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在PBS主链中同时引入己内酯(CL)和1,4-环己烷二甲醇(1,4-CHDM),或CL和二乙醇酸(DGA)得到了PBS-co-PCL-co-CHDM和PBS-co-PCL-co-DGA三元共聚物。通过1H-NMR、FTIR对三元共聚物的结构进行了表征,并采用热分析、广角X射线衍射分析和拉力试验比较了三元共聚物的性能。结果表明:随着CL、1,4-CHDM、DGA的引入,三元共聚物的结晶尺寸有所减小,结晶度降低,与PBS相比晶型略有变化;并且tanδ均增大,而储能模量均降低;在CL同时存在的条件下,1,4-CHDM的加入使共聚物的的玻璃化温度(Tg)上升为-30℃,DGA的加入却使Tg下降为-36℃,但二者的热分解温度仍在300℃以上;改性后三元共聚物的柔韧性增强断,裂伸长率显著提高。 相似文献
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柔性复合材料改造城市燃气管道性能研究 总被引:1,自引:0,他引:1
在西气东输中采用柔性复合材料改造城市原有煤气管道接头来输送天然气是一种经济、实用的方法.本文介绍了一种高性能的聚氨酯-涤纶布-铝箔复合材料内衬的煤气管道接头密封连接结构,还介绍了"诺迪霸工艺",并按有关试验标准,对管道接头密封结构进行了气密性、耐气压、抗弯曲、抗剥离强度及人工加速老化等试验.试验结果证明,这种结构形式和施工工艺性能优良、安全可靠,能够满足天然气输送. 相似文献
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本文阐述了XM-28密封胶和GY-340厌氧密封胶在CK-1高机动靶机油箱上的应用。详细介绍了胶接的表面处理方法、XM-28密封胶的配方试验、密封胶铆试验及其耐温、耐油、耐压试验,并提供了许多试验数据。 经CK-1高机动靶机的多架次试飞证明,这种胶铆和胶接螺接结构及其工艺方法是可行的。 相似文献
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Polyaniline/Attapugite/PE(PAn-ATTP/PE)composites containing particles with core-shell structure were obtained via the two-step blending processs. The experimental condition is as follows: Organo-attapulgite and PAn was obtained by modifying attapulgite with laury benzenesulfonic acid sodium salt and, then added to PE. The electrical conductivity, structure and properties of the composites were studied. Under the function of shear stress, core-shell structure particles with ATTP as the core and PAn as the shell were formed in the composites. The structure of PAn-ATTP/PE composites were characterized by FTIR,XRD,SEM, etc, respectively. The effects of concentration of doping agent on the conductivity and mechanical property of the composites were investigated. The mechanical properties and impact fracture surface of the ternary composites were studied by means of the tensile tester, SEM, etc. The results show that polyaniline encapsulated ATTP enhances the strength of the PE. And the conductivity of PAn-ATTP/PE composites of is improved effectively when polyaniline encapsulated ATTP is added. The composite have good conductivity when 10% polyaniline encapsulated ATTP is added. 相似文献
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