence states of transition‐metal ions. 相似文献
5.
Atsuhiro Iimuro Kosuke Higashida Yusuke Kita Kazushi Mashima 《Advanced Synthesis \u0026amp; Catalysis》2016,358(12):1929-1933
We describe a most straightforward synthetic method for preparing neurokinin‐1 (NK1) receptor antagonist derivatives by asymmetric hydrogenation of 3‐amido‐2‐arylpyridinium salts using dinuclear iridium complexes with enantiopure diphosphine ligands, affording the corresponding chiral piperidines in high cis‐diastereoselectivity (>95:5) and moderately high enantioselectivity (up to 86%). Deprotection treatments afforded the NK‐1 receptor antagonist (+)‐CP‐99,994 (83% ee). In addition, we observed unique additive effects of 10‐camphorsulfonic acid in the asymmetric hydrogenation of 3‐amido‐2‐arylpyridinium salts.
6.
Kosuke Higashida Haruki Nagae Kazushi Mashima 《Advanced Synthesis \u0026amp; Catalysis》2016,358(24):3949-3954
Dinuclear triply chloro‐bridged iridium(III) complexes bearing chiral diphosphine ligands catalyze the asymmetric hydrogenation of tosylamido‐substituted pyrazines to give the corresponding chiral tetrahydropyrazines with an amidine skeleton in high yield and with high enantioselectivity. Addition of N,N‐dimethylanilinium bromide enhanced the catalytic activity of the iridium complexes and also increased the enantioselectivity of the products by trapping the hydrogenated amine products with HBr from N,N‐dimethylanilinium bromide. The amidine skeleton of the products could be transformed to give chiral piperazinones and piperazines without loss of enantioselectivity.
7.
Phosphorus flame retardants in indoor dust and their relation to asthma and allergies of inhabitants
A. Araki I. Saito A. Kanazawa K. Morimoto K. Nakayama E. Shibata M. Tanaka T. Takigawa T. Yoshimura H. Chikara Y. Saijo R. Kishi 《Indoor air》2014,24(1):3-15
Organophosphate esters are used as additives in flame retardants and plasticizers, and they are ubiquitous in the indoor environment. Phosphorus flame retardants (PFRs) are present in residential dust, but few epidemiological studies have assessed their impact on human health. We measured the levels of 11 PFRs in indoor floor dust and multi‐surface dust in 182 single‐family dwellings in Japan. We evaluated their correlations with asthma and allergies of the inhabitants. Tris(2‐butoxyethyl) phosphate was detected in all samples (median value: 580 μg/g in floor dust, 111 μg/g in multi‐surface dust). Tris(2‐chloro‐iso‐propyl) phosphate (TCIPP) was detected at 8.69 μg/g in floor dust and 25.8 μg/g in multi‐surface dust. After adjustment for potential confounders, significant associations were found between the prevalence of atopic dermatitis and the presence of TCIPP and tris(1,3‐dichloro‐2‐propyl) phosphate in floor dust [per log10‐unit, odds ratio (OR): 2.43 and 1.84, respectively]. Tributyl phosphate was significantly associated with the prevalence of asthma (OR: 2.85 in floor dust, 5.34 in multi‐surface dust) and allergic rhinitis (OR: 2.55 in multi‐surface dust). PFR levels in Japan were high compared with values reported previously for Europe, Asia‐Pacific, and the USA. Higher levels of PFRs in house dust were related to the inhabitants' health status. 相似文献
8.
Kazushi Terada Shoji Nakamura Taro Nakao Atsushi Kimura Osamu Iwamoto Hideo Harada 《Journal of Nuclear Science and Technology》2016,53(11):1881-1888
Gamma-ray emission probabilities of 241, 243Am and 239Np have been precisely measured with gamma- and alpha-ray spectroscopic methods. The activities of the samples were determined by measuring alpha particles using a Si semiconductor detector. Gamma rays emitted from the samples were measured with a planar type High-Purity Germanium (HPGe) detector. An efficiency curve of the HPGe detector was derived with uncertainties from 0.7% to 2.5% by combining measured efficiencies and Monte Carlo simulation. The gamma-ray emission probabilities for the major gamma rays of these nuclides were determined with uncertainties less than 1.2%. 相似文献
9.
To investigate the impact resistance of RC slabs strengthened with Fibre Reinforced Plastic (FRP) sheet to the back of the
slab, falling-weight impact tests were conducted. Two loading types were applied: iterative loading and single loading. The
impact load was applied to the centre of the RC slab with a free falling 300 kg steel striker with a diameter of 60 mm. A
total of 12 RC slabs that were 1,650 (L) × 1,650 (W) × 150 (h) mm were used for these experiments. In this study, the strengthening
method and material properties of the FRP sheet and the number of FRP sheet layers were varied. The results obtained from
this study are as follows: (1) the impact resistance of the RC slabs can be improved by attaching a strengthened FRP sheet
to the back surfaces; (2) the load bearing mechanism of RC slabs depends on the loading type and strengthening volume of the
FRP sheet; and (3) the dynamic amplification factor is about two, which is independent of the load bearing mechanism of the
RC slab and the strengthening volume and tensile rigidity of the FRP sheet. 相似文献
10.
Real‐time histological imaging of kidneys stained with food dyes using multiphoton microscopy 下载免费PDF全文
Yasuaki Nagao Kazushi Kimura Shujie Wang Takeshi Fujiwara Akira Mizoguchi 《Microscopy research and technique》2015,78(10):847-858
We have developed a real‐time imaging technique for diagnosis of kidney diseases which is composed of two steps, staining renal cells safely with food dyes and optical sectioning of living renal tissue to obtain histological images by multiphoton microscopy (MPM). Here, we demonstrated that the MPM imaging with food dyes, including erythrosine and indigo carmine, could be used as fluorescent agents to visualize renal functions and structures such as glomerular bloodstreams, glomerular filtration, and morphology of glomeruli and renal tubules. We also showed that the kidneys of IgA nephropathy model‐mice stained with the food dyes presented histopathological characteristics different from those observed in normal kidneys. The use of the food dyes enhances the quality of tissue images obtained by MPM and offers the potential to contribute to a clinical real‐time diagnosis of kidney diseases. Microsc. Res. Tech. 78:847–858, 2015. © 2015 Wiley Periodicals, Inc. 相似文献