A numerical model to predict the powder–binder separation during micro-powder injection molding

The micro-powder injection molding (micro-PIM) process has the potential to bridge the gap between the design and manufacturing of micro-components that are often used in small and handy devices. Numerical modeling helps to analyze and overcome various difficulties of micro-PIM. In the present work, a numerical model is developed to predict the powder–binder separation (a common defect in PIM and especially severe in micro-PIM) during the injection of an alumina feedstock. A powder–binder separation criterion is proposed dealing with applied injection pressure and friction force between the powder and binder. An indirect comparison of feedstock travel time between two locations is used to validate the model. The predicted segregation from the simulated result is supported by a qualitative experimental measurement. The developed model can be used to optimize injection parameters to get a defect-free product.     

A triptycene derived hypercrosslinked polymer for gas capture and separation applications

This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m² g^?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO₂ capture capacity of 132 mg g^?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g^?1 (77 K, 1 bar). T-HCP revealed high CO₂/N₂ selectivity (up to 63) as well as promising CO₂/CH₄ (up to 9.1) selectivity suggesting its potential applicability for CO₂ separation from flue and natural gases.     

Shock/expansion fan interaction with real gas effects for Earth and Mars atmospheric conditions

Numerical simulations are performed to investigate the real gas effects on shock/expansion fan interaction. Initial perfect gas simulations at low enthalpy capture the flow structures efficiently and outcomes are found to have excellent agreement with the analytical calculations. Furthermore, the simulations with the real gas solver for different enthalpies showed that the variation in enthalpy significantly changes the flow structures. It is observed that an increase in enthalpy leads to a decrease and increase in the postshock and postexpansion fan Mach numbers, respectively. Another important observation is the decrement in the peak pressure ratio with an increment in the enthalpy. These effects are noted to be more pronounced for Mars's environment due to the higher dependency of specific heat on temperature.     

Channel Models for Inter-body Communication in Ultra Wideband-Based Body Area Networks

Wireless Personal Communications - Body area networks (BANs) are evolving tremendously over the years and with the progress in the area of internet of things, the BANs are more important than ever....     

Depicting the role of gas-solid interactions on the hydrodynamics of converging pneumatic riser

The understanding of the flow characteristics and effect of gas-solid interactions in pneumatic risers is fundamental to investigate to ensure effective design cost-effective operation. Thus, to understand the effect of gas-solid interactions on the hydrodynamics of newly proposed conversing risers, this study mainly focused on predicting pressure drop in the dilute phase pneumatic conveying system. The experiments were conducted in a converging riser having a convergence angle of 0.2693°. Various solid particles such as sago, black mustard, and alumina have been considered to study the effect of particle sizes and density on the pressure drop. The experimental outcomes indicate that the total pressure drop increases with an increase in the solid density and gas mass flow rate. Moreover, smaller particle sizes are also increased the pressure drop. An empirical correlation is developed for the prediction of total pressure drop ΔP_T in converging pneumatic riser via dimensional analysis. All dependent variables such as particle and air density, drag force, acceleration due to gravity, the mass flow rate of air and particle, the diameter of particle and converging riser, the height of converging riser were considered to develop the empirical correlation. The established relationship is tested, and experimental data have been fitted for its validation. The estimated relative error of less than 0.05 proved the significance of the developed correlation. Hence, it can be stated that the established relationship is useful in studying the effects of various parameters on the pressure drop across the length of the conversing riser.     

