Potential of pulsed electric field to control Aspergillus parasiticus,aflatoxin and mutagenicity levels: Sesame seed quality

Seed processing technologies are essential for seed safety and functionality through protection of physicochemical quality, pathogen inactivation, aflatoxin detoxification and alleviation of mutagenicity. Design of a pilot-scale unit of pulsed electric fields (PEF) to treat sesame seeds with respect to quality parameters, Aspergillus parasiticus inactivation and aflatoxin reduction as well as alleviation of aflatoxin mutagenicity were prompted in this study. PEF energy ranged from 0.97 to 17.28 J achieved maximum reductions of peroxide value and acidity number of 67.4 and 85.7%, respectively, and did not change color L*, a*, b* and hue values. A 60% reduction of A. parasiticus counts occurred at the maximum PEF energy. Aflatoxins G1, G2, B1, and B2 contents decreased by 94.7, 92.7, 86.9, and 98.7%, respectively. Except for the samples treated by 2.16 J with 100 μg/plate and by 6.80 J with 10 μg/plate, PEF treatment provided elimination of aflatoxin mutagenity. It is concluded that PEF treatment can be used to treat sesame seeds with preservation of physicochemical properties, inactivation of A. parasiticus and decomposition of aflatoxins with reduced mutagenicity.     

Inhibition of atmospheric corrosion of mild steel by sodium benzoate treatment

The objective of this study was to evaluate the effectiveness of sodium benzoate as an inhibitor to slow down or prevent atmospheric corrosion/discoloration of the local mild steel during storage in the Arabian Gulf region. Test specimens were prepared from locally produced reinforcing steel products. The inhibitor solution was applied on steel specimens at a concentration of 100 mM for 1 day at room temperature. Wooden exposure racks were used to hold as-received and inhibitor-treated specimens during atmospheric exposure for different periods. Corrosion was evaluated through weight loss determination and electrochemical technique. As expected, the Arabian Gulf atmosphere was corrosive on the as-received local mild steel. On the other hand, treatment of steel with sodium benzoate lowered its corrosion rate during initial days of its exposure to atmosphere. However, atmospheric corrosion inhibition performance of sodium benzoate deteriorated with exposure time after 30 or more days of atmospheric exposure, and the corrosion rates of sodium benzoate-treated specimens reached that of the unprotected specimens at the end of 90 days of atmospheric exposure.     

Performance failure analysis of EDFA cascades in optical DWDM packet-switched networks

A simple and comprehensive technique to determine the probability that a cascade of erbium-doped fiber amplifiers (EDFAs) may be driven into unacceptable regimes of bit error rate (BER) and/or gain levels is presented. This technique allows network designers to determine the tolerances by which the signal power levels may deviate from their predesigned average values and still give acceptable gain variances and BERs at the receiver. We show that even in the signal power range well above the receiver sensitivities (-38 dBm/ch) where the gain spread is not significant, the corresponding spread in BER due to random arrival of packets might result in unacceptable performance. We show for typical levels of operation, the BER temporarily (for about 3 /spl mu/s) deviates to below 10/sup -9/ (10/sup -15/) with a probability of 10/sup -3/ (10/sup -2/), for 100 (64) channels. We show that the gain spread for a single EDFA can be negligible for a range of signal and pump powers at a given average gain.     

Investigation of the Effects of some Parameters in the Production of Chromate from Chromite Ores in Iskenderun Region

The conversion of chromite ore from iskenderun region into chromate was investigated. Firstly, the chromite ore was analysed using conventional chemical methods. Then, the effect of some parameters such as roasting time, temperature and the amount of additives on the conversion efficiency to the chromate was examined. The optimum roasting conditions were determined as 300°C, 2 hours, 10 times the stoichiometrically required amounts of NaClO₃ and 6 times the stoichiometrically required amounts of KOH. Under these conditions, the maximum recovery of chromate was found to be 100%. The product obtained from the roasting process was leached with water to produce a clean chromate solution. The effect of temperature and solid/liquid (S/L) ratio was investigated in the water leaching experiments. The optimum experimental results obtained were 100% at a 1:5 solid to water ratio at 25°C and 20 min leaching period. The chromate solution was purified using conventional purification processes.     

