Fundamental parameters affecting electrospinning of PAN nanofibers as uniaxially aligned fibers

Electrospinning with a collector consisting of two pieces of electrically conductive substrates separated by a gap has been used to prepare uniaxially aligned PAN nanofibers. Solution of 15 wt % of PAN/DMF was used tentatively for electrospinning. The effects of width of the gap and applied voltage on degree of alignment were investigated using image‐processing technique by Fourier power spectrum method. The electrospinning conditions that gave the best alignment of nanofibers for 10–15 wt % solution concentrations were experimentally obtained. Bundles like multifilament yarns of uniaxially aligned nanofibers were prepared using a new simple method. After‐treatments of these bundles were carried out in boiling water under tension. A comparison was made between the crystallinity and mechanical behavior of posttreated and untreated bundles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4350–4357, 2006     

Homotopy perturbation method for motion of a spherical solid particle in plane couette fluid flow

He’s homotopy perturbation method is applied to obtain exact analytical solutions for the motion of a spherical particle in a plane couette flow. It is demonstrated that the applied analytical method is very straightforward in comparison with existing techniques. Furthermore, it is decidedly effectual in terms of accuracy and rapid convergence. The formulation of the problem is presented in the text as well as the analytical and numerical procedures. The current results can be used in different areas of particulate flows.     

Modeling the hollow cylindrical piezo-ceramics with axial polarization using equivalent electro-mechanical admittance matrix

Modeling a piezo-ceramics as an electro-mechanical element is usually done using the laws of electricity. Due to complexity of the derived circuits, this kind of modeling usually results in some simplifications. In this paper using the force–velocity boundary conditions and equalizing the mechanical elements to the electrical ones, the governing equations of a hollow cylindrical piezo-ceramics with axial polarization are solved. Then the equivalent electro-mechanical impedance is represented via matrix notation. Using the matrix algebra the resonance and anti-resonance frequencies are calculated and then compared to the experimental results. The proposed method does not need to any simplification in circuit analysis, and provides the capability of modeling the various layers of piezo-ceramics and metals together in electro-acoustical transducers.     

An optical solution to the 3-SAT problem using wavelength based selectors

In this paper, an optical wavelength-based method to solve a well-known NP-complete problem 3-SAT is provided. In the 3-SAT problem, a formula F in the form of conjunction of some clauses over Boolean variables is given and the question is to find if F is satisfiable or not. The provided method uses exponential number of different wavelengths in a light ray and considers each group of wavelengths as a possible value-assignment for the variables. It then uses optical devices to drop wavelengths not satisfying F from the light ray. At the end, remaining wavelengths indicate satisfiability of the formula. The method provides two ways to arrange the optical devices to select satisfying wavelengths for a given clause: simple clause selectors and combined clause selectors, both requiring exponential preprocessing time. After preprocessing phase, the provided method requires polynomial time and optical devices to solve each problem instance.     

Hydrophilicity improvement of silicone rubber by interpenetrating polymer network formation in the proximal layer of polymer surface

A novel method composed of an interpenetrating polymer network (IPN) formation reaction in aqueous solution was developed to improve the hydrophilicity of silicone rubber (SR) substrate. This solution phase method is compatible, simple, and convenient for some sensitive biomedical applications of SR devices because of using water as reaction solvent instead of harmful chemicals. In this work, a sequential interpenetrating polymer network formation in the proximal layer of SR surface, using poly(2-hydroxyethyl methacrylate) (PHEMA), as the second network was conducted so that led to actually surface modification resulting in an improved hydrophilicity. The modified surfaces were characterized by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), contact angle measurement, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) to assess the wettability, chemical composition and morphology of the surface modified PDMS. The results indicated that the surface modification method offered a novel and facile approach to improve the hydrophilicity of SR without altering its bulk properties. This method could be suitable for biomedical applications because of using water as a monomer solvent and polymerization medium.     

Influence of various surface treated silica nanoparticles on the electrochemical properties of SiO2/polyurethane nanocoatings

Various organosilane-treated SiO₂ nanoparticles were dispersed in a 2-pack polyurethane coating. The influence of surface modification and silica content on the electrochemical behaviour of the resultant nanocoatings was investigated. Electrochemical impedance spectroscopy (EIS) and open circuit potential (OCP) variations were examined. The surface chemistry of nanoparticles and its effect on the resultant nanocoating morphology were also studied utilising FTIR, and TEM analyses. The results reveal that the presence of more hydrophobic groups and longer-lengthed hydrophobic chains on the surface of nanoparticles, greatly improves the interfacial interactions at the polymer/filler interfaces resulting in a better corrosion performance.     

Acquisition of high-precision images for non-contact atomic force microscopy

The atomic force microscope (AFM) system has evolved into a useful tool for direct measurements of intermolecular forces with atomic-resolution characterization that can be employed in a broad spectrum of applications. The distance between cantilever tip and sample surface in non-contact AFM is a time-varying parameter even for a fixed sample height, and typically difficult to identify. A remedy to this problem is to directly identify the sample height in order to generate high-precision atomic-resolution images. For this, the microcantilever (which forms the basis for the operation of AFM) is modeled as a single mode approximation and the interaction between the sample and cantilever is derived from a van der Waals potential. Since in most practical applications only the microcantilever deflection is accessible, we will use merely this measurement to identify the sample height. In most non-contact AFMs, cantilevers with high-quality factors are employed essentially for acquiring high-resolution images. However, due to high-quality factor, the settling time is relatively large and the required time to achieve a periodic motion is long. As a result, identification methods based on amplitude and phase measurements cannot be efficiently utilized. The proposed method overcomes this shortfall by using a small fraction of the transient motion for parameter identification, so the scanning speed can be increased significantly. Furthermore, for acquiring atomic-scale images of atomically flat samples, the need for feedback loop to achieve setpoint amplitude is basically eliminated. On the other hand, for acquiring atomic-scale images of highly uneven samples, a simple PI controller is designed to track the desired constant sample height. Simulation results are provided to demonstrate the feasibility of the approach for both sample height identification and tracking the desired sample height.     

Comparison of 2.3-kV Medium-Voltage Multilevel Converters for Industrial Medium-Voltage Drives

This paper compares the expense of power semiconductors and passive components of a (2.3 kV, 2.4 MVA) two-level, three-level neutral-point-clamped, three-level flying-capacitor, four-level flying-capacitor, and five-level series-connected H-bridge voltage source converter on the basis of the state-of-the-art 6.5-, 3.3-, 2.5-, and 1.7-kV insulated gate bipolar transistors for industrial medium-voltage drives. The power semiconductor losses, the loss distribution, the installed switch power, the design of flying capacitors, and the components of an sine filter for retrofit applications are considered.     

Achieving Outstanding Mechanical Performance in Reinforced Elastomeric Composite Fibers Using Large Sheets of Graphene Oxide

A simple fiber spinning method used to fabricate elastomeric composite fibers with outstanding mechanical performance is demonstrated. By taking advantage of the large size of as‐prepared graphene oxide sheets (in the order of tens of micrometers) and their liquid crystalline behavior, elastomeric composite fibers with outstanding low strain properties have been fabricated without compromising their high strain properties. For example, the modulus and yield stress of the parent elastomer improved by 80‐ and 40‐fold, respectively, while maintaining the high extensibility of ～400% strain inherent to the parent elastomer. This outstanding mechanical performance was shown to be dependent upon the GO sheet size. Insights into how both the GO sheet size dimension and dispersion parameters influence the mechanical behavior at various applied strains are discussed.