C/C-SiC component for metallic phase change materials

Thanks to their high energy density and thermal conductivity, metallic Phase Change Materials (mPCM) have shown great potential to improve the performance of thermal energy storage systems. However, the commercial application of mPCM is still limited due to their corrosion behavior with conventional container materials. This work first addresses on a fundamental level, whether carbon-based composite-ceramics are suitable for corrosion critical components in a thermal storage system. The compatibility between the mPCM AlSi₁₂ and the Liquid Silicon Infiltration (LSI)-based carbon fiber reinforced silicon carbide (C/C-SiC) composite is then investigated via contact angle measurements, microstructure analysis, and mechanical testing after exposure. The results reveal that the C/C-SiC composite maintains its mechanical properties and microstructure after exposure in the strongly corrosive mPCM. Based on these results, efforts were made to design and manufacture a container out of C/C-SiC for the housing of mPCM in vehicle application. The stability of the component filled with mPCM was proven nondestructively via computer tomography (CT). Successful thermal input- and output as well as thermal storage ability were demonstrated using a system calorimeter under conditions similar to the application. The investigated C/C-SiC composite has significant application potential as a structural material for thermal energy storage systems with mPCM.     

盘中的意式美学

正现任金陵饭店太平洋西餐厅主厨的Nino,是一位意大利人,来金陵饭店工作快2年,用他的话说,"这里是我的家"。Nino非常喜欢中餐,做得一手美味的意大利菜,他总是有很多创意和想法,对食材的新鲜度要求严格,并注重摆盘的造型与色彩搭配,在心血来潮的时候会做出几道新菜,然后豪气地告诉小编尽情品尝,但是没有菜名!这可难住了每道菜必问菜名的小编,下面来欣赏一下"没有菜名"的意式美食,说不定能帮Nino起一个同样有美感的菜名。     

Hydroxyoctadecadienoic Acids Regulate Apoptosis in Human THP‐1 Cells in a PPARγ‐Dependent Manner

Macrophage apoptosis, a key process in atherogenesis, is regulated by oxidation products, including hydroxyoctadecadienoic acids (HODEs). These stable oxidation products of linoleic acid (LA) are abundant in atherosclerotic plaque and activate PPARγ and GPR132. We investigated the mechanisms through which HODEs regulate apoptosis. The effect of HODEs on THP‐1 monocytes and adherent THP‐1 cells were compared with other C18 fatty acids, LA and α‐linolenic acid (ALA). The number of cells was reduced within 24 hours following treatment with 9‐HODE (p < 0.01, 30 μM) and 13 HODE (p < 0.01, 30 μM), and the equivalent cell viability was also decreased (p < 0.001). Both 9‐HODE and 13‐HODE (but not LA or ALA) markedly increased caspase‐3/7 activity (p < 0.001) in both monocytes and adherent THP‐1 cells, with 9‐HODE the more potent. In addition, 9‐HODE and 13‐HODE both increased Annexin‐V labelling of cells (p < 0.001). There was no effect of LA, ALA, or the PPARγ agonist rosiglitazone (1μM), but the effect of HODEs was replicated with apoptosis‐inducer camptothecin (10μM). Only 9‐HODE increased DNA fragmentation. The pro‐apoptotic effect of HODEs was blocked by the caspase inhibitor DEVD‐CHO. The PPARγ antagonist T0070907 further increased apoptosis, suggestive of the PPARγ‐regulated apoptotic effects induced by 9‐HODE. The use of siRNA for GPR132 showed no evidence that the effect of HODEs was mediated through this receptor. 9‐HODE and 13‐HODE are potent—and specific—regulators of apoptosis in THP‐1 cells. Their action is PPARγ‐dependent and independent of GPR132. Further studies to identify the signalling pathways through which HODEs increase apoptosis in macrophages may reveal novel therapeutic targets for atherosclerosis.     

