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针对钽与钢之间物化性质差异大,焊接时易产生脆性金属间化合物而导致熔焊接头性能低下及裂纹等问题,按照熔核金属高熵化技术思路,利用基于密度泛函理论的热力学第一性原理设计出新型中间层合金Ta20Fe20Ni20Cr20Co20,结合熔合比得到适用于钽/钢储能焊中间层合金成分为Ta7Ni32Cr19Co42. 采用真空电弧炉熔制纽扣合金锭,继而使用单辊急冷法制备出中间合金箔材,将其用于Ta1/0Cr18Ni9薄板的储能焊连接. 结果表明,在储能焊条件下,Ta1/Ta7Ni32Cr19Co42/0Cr18Ni9搭接接头形成形貌规则、完整,长径约0.8 mm的扁球形熔核,熔核整体向钢侧发生了偏移. 熔核组织由简单的FCC固溶体组成,无金属间化合物析出,具有典型的高熵合金特征,实现了熔核金属高熵化. 在焊接电压1 000 V,电容500 μF,电极压力30 N下,Ta1/Ta7Ni32Cr19Co42/0Cr18Ni9储能焊接头平均强度可达到395 MPa. 相似文献
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基于高熵合金中间层的TA2与Q235电阻焊研究 总被引:1,自引:0,他引:1
本文针对钛和低碳钢焊接时易产生金属间化合物导致性能下降及裂纹等问题,采用焊缝高熵化技术路线,设计出TA2/Q235焊接用高熵合金中间层成分,应用急冷快速凝固装置制备出厚约60um、宽约4mm的Ti5Fe5Al30Ni30Cu30和Ti10Fe10Cr5Ni35Cu40高熵合金箔带,并将其用于TA2/Q235的电阻点焊。分析了焊接工艺参数与接头组织的相关性,研究结果表明,一定条件下应用Ti10Fe10Cr5Ni35Cu40中间层较Ti5Fe5A130Ni30Cu30中间层更易实现钛与钢的焊接。在焊接电流为5000~6000A,电极力为5000N,焊接时间为0.6s条件下,应用Ti10Fe10Cr5Ni35Cu40高熵合金中间层获得了TA2/O235的连接,焊缝组织细小均匀,焊缝与母材的结合区未出现金属间化合物迹象。 相似文献
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"海西新材产业将实现紧密合作,共建共赢.海西新材产业大交流大合作大市场的格局正在形成,并将为全国新材产业的发展以及行业转型升级开拓全新的模式."这是记者从福建省新材办了解到的最新情况.福建省新材办牵头与海峡西岸经济区20个城市(福州、厦门、泉州、温州、丽水、衢州、上饶、鹰潭、抚州、赣州、梅州等)发展新型墙材管理部门共同签署《海峡西岸经济区20个城市发展应用新型墙材合作框架协议》(以下简称《合作框架协议》). 相似文献
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应用微型电容储能焊机对厚度约40~60μm的急冷Cu-Sn合金箔带进行了快速凝固焊接,分析了焊接工艺参数对接头组织与性能的影响.结果表明,在储能电容不变的条件下,焊接电压及电极力对接头抗剪强度有着显著影响.随着锡含量增加,实现合金箔焊接所需要的电压减小,电极力增大.Cu-7%Sn,Cu-13.5%Sn合金箔比较适宜的焊接工艺参数分别为U=90 V,F=11 N及U=85 V,F=11.5 N.气孔是Cu-Sn合金箔主要焊接缺陷.随电压降低或电极力增加,接头冷却速率增大,气相形核率降低,气泡长大、合并和迁移在一定程度上受到抑制,气孔产生降低.Abstract: The rapid solidification welding of quenched Cu-Sn alloy foils with the thickness of 40 - 60μm was conducted by a micro-type capacitor discharge welding machine, and the effects of welding parameters on microstructural morphology and mechanical properties of joint were researched. The results indicate that welding voltage and electrode pressure have obvious influence on the shear strength of joint under fixed capacitance. With the increase of Sn content, the welding voltage needed decreases and electrode pressure rises accordingly. The favorable welding parameters are U = 90 V, F=11 N for Cu-7% Sn alloy and U = 85 V, F = 11.5 N for Cu-13.5% Sn alloy. The main welding defect is porosity. With decreasing of welding voltage and increasing of electrode pressure, the joint cooling rate increases and the pore nucleation rate decreases. Meanwhile, the growth, mergence and migration of porosities are suppressed, resulting in the decrease of porosity forming tendency. 相似文献
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采用微型储能焊机对厚度为 0.2mm 的 0Cr18Ni9 奥氏体不锈钢薄板进行了点焊连接研究,理论分析了微型熔核的温度场和冷却速率.结果表明,微型接头由熔核区和熔合区组成.极短的焊接时间,高的冷却速率 5.1×106 K/s,使得熔核中奥氏体组织来不及长大,熔核凝固组织得到显著细化,具有快速凝固特征;同时,熔核中奥氏体组织在敏化温度区停留时间很短,抑制了铬在奥氏体晶界上的析出.当储能焊接电压为 80V、电容为 6600μF、电极力为 18N 时,可获得综合性能优良的高质量点焊接头.Abstract: The 0Cr18Ni9 austenitic stainless steel sheet with 0.2 mm thickness was welded in capacitor discharge spot welding.The temperature field and cooling rate of nugget was calculated. The results show that the joint microstructure consists of nugget zone and semi-melt zone. Due to very short time in welding, the cooling rate of the joint reaches to 5.1×106 K/s, the growth of austenite microstructure is impeded, and the microstructure of the nugget is refined,which has rapidly solidified characteristics. As the austenite microstructure of the nugget stays in temperature province of activation with very short time, the chrome of austenite grain boundary precipitations is checked. To obtain the high quality spot-weld joint, the welding parameters are determined as: welding voltage 80 V, capacitor 6 600μF and electrode pressure 18 N. 相似文献