再养护液对受高温后高强混凝土的渗透性能的影响

采用3种再养护液,即水、硫酸铝溶液及氟硅酸镁-硅酸钠溶液,研究了再养护液对掺加聚丙烯纤维及2种不同掺合料的高强混凝土经500℃高温后的湿迁移渗透系数及氯离子渗透系数的影响,并从显微结构和孔分布分析了渗透机理.研究表明:经3种养护液浸泡,高温后高强混凝土的湿迁移渗透系数及氯离子渗透系数降低,高强混凝土水泥浆体的孔隙率降低,孔径减小,形成了新的水化产物.     

高强混凝土受火后力学性能变化规律的研究

对受火后的混凝土试件进行了抗压强度、抗折强度和劈裂抗拉强度试验,讨论了温度、强度等级、试件尺寸、含水量对其高温后力学性能的影响。研究表明,受火后,抗折强度较抗压强度下降更快;高强度的混凝土在600℃前抗压强度下降不多;大尺寸混凝土试件较小尺寸混凝土试件的残余抗压强度下降慢;混凝土试件的含水率越高,相对残余抗压强度越低。采用超声波速度法和质量损失法对火灾高温后混凝土内部结构的变化进行了探讨。     

连续纤维增强热塑性树脂基复合材料拉挤工艺研究与应用现状

拉挤工艺是一种能够经济的连续生产复合材料的典型制造工艺，它不但具有其它成型方法的优点，而且还具有其它工艺所不具备的优点，如生产效率高，重复性好，长度可任意切断，省原料、省能耗等。本文简要介绍了连续纤维增强热塑性树脂基复合材料拉挤工艺研究与应用的现状，包括目前国内外主要的拉挤工艺，以及拉挤工艺过程的若干工序。     

加固用复合材料力学性能的影响因素

在土木工程中，混凝土结构的加固补强要求连续纤维增强树脂基复合材料应具有较高的抗拉强度、弹性模量和一定的断裂延伸率，本文探讨了在一定成型工艺和环氧树脂基体的条件下，影响这些性能的因素．试验表明，纤维品种、纤维表面处理方法、片材厚度对这些性能有显著的影响；纤维束或纤维布与树脂基体复合固化后，由于固化应力的作用，其增强效率将大大下降。对此，在加固设计时应予以重视。     

Calculation of alkali silica reaction (ASR) induced expansion before cracking of concrete

A calculation method for predicting the formation of alkali-silica gel and analyzing the relationship of ASR induced expansion and aggregate size was proposed. The complicated chemistry of alkali silica reaction was simplified to be controlled by the diffusion process of chemical ions into reactive aggregates. The transport of chemical ions was described by the Fick’s law. The ASR induced expansion was assumed to be directly related to the volume of produced alkali-silica gel. The finally expansion of a representative volume element (RVE) of concrete was then calculated according to the ratio of volume of alkali-silica gel and RVE. The input parameters of the model contains radius of reactive aggregate, volume fraction of reactive aggregate, initial concentration of chemical ions and porosity of cement paste. The applicability of the model was validated by an experiment of ASR-affected concrete specimens containing glass aggregate. It is shown that the amount of alkali-silica gel and ASR induced expansion can be well predicted. The expansion increasing with the decreasing aggregate size can be reproduced by the proposed model.     

微生物水泥研究与应用进展

微生物诱导碳酸钙沉积(MICP),即利用微生物代谢活动中矿化行为,诱导形成碳酸钙沉淀,其具有特殊的胶结作用,可作为一种新颖的生物胶凝材料—微生物水泥。本文从MICP矿化机制、胶结机理以及微生物水泥在岩土工程中的应用等方面探讨了相应的最新进展,分析了目前存在的问题,并对微生物水泥的进一步研究提出了思路和建议。     

Effect of borax on hydration and hardening properties of magnesium and pottassium phosphate cement pastes

Magnesium and potassium phosphate cement (MKPC) sample were prepared by mixing dead burnt MgO powder, potassium phosphate and different dosages of retarder borax to investigate the effect of borax on its hydration and hardening characteristics. The pH value, fluidity, hydration temperature and strength development of MKPC paste were investigated, and the mineralogical composition and microstructural morphology of its hydration products were analyzed. The experimental results indicated that, within a certain dosage, borax caused an endothermal effect for MKPC paste, which decreased the early hydration rate of MKPC paste, increased the fluidity of MKPC paste. Thus, strength and micro-morphology of hardened MKPC are affected. It can be concluded that borax in MKPC paste retards the early hydration rate of MKPC paste by forming a film onto surface of MgO, decreasing the temperature and increasing the pH value of the system. As borax dosage varying, different factors may dorminate the effects.     

混凝土化学外加剂与碱—集料反应

外加剂是混凝土中碱的重要来源之一,这些碱与水泥熟料中的碱一样也将参与碱-集料反应。目前,我国应用的防冻剂、早强剂中大部分含有大量碱金属盐,且掺量很高,它们引入混凝土中的碱量往往就已远远大于许多国家规定的单位碱含量的安全极限值。文章呼吁有关部门应对此予以重视,并尽早采取有效措施。     

NO2浓度对水泥基材料负载纳米TiO2光催化性能的影响

研究鉴于汽车尾气排放后首先与路面材料接触的事实,探讨路面材料负载光催化剂实现尾气二次净化的目的.针对路面水泥基材料负载纳米TiO2光催化氧化汽车尾气中的氮氧化物,首重研究模拟气源NO2的浓度对催化反应的影响.试验和分析表明,水泥基材料负载纳米TiO2光催化氧化NO2浓度提高呈线性下降:水泥基材料负载纳米TiO2光催化反应速率随NO2浓度提高而加快;若载体具有吸附被光催化氧化气体的能力,可加快负载TiO2的光催化反应.