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In this study, white organic electroluminescent devices with microcavity structures were developed. A flexible high‐resolution active‐matrix organic light‐emitting diode display with low power consumption using red, green, blue, and white sub‐pixels formed by a color‐filter method was fabricated. In addition, a side‐roll touch display was developed in combination with a capacitive flexible touch screen.  相似文献   
3.
The zeta potential of alumina (Al2O3) powder with different crystalline phases, prepared by heat treatment of boehmite, was measured in simulated body fluids in order to discuss the mechanism on in vivo formation of a calcium and phosphorus (CaP)-rich layer on bone cement containing δ-Al2O3-based bead powder. γ, δ, and θ-Al2O3 powders were obtained by heat treatment of boehmite powder at 600 °C, 900 °C, and 1025 °C, respectively. It was found that δ-Al2O3 gave a negative zeta potential in an acidic simulated body fluid, whereas γ-Al2O3 and θ-Al2O3 gave a positive potentials. During the bone fracture healing process, acidic conditions are maintained at the site of fracture for several days. Consequently, it is speculated that the negative surface potential of δ-Al2O3 in an acidic body fluid, similar to the fracture site, might be responsible for the in vivo formation of the CaP-rich layer on the overlying bone cement, given that the negatively charged surface of δ-Al2O3 would attract calcium ions from the surrounding body fluid, thereby facilitating the formation of the CaP-rich layer.  相似文献   
4.
以对溴苯酚为原料,经四步反应合成一种取代苯乙炔单体4-乙炔基-(2,6)二羟甲基-1-十二烷基酚醚。利用手性的铑催化剂引发聚合,得到高分子量的螺旋聚合物,通过GPC和CD对分子量和螺旋结构进行表征。最后通过光环化反应高效合成了环状三聚体,并通过1HNMR和GPC确认其化合物结构。  相似文献   
5.
A soluble and stable one-handed helical conjugated polymer without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer having two hydroxyl groups followed by desubstitution of the chiral groups in a solid membrane state. The reason for the success was the polymer reaction was carried out in the membrane state. This is an alternative method to obtain such a unique chiral polymer which was obtained only by the helix-sense-selective polymerization (HSSP) we reported before. In addition the efficiency of the chiral induction was higher than that of the HSSP. It is interesting that the “Membrane state” acted like as if a protecting group.  相似文献   
6.
For efficient oxygen supply to pressurized culture, we developed a method using a highly pressurized membrane reactor with an air-saturated medium circulation system. The new method increased the cell growth of aerobic yeast approximately 20 folds larger than that in the case of using a conventional method.  相似文献   
7.
Direct dissimilar joining of various Al alloy (A1050, A3004, A5052 and A5083) plates and a polyamide 6 plate was performed using friction lap joining (FLJ) with the Al alloy plate as a top and the polyamide 6 plate as a bottom. The effect of Mg content in Al alloys on the joining strength was investigated. TEM analysis made clear that the polyamide 6 and Al alloys were joined via oxide layer consisting of Al2O3 and MgO. The results of XPS analysis indicated that MgO was formed by the heating during FLJ, and the quantity of MgO was increased with increasing Mg content in Al alloys. The tensile shear strengths of A3004, A5052 and A5083 joints were saturated to about 2 kN because of the tensile fracture at the polyamide 6 plate outside the tool-passed zone, which were higher than that of the A1050 joint fractured at the joint interface. The peel strength of the joint was increased with increasing Mg content in Al alloys, and the fracture occurred both at the joint interface and at the polyamide 6 plate on the joint area. The fraction of polyamide 6 plate fracture was also increased with increasing Mg content in Al alloys.  相似文献   
8.
Silk is a protein fiber used to weave fabrics and as a biomaterial in medical applications. Recently, genetically modified silks have been produced from transgenic silkworms. In the present study, transgenic silkworms for the mass production of three colors of fluorescent silks, (green, red, and orange) are generated using a vector originating from the fibroin H chain gene and a classical breeding method. The suitability of the recombinant silks for making fabrics is investigated by harvesting large amounts of the cocoons, obtained from rearing over 20 thousand silkworms. The application of low temperature and a weakly alkaline solution for cooking and reeling enables the production of silk fiber without loss of color. The maximum strain tolerated and Young's modulus of the fluorescent silks are similar to those of ordinary silk, although the maximum stress value of the recombinant silk is slightly lower than that of the control. Fabrics with fluorescent color are demonstrated using the recombinant silk, with the color persisting for over two years. The results indicate that large amounts of genetically modified silk can be made by transgenic silkworms, and the silk is applicable as functional silk fiber for making fabrics and for use in medical applications.  相似文献   
9.
Three soluble hyperbranched polyazomethines containing oligosiloxane end group HBP-PAZ-SiOn were successfully synthesized. HBP-PAZ-SiOns were used as modifiers of ethyl cellulose (EC) and polysulfone (PS) membranes. Blend membranes, HBP-PAZ-SiOn/EC and HBP-PAZ-SiOn/PS were prepared by blending the THF solution of HBP-PAZ-SiOn with ethanol solution of EC and dichloromethane solution of PS, respectively. Surprisingly, the permeabilities for CO2 of the blend membranes were more than 15–16 times higher than those of pure EC and PS membranes without any drop of pemselectivity to N2. This unusual improvement has been achieved by both enhancement of diffusivity for carbon dioxide and nitrogen by the oligosiloxane groups and enhancement of affinity of the amino groups with carbon dioxide at the end groups of HBP-PAZ-SiOn.  相似文献   
10.
Unconventional pretreatment, that is, delignification and the addition of guanidine phosphate, was performed for the synthesis of activated carbon having a high specific surface area from bamboo by physical activation. The values of the specific surface area, total pore volume, and average pore size depended on the amount of added guanidine phosphate and the CO2 activation time. The amount of the added guanidine phosphate under the optimum conditions for the highest specific surface area was much lower than that of the phosphorous acid chemical activator under conventional conditions. The N2 adsorption isotherms of all the samples were type I, which means that micropores were dominant. The pore sizes of the samples in this study were similar to that of the physically-activated carbon. Therefore, the activation process was presumed to be essentially not chemical, but physical. The relation between the yield and the specific surface area improved with the addition of guanidine phosphate. The reason for the improvement may be the change in the reactivity of the carbon material generated during the heating process. The maximum specific surface area was ca. 2000 m2 g?1, which is a high value for a physically-activated carbon.  相似文献   
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