State-of-the-art technology: Recent investigations on laser-mediated synthesis of nanocomposites for environmental remediation

In both developing and industrialized/developed countries, various hazardous/toxic environmental pollutants are entering water bodies from organic and inorganic compounds (heavy metals and specifically dyes). The global population is growing whereas the accessibility of clean, potable and safe drinking water is decreasing, leading to world deterioration in human health and limitation of agricultural and/or economic development. Treatment of water/wastewater (mainly industrial water) via catalytic reduction/degradation of environmental pollutants is extremely critical and is a major concern/issue for public health. Light and/or laser ablation induced photocatalytic processes have attracted much attention during recent years for water treatment due to their good (photo)catalytic efficiencies in the reduction/degradation of organic/inorganic pollutants. Pulsed laser ablation (PLA) is a rather novel catalyst fabrication approach for the generation of nanostructures with special morphologies (nanoparticles (NPs), nanocrystals, nanocomposites, nanowires, etc.) and different compositions (metals, alloys, oxides, core-shell, etc.). Laser ablation in liquid (LAL) is generally considered a quickly growing approach for the synthesis and modification of nanomaterials for practical applications in diverse fields. LAL-synthesized nanomaterials have been identified as attractive nanocatalysts or valuable photocatalysts in (photo)catalytic reduction/degradation reactions. In this review, the laser ablation/irradiation strategies based on LAL are systematically described and the applications of LAL synthesized metal/metal oxide nanocatalysts with highly controlled nanostructures in the degradation/reduction of organic/inorganic water pollutants are highlighted along with their degradation/reduction mechanisms.     

Microstructure and mechanical properties of a copper–stainless-steel dual-phase system prepared by spark plasma sintering

Spark plasma sintering (SPS) has been used to synthesise samples of a model dual-phase (DP) system, consisting of copper and AISI420 martensitic steel. Mixed powders were sintered at different temperatures in the range from 850°C to 1000°C using a loading pressure of 60?MPa. Tensile testing revealed dimpled fracture surfaces in samples sintered at higher temperatures, indicating ductile failure and good interfacial bonding between the phases, with the best results overall obtained for samples sintered from wet-mixed powders. The results show that by control of the mixing, sintering and post-sintering heat treatment conditions, the fabrication of dense samples covering a range of DP microstructures is possible using SPS, with independent control of the microstructure and properties of the two phases.     

Aging effect of atmospheric pressure plasma jet treated polycaprolactone polymer solutions on electrospinning properties

In previous work, an atmospheric pressure plasma jet was applied to successfully improve the electrospinnability of poly-ε-caprolactone (PCL) which enabled the fabrication of beadless nanofibers. In this paper, we report the aging effect of the plasma treatment to evaluate the robustness of the developed process. For this purpose, plasma-treated PCL polymer solutions with different exposure time were stored for 1 and 8 days and the aged solutions were analyzed in terms of conductivity, viscosity, surface tension, pH, and polymer molecular weight. During storage, the surface tension and acidity of the plasma-treated solutions were maintained constant. However, the viscosity was found to be significantly lower after 8 days which was attributed to PCL degradation. Electrospinning of all stored PCL solutions resulted in the generation of beadless PCL nanofibers. The plasma treatment effects were thus found to be highly stable over time and capable of producing high-quality PCL nanofibers up to 8 days. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48914.     

Effects of GPTMS concentration and powder to liquid ratio on the flowability and biodegradation behaviors of 45S5 bioglass/tragacanth bioactive composite pastes

Injectable composite pastes were prepared using melt-derived 45S5 bioactive glass and tragacanth crosslinked by (3-glycidyloxypropyl)trimethoxysilane (GPTMS). The effect of powder to liquid ratio (P:L = 1.0:2.0–1.0:2.5) and GPTMS/tragacanth ratio (0.0–1.5) on the injectability, swelling behavior, rheology, bioactivity, and cellular behavior of the pastes was investigated. Based on the results, the apparent stability and consistency of the pastes increased upon crosslinking by GPTMS. Due to the increased interactions between tragacanth and glass, a hysteresis loop with larger area was formed in the presence of GPTMS. With increase of GPTMS:tragacanth ratio from 0 to 1.5, the swelling percent dropped from 24.65 to 16.25% after 24 h and the degradation percent also went down from 27.89 to 9.11% after 21 days in the simulated body fluid. The 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay showed a drop in the optical density of MG63 osteoblasts up to 30.07% after exposure to the GPTMS-crosslinked composite pastes for 3 days. However, the number of viable cells gradually increased in the presence of the pastes and the cell morphology remained unchanged over time. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47604.     

