Formation of acrylamide in microwave-roasted sorghum and associated dietary risk

The effect of microwave roasting parameters (300, 450 and 600 W; 5, 10 and 15 min) on acrylamide content in sorghum grain was determined using High Pressure Liquid Chromatography (HPLC)-photo diode array (PDA) detector coupled with C-18 column. Samples roasted at 300 and 450 W did not possess acrylamide, whereas 600 W (15 min) favoured formation of 2740.19 µg/kg of acrylamide, levels far exceeding the defined European Union (EU) limits. The chronic daily intake (CDI) for acrylamide through consumption of such grain flour was 3.25–9.5-fold higher to Joint FAO/WHO Expert Committee on Food Additives (JECFA) defined high exposure limits. The margin of exposure (MOE) values ranged from 4.3 to 12.76 and from 11.07 to 32.27 for neoplastic and neurological effects, respectively, demonstrating high exposure and serious health concerns associated with dietary intake of this toxicant. This study assesses the risk for the Indian population and highlights the importance of optimising process parameters for food product to minimise such exposure risks.     

Escherichia coli,Salmonella spp., and Staphylococcus aureus susceptibility to antimicrobials of human and veterinary importance in poultry sector of India

In India, little attention has been paid on antimicrobial resistance (AMR) in the context of developing “One Health” approach. Hence, utilizing multi-disciplinary approach, we assess the AMR level and dynamics/pattern of multi-drug resistance (MDR) in Escherichia coli, Salmonella spp., and Staphylococcus aureus circulating over the different stages of poultry in India. A total of 342 isolates including E. coli (n = 143), Salmonella spp. (n = 104), and S. aureus (n = 95) were recovered from fecal (n = 80) and cecal (n = 80) samples of chicken, collected across the different poultry-retail shops and poultry-farms located at urban and rural areas of Rajasthan, India, respectively. High rates of AMR to drugs that are critically/highly important both in human and veterinary medicine were observed among all the isolates. Upward trends in AMR prevalence was observed in poultry-retail shops than in poultry-farms. Notably, >90% of all the isolates were MDR, of particular, pattern/prevalence of MDR was substantially varied across the poultry-farms vs. poultry-retail shops. Our results indicate AMR including MDR to be common in E. coli, Salmonella spp., and S. aureus distributed frequently in poultry. The study encourages the formulation of national policy, programmes and further research with a “One Health” approach that can benefits to the human/animal and the environment.     

High‐performance thermosets with tailored properties derived from methacrylated eugenol and epoxy‐based vinyl ester

A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low‐viscosity co‐monomer to replace styrene in a commercial epoxy‐based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loading and temperature on the viscosity of the VE–ME resin is investigated. Moreover, the thermomechanical properties, curing extent and thermal stability of the fully cured VE–ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, the viscosity of the VE–ME resin can be tailored by adjusting the ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE–ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE–ME thermosets. Overall, the developed ME monomer exhibits promising potential for replacing styrene as an effective low‐viscosity co‐monomer. The VE–ME resins show great advantages for use in polymer matrices for high‐performance fiber‐reinforced composites. This work is of great significance to the vinyl ester industry by providing detailed experimental support. © 2018 Society of Chemical Industry     

用于控制变速电动机的功率模块

改善洗衣机、电冰箱以及空调等家用电器能源使用效率的需求正在增加。从传统的固定转速马达转换到变速马达可以节省能耗30％之多。但这种设计的难度较大，虽已经出现了几种方案来降低此类项目的数字设计工作难度，但是设计人员仍需要集成模块和相关的设计工具来促进功率级的设计。为了使低成本变速马达控制器成为可能，元器件供应商设法通过简化设计和降低结构复杂度来减少变速控制器的成本。例如，已经出现了几种数字信号控制平台，它们结合了DSP和集成PWM和马达控制外围设备的RISC处理器。这些平台可运行第三方或者自行开发的马达控制算法。     

Irradiation of large area Mylar membrane and characterization of nuclear track filter

Ion irradiation of Si⁸⁺ ion beam of 100 MeV was scattered by a gold foil on a Mylar membrane of 25 Μm thickness in the form of film roll (width, 12.5 cm and length, 400 cm) at the Nuclear Science Centre, New Delhi. The characterization of etched nuclear tracks was carried out by gas permeation measurements. The samples cut from the film roll of required size for permeability measurements were etched in a controlled manner in a constant temperature bath of 6N NaOH solution. The opening of the conical etched tracks was characterized by hydrogen gas permeation.     

A radix-8 wafer scale FFT processor

Wafer Scale Integration promises radical improvements in the performance of digital signal processing systems. This paper describes the design of a radix-8 systolic (pipeline) fast Fourier transform processor for implementation with wafer scale integration. By the use of the radix-8 FFT butterfly wafer that is currently under development, continuous data rates of 160 MSPS are anticipated for FFTs of up to 4096 points with 16-bit fixed point data.     

Microclusters as superatoms for developing new materials

With the discovery of solid C₆₀, efforts are being made to develop new clusters and molecules which could be assembled to form new materials. Here we present some recent developments in this direction and discuss bonding in such materials.     

Simulation of leachate migration in leaky aquifers

A two-dimensional cross-section finite difference model is presented to simulate density dependent leachate migration in leaky aquifers. Unlike existing models, a new approach is adopted to couple the groundwater-flow equation and the hydrodynamic dispersion equation with the elimination of the intermediate step of calculating velocities. The concept of the reference density is employed, permitting increased accuracy (over pressure-based models) in the representation of the transport process. The model is then used to study the effect of several hydraulic and transport parameters on the flow pattern and plume migration which are found to be very sensitive to most of these parameters. Equiconcentration and equipotential lines are overlapped to provide a better understanding of the coupling effect.     

Flexible and light weight copper indium diselenide solar cells on polyimide substrates

Thin film flexible CuInSe₂ (CIS) solar cells have been fabricated for the first time on light-weight polymeric substrates. Evaporated Cu---In alloy precursors were selenized in H₂Se atmosphere at around 400°C to grow the CIS absorber layers. Low temperature techniques which are compatible with the polymeric substrates were used to deposit the window layers of CdS and ZnO. The demonstrated active area conversion efficiency of 9.3% makes this light-weight device very attractive for many terrestrial and space power generation applications where high specific power and mechanical flexibility are needed.     

Comparison of vibration and hot‐tool thermoplastic weld morphologies

Because of very different heating rates in hot‐tool and vibration welding, and the higher weld pressures used in vibration welding inducing more squeeze flow, the weld zones in these two processes see very different flows and cooling rates, resulting in different morphologies. The weld morphologies of bisphenol‐A polycarbonate (PC) and poly(butylene terephthalate) (PBT) for these two processes are discussed in relation to these differences. The thickness of the heat‐affected zone (HAZ) in hot‐tool welds increases with the melt time; this zone is thicker than in vibration welds. The HAZ thickness in hot‐tool welds increases from the center toward the edges. The HAZ thickness is more uniform in vibration welds. Hot‐tool welds of PC have large numbers of bubbles around the central plane; the bubble size increases from the center to the edges. PC vibration welds do not have bubbles except near the edges. Both hot‐tool and vibration welds of PBT do not have bubbles. The morphology of the HAZ in PBT is very different in hot‐tool and vibration welds. In hot‐tool welds, the resolidified material consists of a sandwich structure in which two thin layers with very small crystallites surround a thicker central layer in which the spherulites are almost as large as in the original molded material. In vibration welds, the HAZ has large crystallinity gradients across the weld zone as well as squeeze‐flow induced distortion of the small spherulites.