碳酸钾生产中吹脱除氨新工艺实验研究

在离子交换法生产碳酸钾的基础上,将原有蒸发除氨工艺改为真空加热吹脱除氨工艺.进行了常压加热除氨、真空加热除氨、常压加热吹脱除氨和真空加热吹脱除氨4种工艺方法的实验研究和比较.结果表明,在实验条件下离子交换液的温度、蒸氨时间、气相压力和吹脱气量等对铵离子的分解率有很大影响.真空加热吹脱除氨效果显著.     

波纹板填料的流体力学性能

应用商用Fluent软件,采用RNG k-?湍流模型,对波纹板填料内三维气相流场进行了数值模拟研究。结果发现,气体从填料底部进入后,大部分气体流入波纹板波谷,并沿波纹板倾角方向流动,此时气体流速较大,压降较小;小部分气体在波纹板波锋区域流动,方向曲折向上,气体流速较小,压降也较大;不同气体动能因子下填料的干板压降模拟值与Billet模型预测值、文献实验数据吻合较好;在理想波纹板填料模型中,气体沿波纹板倾角方向流动碰到塔壁时,转向相邻板片波纹倾角的方向流动,实际应用中容易出现壁流现象。本研究对波纹板填料结构改型及应用具有重要指导意义。     

Mellapak 350Y填料气相流流场数值模拟研究

采用周期性边界条件对大体积Mellapak350填料内部三维气体流场进行数值模拟研究。结果发现:气体在波纹板波峰、波谷和开孔处均有流动,在波纹板波谷处,气体流速较大、压力较小、湍动能较大;在波纹板波峰处,气体流道复杂、受干扰较大,气体流速较小、压力较大、湍动能较小;模拟计算的填料干板压降模拟值与经验关联式计算值误差在14%之内,吻合较好。     

Rheological properties of salt-tolerant HPAM solutions with ultrahigh molecular weight

The rheological properties of salt-tolerant partially hydrolyzed polyacrylamide(HPAM)solutions with molecular of 2.5×107 g/mol at different concentrations were measured in steady-state shear flow mode by Haake Rheostress 150 rheometer.Three constitutive equations(Oldroyd four constant model,Guesekus model and FENE-P model) were used for describing the apparent viscosity and first normal stress difference.The apparent viscosity of salt-tolerant HPAM solutions appears a first Newtonian zone when the shear rate is approximately lower than 0.2 s-1.At high shear rate,the HPAM solutions show shear-thinning and elasticity.The results show that the FENE-P model has the best agreement between theoretical and experimental data within the available shear rate range.The material parameters are useful for numerical analysis of polymer solution flow fields.     

双螺带桨Metzner常数的模拟计算

Using the multiple reference frames （MRF） impeller method, the three-dimensional non-Newtonian flow field generated by a double helical ribbon （DHR） impeller has been simulated. The velocity field calculated by the numerical simulation was similar to the previous studies and the power constant agreed well with the experimental data. Three computational fluid dynamic （CFD） methods, labeled Ⅰ, Ⅱ and Ⅲ, were used to compute the Metzuer constant k5. The results showed that the calculated value from the slop method （method Ⅰ） was consistent with the experimental data. Method Ⅱ, which took the maximal circumference-average shear rate around the impeller as the effective shear rate to compute ks, also showed good agreement with the experiment. However, both methods suffer from the complexity of calculation procedures. A new method （method Ⅲ） was devised in this paper to use the area-weighted average viscosity around the impeller as the effective viscosity for calculating k5. Method Ⅲ showed both good accuracy and ease of use.     

一种多翼离心风机流场模拟与性能分析

综合多叶片离心风机噪音低以及长短叶离心风机气流稳定的优点,设计了一种具有大小叶片交错组合结构的多翼离心风机.采用计算流体力学方法,分别模拟了前向式和后向式2种不同叶轮形式的风机流场.通过对比发现,在相同转速和流量下,后向式风机进出口压差比前向式叶轮风机小11.8％,但功率消耗降低了24.5％,综合效率较前向式高;后向式...     

非牛顿流体搅拌流场的数值模拟研究进展

对非牛顿流体搅拌流场数值模拟过程中的控制方程、旋转桨叶的处理以及数值计算方法三个方面进行了综合论述。阐述了广义牛顿流体模型形式简单、计算量低,在非牛顿流体搅拌流场数值模拟过程中应用广泛;黏弹性流体本构方程具有高度的非线性,采用计算流体力学(CFD)方法对其搅拌流场进行数值模拟难度较高,目前仍处于起步阶段;通过合理简化黏弹性流体本构方程以及采用恰当的数值离散方法,有助于在黏弹性流体的搅拌流场数值模拟中取得进展。     

工业萘塔工程计算及塔内件设计

基于现代传质分离理论、过程分析与优化方法、计算流体力学等对工业萘塔的煤焦油加工系统的研究开发和工程设计进行了工艺流程模拟和流体力学核算,并采用喷射型导向梯形浮阀(SGTV)塔板作为工业萘塔塔板.该设计技术成功应用于300 kt/a煤焦油深加工工程.开车以来,全塔系统运行平稳,操作易于控制,产品质量高,塔顶产品中萘含量高速97.6%,总回收率达90.31%,生产能力达到预期标准,同时能耗也显著降低,该装置是国内单套处理量最大的煤焦油深加工装置之一.