Microstructure and Properties of Plasma Ceramics

Plasma spraying, originally a surfacing technology used for ceramic coating of metal and nonmetal substrates, is suitable for producing large, full ceramic bodies, such as plates and tubes, in situ to almost the desired dimensions; i.e., conventional methods of designing by molding and casting green bodies followed by sintering are not required. These "plasma ceramics" exhibit characteristic mechanical and thermomechanical properties. Their porous laminar grain structure results in low E -modulus and strength, and in extreme thermal shock resistance, which is enhanced by the comparably high fracture resistance of the material. Because of these properties and their low hardness, plasma ceramics can be easily machined with almost conventional methods of metal processing.     

Application of active coke in processes of SO2- and NOx-removal from flue gases

In the field of flue gas cleaning, active coke plays an important role as adsorbant and catalyst. In the temperature range usually prevailing downstream of the air preheater of power plants, SO₂ becomes adsorbed on carbonaceous materials and in a consecutive step is catalysed by the carbonaceous surface and converted to sulphuric acid. The quality demands for a cyclic regenerative process for SO₂ removal are fulfilled by the active coke which is used in the BF-process. The same active coke catalyses the reaction of NO with NH₃ to N₂ and steam. This is the basis for processes for simultaneous SO₂ and NO_x removal. By the addition of ammonia the SO₂ removal by active coke is improved. Two processes are described and results from the laboratory and from the demonstration plant for the BF-process are presented. These show that SO₂ removal efficiences exceed 95% and NO conversions of > 80% can be realized without problems. The cost of the processes using active coke with ammonia addition are comparable with those of wet flue gas desulphurization processes without any additional equipment should NO have to be removed.     

Theory of the hall effect in strongly correlated Fermi systems

The anomalous properties of the Hall constant in the normal state of high-T_c superconductors are investigated within the Hubbard model. In Mori theory, the frequency dependent Hall constant is given as the sum of its infinite frequency limit and a memory function contribution. The first term (R _H ) was already considered by Shastry et al.¹ In perturbation theory and in the limit of infinite spatial dimensions, the memory function contribution causes the Hall constant to change sign as a function of doping () and to decrease as a function of temperature, if we allow U to be 2W (U: Coulomb repulsion; W: bandwidth). In the limit U , the memory function is calculated via its moments. For frequencies W U, this leads to a decrease of R _H by a factor of (1 + )/2.     

<Emphasis Type="Bold">Stefan Hügel</Emphasis> transparenz.arbeit.kontrolle,Gemeinsame Jahrestagung von FIfF und DVD

DuD ReportVeranstaltungsbesprechungen

Stefan Hügel transparenz.arbeit.kontrolle, Gemeinsame Jahrestagung von FIfF und DVD K?ln, 5.–7. November 2010     

Antiferromagnetic,Neutral, and Superconducting Band in La<Subscript>2</Subscript>CuO<Subscript>4</Subscript>

The symmetry of the Bloch functions in the conduction band of tetragonal and orthorhombic La₂CuO₄ is examined for the existence of symmetry-adapted and optimally localizable (usual or spin-dependent) Wannier functions. It turns out that such Wannier functions do not exist in the tetragonal phase. In the orthorhombic phase, on the other hand, the Bloch functions can be unitarily transformed in three different ways into optimally localizable Wannier functions: they can be chosen to be adapted to each of the three phases observed in the pure or doped material, that is, to the antiferromagnetic phase, to the superconducting phase or to the phase evincing neither magnetism nor superconductivity. This group-theoretical result is proposed to be interpreted within a nonadiabatic extension of the Heisenberg model. Within this model, atomic-like states represented by these Wannier functions are responsible for the stability of each of the three phases. However, all the three atomic-like states cannot exist in the tetragonal phase, but are stabilized by the orthorhombic distortion of the crystal. A simple model is proposed which may explain the physical properties of La_2−x Sr _x CuO₄ as a function of the Sr concentrationx.     

Heterogeneous functionalizing of polysulfone membranes

In recent years efforts have been increased to work with more intelligent membranes which render more than normal filtration properties. Thus, membranes have been prepared using chemically modified polymers or have been furnished with additives in order to increase their selectivity and/or special sorbing capabilities. In this paper, methods are described how commercially available polysulfone membranes can be functionalized by chemical reactions without disintegrating their mechanical properties. For this purpose, Sulfonation, chloromethylation, aminomethylation, and lithiation reactions were applied. A broad spectrum for further conversions modified membranes is opened by these chemical reactions which allow an individual fitting of the membranes with special substitutes. The chemical reactions and the analytical procedures are also described.