Graphene network enabled high speed electrical actuation of shape memory nanocomposite based on poly(vinyl acetate)

Here strong electroactive shape memory nanocomposites were prepared by incorporating graphene nanoplatelets into poly(vinyl acetate) (PVAc ) through the simple solvent mixing method. TEM and XRD revealed that well exfoliated graphene nanoplatelets formed a continuous network throughout the matrix with a large amount of interconnectedness. Dynamic mechanical analysis showed that the inclusion of graphene significantly improves both glassy and rubbery moduli of the matrix. Furthermore, the prepared nanocomposites demonstrated a marked electrical conductivity up to 24.7 S m^?1 and thereby surprisingly rapid electrical actuation behaviour exhibiting a 100% recovery ratio in 2.5 s. Moreover, PVAc and its nanocomposites displayed scratch self‐healing capability. This work demonstrates that the PVAc /graphene nanocomposites with high modulus and excellent electroactive shape memory performance can be a promising material in many applications such as sensors and fast deployable and actuating devices. © 2016 Society of Chemical Industry     

Soil quality response to long-term wastewater irrigation in Inceptisols from a semi-arid environment

Thirty-nine paired soil samples belonging to Inceptisols, irrigated with wastewater and well water, were examined to monitor the combination of clay mineralogy, physicochemical properties, and trace metals (Zn, Cu, Cd, and Pb) following long-term wastewater irrigation. Results of XRD analysis indicated that the quantity of clay minerals did not change by long-term wastewater irrigation although some modifications in smectite were occurred in Fluvaquentic Endoaquepts compared to control (well water-irrigated soil). Irrigation with wastewater was resulted in an increase in clay content from 3 to 17%, EC from 90 to 160%, organic carbon from 13 to 44%, and CEC from 10 to 13%. In this context, improvement in total N was as 80–110%, available P as 270–330%, and available K as 5–50% as compared to the control soil. Irrigation with wastewater was led to a significant enrichment in both EDTA-extractable and total metals of Zn, Cu, Cd, Pb, mainly as result of the combination of their addition through wastewater along with interaction between the used wastewater and its receiving soils. In the light of this, wastewater irrigation system showed the relative enrichment (RE) for total-Zn, Cu, Cd, and Pb as 3.6–6.8, 2.8–4.9, 4.4–5.7, and 1.8–2.3, respectively. Fine particle-size fraction (<0.002 mm), organic matter, and calcium carbonates were appeared as the main agents in retaining the total trace metals as reflected in significant positive correlation among the physicochemical properties and the examined metals. Degree of contamination (C_d) for the four analyzed metals was in the range of 3–5. Based on C_d values, the wastewater-irrigated soils were classified as moderate degree of contamination (2 ≤ C_d < 4) to high degree of contamination (4 ≤ C_d < 8). Fluvaquentic Endoaquepts highlighted to be a major contributor of the load and contamination rate of trace metals regarding to geoaccumulation index, contamination factor, and Degree of contamination.     

Improved Turbo Decoding Using Soft Combining Principle

One great challenge in wireless communication systems is to ensure reliable communications. Turbo codes are known by their interesting capabilities to deal with transmission errors. In this paper, we present a novel turbo decoding scheme based on soft combining principle. Our method improves decoding performance using soft combining technique inside the turbo decoder. Working on Max-Log-Maximum a Posteriori (Max-Log-MAP) turbo decoding algorithm and using an Additive White Gaussian Noise (AWGN) channel model and 16 Quadrature Amplitude Modulation (16QAM), simulation results show that the suggested solution is efficient and outperforms the conventional Max-Log-MAP algorithm in terms of Bit Error Rate (BER). The performance analysis is carried out in terms of BER by varying parameters such as the Energy per bit to Noise power spectral density ratio ( \(\text {E}_{\text {b}}/\text {N}_{\text {o}}\) ), and decoding iterations number. We call our proposed solution Soft Combined Turbo Codes.