A metaheuristic analysis of heat transfer rates through porous fins of tapered and step profiles: a comparative study

Neural Computing and Applications - The advanced high-end gadgets and sophisticated machines require effective mechanism of transferring heat away from the sources. In a large number of...     

Synthesis of Self-Healing Bio-Based Tannic Acid-Based Methacrylates By Thermoreversible Diels–Alder Reaction

This investigation reports the effective use of the Diels–Alder (DA) click reaction in the preparation of self-healing bio-based dendritic methacrylates having reactive furfuryl functionality. Bio-based methacrylates were synthesized by modifying tannic acid with glycidyl methacrylate and furfuryl functionality was introduced by atom transfer radical polymerization with varied amount of furfuryl methacrylate monomer. The thermoreversible network was successfully achieved by DA and retro-DA reaction between the furfuryl groups and a bifunctional maleimide crosslinker, bismaleimide. This process was studied by nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and solvent exposure tests. Differential scanning calorimetry analysis was used to determine the endothermic retro-DA reaction in the DA adduct. The self-healing property of the above crosslinked material was demonstrated by monitoring the repair of a scratch in the polymer film upon heating and cooling. This was analyzed by scanning electron microscopy. POLYM. ENG. SCI., 60:140–150, 2020. © 2019 Society of Plastics Engineers     

Nonlinear static and dynamic analysis of circular plates and shallow spherical shells using the collocation method

The present work investigates the efficacy and applicability of interior global orthogonal point collocation method to the axisymmetric nonlinear analysis of elastic circular plates and shallow spherical shells subjected to uniformly distributed transverse load. Spacewise discretisation has been carried out using a polynomial expansion with the zeros of a Chebyshev polynomial as collocation points. Timewise integration has been carried out with Newmark k-β scheme corresponding to average acceleration method. The static response and snap-through buckling results, as well as, the dynamic response and dynamic buckling results under a uniformly distributed step load have been obtained and found to agree closely with the available results.     

An efficient clustering scheme using support vector methods

Support vector clustering involves three steps—solving an optimization problem, identification of clusters and tuning of hyper-parameters. In this paper, we introduce a pre-processing step that eliminates data points from the training data that are not crucial for clustering. Pre-processing is efficiently implemented using the R*-tree data structure. Experiments on real-world and synthetic datasets show that pre-processing drastically decreases the run-time of the clustering algorithm. Also, in many cases reduction in the number of support vectors is achieved. Further, we suggest an improvement for the step of identification of clusters.     

Non-darcy natural convection from a heated vertical plate in saturated porous media with mass transfer

The nonsimilar and self-similar flows for the steady natural convection over a vertical heated surface in a saturated porous medium with mass transfer using non-Darcy model have been studied under boundary layer approximations. The differential equations governing both the nonsimilar and self-similar flows have been solved numerically using an implicit finite-difference scheme developed by Keller. The results indicate that both heat transfer and velocity field are appreciably affected by the modified Grashof number and mass transfer except that the effect of the modified Grashof number on the heat transfer for large suction is very small. It is found that the maximum velocity occurs at the wall and it increases as the modified Grashof number or injection increases.     

Preparation,structure and properties of transition metal trichalcogenides

In recent years, the transition metal trichalcogenides (TX₃) of Group IVB, VB and VIB have received much more attention because of the considerable diversity in their physical properties. The most striking feature of these compounds is that the structure here may be classified into three types depending on the number of different TX₃ chains present in the unit cell. Thus ZrSe₃, TaSe₃ and NbSe₃ are the representative compounds having one, two and three types of chain based on the different bond lengths for the (X₂)^2– pairs in the base of the TX₃ trigonal prismatic framework. A similar model is also applicable in the case of NbS₃, with the addition of a 2b-superstructure associated with the formation of niobium pairs. The chain structure also facilitates the process of intercalation which has been most effectively used in secondary batteries. These compounds exhibit the superconductivity phenomena and charge density wave, etc. and also find application in photoelectrochemical cells. An attempt has been made here to review the up-to-date chemistry of transition metal trichalcogenides related with their preparation, structure and properties such as physical and chemical, thermodynamic, electrical, magnetic and optical properties, intercalation and use in the photoelectrochemical cells. 93     

Effect of Calcium Lactate, 4-Hexyl Resorcinol and Vacuum Packing on Physico-chemical, Sensory and Microbiological Qualities of Minimally Processed Litchi (Litchi chinensis Sonn.)

Litchi (Litchi chinensis Sonn.) fruits are very susceptible to pericarp browning which adversely affects consumer acceptability even though the aril portion remains in excellent condition. Litchi arils (litchis) were treated with a solution containing 0–2% (w/v) calcium lactate (CL), 0–0.02% (w/v) 4‐hexyl resorcinol (4‐HR) and 1% potassium sorbate. The pH of solution was adjusted to 4.0 with citric acid. Treated litchis were packed in polystyrene trays, over‐wrapped with polypropylene film, vacuum‐packed (0, 47409.3, 94831.9 Pa) and stored at 4 ± 2 °C. Drip losses, pH, total soluble solids (TSS), sensory attributes and microbiological quality of stored samples were estimated. A four‐factor, three‐level experimental design (D₆ Hokes design) with 19 experiments was chosen. Mathematical models were developed to analyse and predict the effect of CL, 4‐HR, in‐package vacuum and storage time on the responses. TSS, pH and sensory scores decreased significantly (P 0.01), whereas drip losses and microbial count increased significantly (P 0.01) with time. Drip loss was significantly (P 0.1) reduced by addition of CL. 4‐HR prevented browning and changes in colour score during storage were significantly less. Vacuum in packages exerted significant (P 0.01) effect over pH, TSS, sensory and microbiological qualities of minimally processed litchis.