Study of the Degradation Effects on Aged Wood Beams from the Cathedral of Morelia,Mexico by Acoustic Birefringence Measurements

Russian Journal of Nondestructive Testing - The present study investigates the influence of degradation effects due to natural aging of wood beams from the Cathedral of Morelia, Mexico by using...     

A context-centered methodology for IoT forensic investigations

International Journal of Information Security - The weakness of the security measures implemented on Internet of Things (IoT) devices, added to the sensitivity of the data that they handle, has...     

Polypyrrole and platinum deposited onto carbon substrate to enhance direct methanol fuel cell electrodes behaviour

The aim of this work is to study the ability of polypyrrole to reduce the platinum load of low temperature methanol fuel cell electrodes. Platinum was deposited onto carbon paper and a layer of polypyrrole electrodeposited onto carbon paper, using electron beam evaporation and electrodeposition by pulses. Subsequently, the morphology and electrochemical behaviour of the synthesised samples were analysed in sulphuric acid solution, determining their electrochemically active surface area; and in a solution of sulphuric acid and methanol, to analyse their catalytic performance. The electrochemical measurements showed that the electrochemically active surface area and the catalytic performance of the electrodes prepared by evaporating platinum are increased when prepared on the polypyrrole film. Electrodes prepared using the pulse electrodeposition technique presented fairly homogeneous coatings that led to the reduction of the oxidation potential of methanol and the increase of their resistance to CO poisoning.     

Synthesis and Theoretical Study of New Guanylated Cyclophosphazenes and Their Use in the CO2 Fixation into Styrene Carbonate

Three new guanylated cyclophosphazenes G1–G3 have been synthesized through the catalytic guanylation of three different bi, tetra and hexa (p-aminophenoxy)-cyclophosphazenes by using N,N’-diisopropylcarbodiimide as guanylating agent, ZnEt₂ as catalyst and dry tetrahydrofuran as solvent. The resulting products have been characterized by ¹H, ¹³C{¹H} and ³¹P{¹H} NMR spectroscopy. The hexaguanylated cyclophosphazenes exhibit a deep purple colour, unusual for this type of compounds. The electronic structure of these compounds was investigated by carrying out density functional calculations at PBE-D3(BJ)/TZP level of theory. The molecular structural analysis reveals that aromatic rings are stacked and time dependent density functional calculations show that a charge transfer electronic transition occurs between the aromatic rings which absorb light around 500–700 nm. Finally, the catalytic usefulness of guanylated cyclophosphazene compounds G1–G3 has been proven by the preparation of styrene carbonate from the reaction between styrene oxide and carbon dioxide.

     

Optical,Morphological, and Structural Properties of Tablets Obtained from Porous Silicon

Silicon - Porous silicon (PS) is a material with a great interest due to its optical (photoluminescent) and chemical (reactive surface) properties, for this reason, it is important to find new ways...     

Electrospinning of gelatin fibers using solutions with low acetic acid concentration: Effect of solvent composition on both diameter of electrospun fibers and cytotoxicity

Gelatin fibers were prepared by electrospinning of gelatin/acetic acid/water ternary mixtures with the aim of studying the feasibility of fabricating gelatin nanofiber mats at room temperature using an alternative benign solvent by significantly reducing the acetic acid concentration. The results showed that gelatin nanofibers can be optimally electrospun with low acetic acid concentration (25%, v/v) combined with gelatin concentrations higher than 300 mg/mL. Both gelatin solutions and electrospun gelatin mats (prepared with different acetic acid aqueous solutions) were analyzed by Fourier transform infrared spectroscopy and differential scanning calorimetry techniques to determine the chemical and structural changes of the polymer. The electrospun gelatin mats fabricated from solutions with low acetic acid content showed some advantages as the maintenance of the decomposition temperature of the pure gelatin (～ 230°C) and the reduction of the acid content on electrospun mats, which allowed to reach a cell viability upper than 90% (analyzed by cell viability test using human dermal fibroblast and embryonic kidney cells). This study has also analyzed the influence of gelatin and acetic acid concentration both on the solution viscosity and the electrospun fiber diameter, obtaining a clear relationship between these parameters. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42115.     

Thermal properties of duck fatty liver (foie gras) products

Thermal properties of duck fatty liver (foie gras), foie gras emulsion and fatty liver fat, as well as regular duck fat, were determined as a function of temperature. Density of foie gras and foie gras fat and emulsion at 20°C was measured as 947, 836, and 928 kg/m³, respectively. Differential scanning calorimetry thermograms for foie gras fat resulted in melting points ranging from –20 to 40°C. Values for the specific heat at 65°C for the fatty liver, its emulsion and fat, and duck fat were 1.79, 2.38, 1.71, and 2.48 J/g°C, respectively. Thermal conductivity of foie gras (organ) and its emulsion at 40°C was determined as 0.330 and 0.428 W/m°C, respectively. Mathematical models based on composition and temperature were developed for all the thermal properties obtained in this work.     

Synthesis of planar inductors in low temperature co-fired ceramic technology

A simple bisection algorithm for the synthesis of planar inductors using a fast electromagnetic analysis algorithm is presented in this work. Both bisection and electromagnetic analysis algorithms are based on a set of heuristic and physical rules obtained from the study of the electromagnetic behavior of these planar devices. With this procedure, the benefits are two fold: (i) the number of iterations is kept moderately low in the synthesis loop, and (ii) the analysis at each iteration step is speed up without compromising accuracy. The algorithm is applied to the development of an inductor library for a low temperature co-fired ceramic process technology.