Degradation of 4-chloro-2-methylphenol in aqueous solution by electro-Fenton and photoelectro-Fenton processes

Degradation of 4-chloro-2-methylphenol (PCOC), a refractory toxic chemical emitted to the environment from the industrial production of phenoxy herbicides was studied in aqueous solution. Electro-Fenton and photoelectro-Fenton processes were used as the degradation methods. H₂O₂, produced by the reduction of oxygen at carbon cathode reacted with dissolved metal ions to form hydroxyl radicals, which in turn reacted with PCOC sequentially to degrade the aromatic ring. The effects of using different [Fe²⁺]/[PCOC]₀ and the effect of replacing Fe²⁺ by Mn²⁺ ion have been examined. It was found that degradation rate was increased with increasing [Fe²⁺]/[PCOC]₀ ratio from 2 to 4. However, the total charge utilized during the treatment was also increased. The efficiency of PCOC degradation was observed to be higher when Mn²⁺ was used as the catalyst. The mineralization of aqueous solutions of PCOC, withdrawn from the reactor at certain time interval, has been followed by total organic carbon (TOC) decay and dechlorination. A fast and complete degradation of the aromatic ring was achieved in photoelectro-Fenton system. 41.7% TOC decay and complete dechlorination were observed by consuming only 141.4 C electrical charge during a 300 min photoelectron-Fenton treatment. In the case of electro-Fenton system, 280.7 C electrical charge was consumed during 450 min of electrolysis to attain a similar degradation of PCOC. 14.9% TOC removal and 89.3% dechlorination have been obtained in this system under the applied conditions.     

Synthesis and properties of chitosan-modified poly(vinyl butyrate)

Modification of chitosan by grafting of vinyl butyrate was carried out in homogeneous phase using potassium persulfate as redox initator and 1.5% acetic acid as solvent. The percent grafting and grafting efficiency were analysed and the high grafting efficiency up to 94% was observed. The effects of reaction variables such as monomer concentration, initiator concentration, temperature and reaction time were investigated. It was observed that the solubility of chitosan was markedly reduced after grafting with vinyl butyrate. The grafted product is insoluble in common organic solvents as well in dilute organic and inorganic acids. Characterization of the graft copolymers were carried out by using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) technics. Characteristic signal of carbonyl group was observed at 1,731 cm⁻¹ which belongs to the poly vinyl butyrate segments in the graft copolymer. The melting transition of the chitosan main chain in the copolymer shifted to 124°C from its original value 101°C. In addition to these, we have also studied topology of the graft copolymer and the SEM micrograph showed continuous homogenous matrix which means there is no phase separation.     

An experimental evaluation of visual similarity for HDR images

In this paper, we investigate visual similarity for high dynamic range (HDR) images. We collect crowdsourcing data through a web-based experimental interface, in which the participants are asked to choose one of the two candidate images as being more similar to the query image. Triplets forming the query-and-candidates sets are obtained by random sampling from existing HDR data sets. Experimental control factors include choice of tone mapping operator (TMO), choice of distance metric, and choice of image feature. The image features that we experiment with are chosen from the features that are commonly used in the usual low dynamic range setting including features learned via Convolutional Neural Networks. The set of image features also includes combined features where the combination coefficients are estimated using logistic regression. We compute correlations between human judgments and quantitative features to understand how much each feature contributes to visual similarity. Combined features yield nearly 84% agreement with human judgments when applied on tone mapped images. Though we observed that using common features directly on raw or linearly scaled HDR images yield subpar correlation estimates compared to using them on tone mapped HDR images, we did not observe significant effect due to the choice of TMO on the estimates. As an application, we propose an improvement to style-based tone mapping for more correctly imparting desired styles to HDR images with different characteristics.

     

Fuzzy multiattribute evaluation of R&D projects using a real options valuation model

R&D project selection decision is very important in two ways. First, in many organizations, R&D budget represents huge investment. Project selection decisions could be thought with the strategic objectives and plans of the firm. Second, R&D projects' organizational returns are multidimensional in nature and risky in terms of projected outcome. Real options approach helps to calculate this risky side of the selection process. This paper considers that multidimensional side of the R&D project selection process. Another consideration is the vagueness in the evaluation process. The fuzzy analytic hierarchy process, which takes monetary (fuzzy real option value) and nonmonetary (capability, success probability, trends, etc.) criteria into account, is used to make this selection among alternative R&D projects. A real case study is given to illustrate the application of the proposed approach. © 2008 Wiley Periodicals, Inc.     

A tabu-search based heuristic for the hub covering problem over incomplete hub networks

Hub location problems deal with finding the location of hub facilities and with the allocation of demand nodes to these located hub facilities. In this paper, we study the single allocation hub covering problem over incomplete hub networks and propose an integer programming formulation to this end. The aim of our model is to find the location of hubs, the hub links to be established between the located hubs, and the allocation of non-hub nodes to the located hub nodes such that the travel time between any origin–destination pair is within a given time bound. We present an efficient heuristic based on tabu search and test the performance of our heuristic on the CAB data set and on the Turkish network.