Defect Chemistry and Microstructure of Hydrothermal Barium Titanate

Hydrothermal powders of BaTiO₃ and (Ba,Ca)(Ti,Zr)O₃ contain large amounts of protons in the oxygen sublattice. The proton defects are compensated by vacancies on metal sites. When the powder is annealed, water is released and the point defects disappear in the temperature range of 100°–600°C. Metal and oxygen vacancies combine to small nanometer-sized intragranular pores. At temperatures of >800°C, the intragranular pores migrate to the grain boundaries and disappear. In multilayer ceramic capacitors that have been prepared from hydrothermal powders, the intragranular pores are preferentially collected at the inner electrodes, which results in "bloating," cracks, and delamination.     

Distributed SIP conference management with autonomously authenticated sources and its application to an H.264 videoconferencing software for mobiles

The design of conferencing systems for achieving efficient and flexible communication in a fully distributed, infrastructure-independent fashion is a promising direction, both in terms of research and practical development. In the particular case of video communication, the seamless adaptation to heterogeneous mobile devices poses an additional strong challenge to those seeking for interoperable and easy-to-deploy solutions. In this paper, we make several contributions towards a generic peer-to-peer (P2P) videoconferencing solution that extends into the mobile realm. We describe the essential building blocks for conference management and media distribution that are necessary for a distributed conferencing approach. Establishing a distributed SIP conference focus, participants share the conference according to their individually given capabilities and resources in terms of bandwidth and processing power rather than in a centralized and fixed way. Overall concepts and SIP-primitives for such an autonomous organization are presented. Security issues that derive from this decentralized identity management are resolved by so-called Overlay AuthoCast, a novel use of cryptographically generated identifiers. Furthermore, this work is dedicated to the development of a software-based H.264 video codec implementation and the specific aspects resulting from tuning such a highly resource-intensive software codec to the given target platform of a standard consumer smartphone.     

Cofiring of Thin Zirconia Films During SOFC Manufacturing

High-performance solid oxide fuel cells require a thin and gas-tight electrolyte membrane that must be coated on a porous and relatively rough support. A pretreatment of the delivered submicronmeter electrolyte powder of 8 mol%-yttria-stabilized zirconia (8YSZ) yielded a reduced sintering mismatch between the anode substrate made from NiO/8YSZ and the electrolyte coating. Furthermore, it also enhanced the powder packing inside the green film. Constrained sintering usually leads to inadequate film density and an unfavorable pore deformation and orientation. It was demonstrated that these limitations can be resolved by using a coshrinking substrate in a planar cell design. Relative densities of >97% were achieved, which are higher than those for free-standing layers. Additionally, the camber behavior was investigated in dependence of the temperature program with and without gravity effects, giving an overall suggestion for the cofiring parameters of the electrolyte.     

Friction Stir Knead Welding of steel aluminium butt joints

To develop steel aluminium-tailored hybrids in a butt joint for sheets in a thickness of about 1 mm conventional Friction Stir Welding is not feasible due to a high distortion of the welded specimen. Contrary to Friction Stir Welding the tool used for Friction Stir Knead Welding has no pin wherefore higher welding speeds can be realised. Due to the fact that this is a newer process, applied for patent in 2005, the cut contours of the edges and their variations have to be optimised by numerical analysis to transfer a maximum of load in order to improve the formability. The examined materials in this paper are steel DC04, as well as the aluminium alloys AA5182 and AA6016 in sheet thicknesses of 1 mm. Accompanying experimental investigations, as tensile tests, will evaluate the quality of the welding mechanism. As the mechanics of the new welding technology is not fundamentally investigated until now, metallographic investigations are performed, and additionally micro hardness measurements are carried out to verify the changes in the hardness distribution in the welding zone after stirring and welding.     

Satellite-derived irradiance statistics for Africa

Hourly images registered by the Meteosat satellite are used to derive the global irradiance at ground level. Keeping almost the full spatial information of the original images, maps of irradiance characteristics for Africa are derived with a resolution of approx. 10 × 10 km². Monthly irradiance conditions are characterized by means and standard deviations of daily sums and the irradiance of specific daytime hours. The data also allow for the extraction of irradiance time series for specific sites. In addition, the analysis of the spatial structure of the satellite-derived irradiance fields is used to identify regions in which the radiation characteristics call for special attention.     

Effects of sea surface temperature accuracy on offshore wind resource assessment using a mesoscale model

Offshore wind simulations were performed with the Weather Research and Forecasting (WRF) model driven by three different sea surface temperature (SST) datasets for Japanese coastal waters to investigate the effect of the SST accuracies on offshore wind simulations. First, the National Centers for Environmental Prediction Final analysis (FNL) (1° × 1° grid resolution) and the Operational Sea Surface Temperature and Sea Ice Analysis (OSTIA) (0.05° × 0.05° grid resolution) datasets were compared with in situ measurements. The results show a decrease in accuracy of these datasets toward the coast from the open ocean. Aiming at an improved accuracy of SST data, we developed a new high‐resolution SST dataset (0.02° × 0.02° grid resolution). The new dataset referred to as MOSST is based on the Moderate Resolution Imaging Spectroradiometer (MODIS) product, provided by the Japan Aerospace Exploration Agency (JAXA). MOSST was confirmed to be more accurate than FNL and OSTIA for the coastal waters. Then, WRF simulations were carried out for 1 year with a 2 km grid resolution and by using the FNL, OSTIA and MOSST datasets. The use of the OSTIA dataset for a WRF simulation was found to improve the accuracy when compared with the FNL dataset, and further improvement was obtained when the MOSST dataset was applied. The sensitivity of wind speed and wind energy density to SST is also discussed. We conclude that the use of an accurate SST is a key factor not only for realistic offshore wind simulations near the surface but also for accurate wind resource assessments at the hub height of wind turbines. Copyright © 2014 John Wiley & Sons, Ltd.     

Progress in the Synthesis of Nanocrystalline BaTiO3 Powders for MLCC

Future improvements in the development of highly volume-efficient multilayer ceramic capacitors (MLCC) require manufacturing processes that allow for a reduced dielectric thickness well below 1 μm. Obviously, such thin dielectric layers can only be produced if nanosized dielectric powders are applied and deposited by techniques more advanced than tape casting and screen printing. These processes require high-purity, homogeneous, weakly agglomerated ultrafine powders. Over the past few years, significant progress has been made in the synthesis of nanocrystalline BaTiO₃-based powders for use in MLCC. The present review article aims to summarize the present state of the art with respect to some of the technically and industrially most relevant preparation routes, including methods based on solid-state reactions and, more importantly, solution-based approaches.