Extracting dust from soil: a simple solution to a tricky task

Air quality is commonly assessed by the ambient concentration of airborne particles sized smaller than 10 microm (PM10). However, in addition to concentration, particle shape as well as the type and bioaccessibility of elements adsorbed to this particulate fraction are likely to be related to subsequent respiratory health effects. In order to investigate this relationship, a relatively large mass of the relevant size fraction is needed since sample preparation is necessary prior to analysis. Most existing methods for sampling dust have been developed for analysing the dust directly, without prior handling or digestion. In order to provide sufficient material to be used for subsequent bioaccessibility analysis, these methods require repetitive and time consuming sampling as well as special equipment and procedures which are high in both cost and maintenance. This paper describes an inexpensive and relatively simple procedure for extracting the PM10 fraction from soil to be used for lung bioaccessibility studies. The method described involves dry and wet sieving in order to exclude larger size fractions as far as possible. Vacuum filtering of the wet-sieved soil solution through a 10 microm mesh was then employed to extract the required fraction. In order to avoid frequent blocking of the mesh, Stokes's law was applied in the construction of a tube which enables separation of the solution holding the smallest fraction.     

‘Living outside the house’: how families raising young children in new,private high-rise developments experience their local environment

ABSTRACT

Families are increasingly choosing to raise children in the growing number of private, high-rise apartment complexes developed in Australian capital cities. However, most of these developments have been designed for the childless and there are concerns as to how supportive these settings are for young children. This paper explores parents’ experiences of the environment surrounding their high-rise dwellings in an inner-city municipality of Melbourne, Australia using the participatory method, Photovoice. Ten parents photographed elements of their dwellings and environments that had positive or negative impacts on raising young children. Findings indicate that environments surrounding parents’ high-rise dwellings were used on a daily basis, often due to limited space within apartment complexes. However, aspects of this environment were challenging, requiring mutual accommodation between families and their immediate settings. This has implications for policy to ensure the neighbourhoods surrounding high-rise developments in inner-city areas are more child friendly.     

Estimating person-to-person variability in VOC emissions from personal care products used during showering

An increasing fraction of volatile organic compounds (VOC) emissions come from the domestic use of solvents, contained within myriad commonplace consumer products. Emission rates are often poorly characterized and depend significantly on individual behavior and specific product formulation and usage. Time-concentration profiles of volatile organic compounds (VOCs) arising from the use of a representative selection of personal care products (PCPs) during showering are generated, and person-to-person variability in emissions calculated. A panel of 18 participants used a standardized set of products, dosages, and application times during showering in a controlled indoor bathroom setting. Proton transfer mass spectrometry was used to measure the in-room VOC evolution of limonene (representing the sum of monoterpenes), benzyl alcohol, and ethanol. The release of VOCs had reproducible patterns between users, but noticeable variations in absolute peak concentrations, despite identical amounts of material being used. The amounts of VOC emitted to air for one showering activity were as follows: limonene (1.77 mg ± 42%), benzyl alcohol (1.07 mg ± 41%), and ethanol (0.33 mg ± 78%). Real-world emissions to air were between 1.3 and 11 times lower than bottom-up estimates based on dynamic headspace measurements of product emissions rates, likely a result of PCPs being washed away before VOC evaporation could occur.     

Crystallization in Confinement

Many crystallization processes of great importance, including frost heave, biomineralization, the synthesis of nanomaterials, and scale formation, occur in small volumes rather than bulk solution. Here, the influence of confinement on crystallization processes is described, drawing together information from fields as diverse as bioinspired mineralization, templating, pharmaceuticals, colloidal crystallization, and geochemistry. Experiments are principally conducted within confining systems that offer well-defined environments, varying from droplets in microfluidic devices, to cylindrical pores in filtration membranes, to nanoporous glasses and carbon nanotubes. Dramatic effects are observed, including a stabilization of metastable polymorphs, a depression of freezing points, and the formation of crystals with preferred orientations, modified morphologies, and even structures not seen in bulk. Confinement is also shown to influence crystallization processes over length scales ranging from the atomic to hundreds of micrometers, and to originate from a wide range of mechanisms. The development of an enhanced understanding of the influence of confinement on crystal nucleation and growth will not only provide superior insight into crystallization processes in many real-world environments, but will also enable this phenomenon to be used to control crystallization in applications including nanomaterial synthesis, heavy metal remediation, and the prevention of weathering.