Electrical and magnetic properties of double perovskite: Y2CoMnO6

In this communication, the structural, micro-structural, dielectric, electrical, magnetic, and leakage-current characteristics of a double perovskite (Y₂CoMnO₆) ceramic material have been reported. The material was synthesized via a high-temperature mixed-oxide route. The compound crystallizes in a monoclinic structure which is confirmed from preliminary X-ray structural study. The morphological study by using scanning electron micrograph reveals the almost homogeneous distribution of grains throughout the surface of the sample. The nature of frequency-dependence of dielectric constant has been described by the Maxwell-Wagner model. The occurrence of a dielectric anomaly in the temperature dependence of dielectric permittivity study demonstrates the ferroelectric-paraelectric phase transition in the material. From the Nyquist plots, we found the existence of both grain and grain boundary effects. The frequency dependence of conductivity was studied by the Jonscher’s Power law, and the conduction phenomenon obeys the large overlapping polaron tunneling model. By using the Arrhenius equation, the activation energy has been calculated which is nearly equal to the energy required for the hoping of the electron. Both impedance and conductivity analysis demonstrate that the sample exhibits negative temperature coefficient of resistance (NTCR) properties indicating the semiconducting type of material at high temperatures. The anti-ferromagnetic character of the material is observed from the nature of magnetic hysteresis loop. The leakage current analysis suggests that the conduction process in the material follows the space charge limited conduction phenomenon. Such material will be helpful for modern electronic devices and spintronic applications.     

Interpretable semantic textual similarity of sentences using alignment of chunks with classification and regression

Applied Intelligence - The proposed work is focused on establishing an interpretable Semantic Textual Similarity (iSTS) method for a pair of sentences, which can clarify why two sentences are...     

Surface characteristics and electrolysis efficiency of a Palladium-Nickel electrode

In view to finding a better electrode for water electrolysis-the hydrogen and oxygen evolution efficiencies of a Pd-80 at% Ni electrode along with its surface oxidation-reduction characteristics were investigated in alkaline medium using cyclic voltammetry. On cycling the electrode in between the potential range of ?1.0 to +0.65 V, two oxidation and two reduction transformations were observed. The origins of the transformations were found out. Most of the transformation peak potentials were found to be different than that of Pd and Ni electrodes. The generation of (PdNi)(III) species over the electrode surface identified to be the crucial for the oxygen evolution and continuous cycling up to 100 min succeeded to obtain its saturated layer. Tafel plots for both the hydrogen and oxygen evolution reactions (HER and OER) showed two regions. The kinetic parameters for the HER and OER, i.e., exchange current density at zero overpotential (i_o) and slope (b) values for both the low and high overpotential (η) regions were found out. For the HER, the i_o and b values are found to be 6.17 × 10^?2 and 4.36 mA/cm² and 137.0 and 343.9 mV/dec, respectively. For the OER, the values are 2.83 × 10^?3 and 2.35 mA/cm² and 72.8 and 215.1 mV/dec, respectively. On comparing these kinetic values with that available for Pd, Ni and Pd-50 at% Ni, it is realized that the investigated Pd-80 at% Ni electrode showed better electrolysis efficiencies than that of its component materials and Pd-50 at% Ni electrode.     

Sustainable supply chain management in Indian organisations: an empirical investigation

The present work is an attempt to investigate the adoption of sustainable supply chain management (SSCM) practices amongst manufacturing and process based organisations in India and its impact on organisational performance encompassing all three dimensions of sustainability. SSCM practices conceived in the present study include environmental management practices (EMP), socially inclusive practices for employees (SPE), socially inclusive practices for community (SPC), operations practices (OP) and supply chain integration (SCI) which were treated as exogenous variables. Organisational performance considered in this study includes five dimensions, namely environmental performance (EPR), employee-centred social performance (ESP), community-centred social performance (CSP), operations performance (OPR) and competitiveness, which were regarded as endogenous variables. The analysis was carried out with the help of structural equation modelling considering natural logarithm of manpower as a control variable. Few major findings are mentioned. EMP does not have any significant association with OPR, nor does it result in competitiveness. However, when jointly mediated through both EPR and OPR, EMP leads to competitiveness. SPC has significant negative association with competitiveness, when only direct relationship is considered. However, indirect relationship between SPC and competitiveness shows significant positive association when mediated through CSP. The resultant total effect between SPC and competitiveness turns out to be insignificant. Further, OPR fully mediates the relationship between OP and competitiveness. Managerial implications of the findings are discussed.