复合外加剂改性盐石膏的研究

盐石膏的主要成分为无水硫酸钙,其活性差、凝结硬化慢、强度低,需要添加活性剂来激发盐石膏的活性。通过复合外加剂对盐石膏加以改性,并通过XRD和SEM对其作用机理做了分析。结果表明,单掺脱硫石膏和建筑石膏均能缩短盐石膏的凝结时间,建筑石膏的效果较好,但掺量不宜过高。复掺建筑石膏和缓凝剂时,两者比例要控制得当,适宜的建筑石膏和缓凝剂掺量分别为50%和0.10%~0.12%（质量分数）。分析可知,大掺量建筑石膏会增加盐石膏硬化体中二水相和针棒状晶体的含量;缓凝剂掺量的增加,会降低盐石膏硬化体中二水相的含量,棱形晶体增多,从而降低了盐石膏的强度。     

Boundary element analysis of thermal stress intensity factors for interface griffith and cusp cracks

The thermal stress intensity factors for interface cracks of Griffith and symmetric lip cusp types under vertical uniform heat flow in a finite body are calculated by the boundary element method. The boundary conditions on the crack surfaces are insulated or fixed to constant temperature. The relationship between the stress intensity factors and the displacements on the nodal point of a crack-tip element is derived. The numerical values of the thermal stress intensity factors for an interface Griffith crack in an infinite body are compared with the previous solutions. The thermal stress intensity factors for a symmetric lip cusp interface crack in a finite body are calculated with respect to various effective crack lengths, configuration parameters, material property ratios and the thermal boundary conditions on the crack surfaces. Under the same outer boundary conditions, there are no appreciable differences in the distribution of thermal stress intensity factors with respect to each material property. However, the effect of crack surface thermal boundary conditions on the thermal stress intensity factors is considerable.     

掺杂铁电纳米粉的液晶的电光特性

铁电纳米粒子悬浮在向列相液晶母体中，增强介电各向异性，而且对施加的电场信号敏感。本文也展示了纳米粒子对所述复合材料可实现的总的相变的作用。这种方法也许可应用于设计新型显示材料。     

Trenched‐Sinker LDMOSFET (TS‐LDMOS) Structure for 2 GHz Power Amplifiers

This paper proposes a new LDMOSFET structure with a trenched sinker for high‐power RF amplifiers. Using a low‐temperature, deep‐trench technology, we succeeded in drastically shrinking the sinker area to one‐third the size of the conventional diffusion‐type structure. The RF performance of the proposed device with a channel width of 5 mm showed a small signal gain of 16.5 dB and a maximum peak power of 32 dBm with a power‐added efficiency of 25% at 2 GHz. Furthermore, the trench sinker, which was applied to the guard ring to suppress coupling between inductors, showed an excellent blocking performance below ?40 dB at a frequency of up to 20 GHz. These results confirm that the proposed trenched sinker should be an effective technology both as a compact sinker for RF power devices and as a guard ring against coupling.     

Droplet de-entrainment by inertial impaction on vertical rods in an air-droplet mixture flow

We experimentally investigate the de-entrainment of droplets by inertial impaction on an array of vertical rods in an air-droplet mixture flow. The de-entrainment efficiencies are measured for a single rod, for a single row of rods, and for a multi-row of rods. We investigate the effects of the droplet mass flux (0.5–5.4 kg/m² s), the droplet Weber number (3000–8000), the air velocity (0–6 m/s), the rod geometry, and the surface roughness on the de-entrainment, and the rod diameter-to-pitch ratio effect on the de-entrainment. The results for a single rod show that the de-entrainment efficiency decreases slightly as the droplet mass flux increases; however, in our experimental ranges, there is negligible dependence on the droplet Weber number, the air velocity, and the surface roughness. The rod geometry affects the de-entrainment efficiency. The results for a single row of rods show that the existence of neighboring rods promotes de-entrainment due to droplet splashing, and we develop a correlation to show the effect of diameter-to-pitch ratio on the de-entrainment. Using information on the de-entrainment efficiencies of a single rod and those of a single row of rods, we propose a correlation that predicts the de-entrainment efficiency for a multi-row of rods with a staggered array. The RMS errors of the correlation from the de-entrainment efficiencies experimentally obtained are within 13.5%.     

Synthesis and comparative molecular field analysis (CoMFA) of antitumor 3-arylisoquinoline derivatives

In this study a series of 3-arylisoquinoline derivatives were synthesized and cytotoxicity against human melanoma tumor cell evaluated, and a three dimensional quantitative structure-activity relationship was investigated using the comparative molecular field analysis (CoMFA). The results suggested that the electrostatic, steric and hydrophobic factors of 3-arylisoquinolines were strongly correlated with the antitumor activity. Considerable predictive ability (cross-validated r2 as high as 0.721) was obtained through CoMFA.     

基于排序损失的ECC多标签代码异味检测方法

代码异味是由糟糕的代码或设计问题引起的一种软件特征,严重影响了软件系统的可靠性和可维护性.在软件系统中,一段代码元素可能同时受到多种代码异味的影响,使得软件质量明显下降.多标签分类适用该情况,将高共现的多个代码异味置于同一标签组,可以更好地考虑代码异味的相关性,但现有的多标签代码异味检测方法未考虑同一段代码元素中多种代码异味检测顺序的影响.对此,提出了一种基于排序损失的集成分类器链(ensemble of classifier chains,ECC)多标签代码异味检测方法,该方法选择随机森林作为基础分类器并采取多次迭代ECC的方式,以排序损失最小化为目标,选择一个较优的标签序列集,优化代码异味检测顺序问题,模拟其生成机理,检测一段代码元素是否同时存在长方法长参数列表、复杂类消息链或消息链过大类这3组代码异味.实验采用9个评价指标,结果表明所提出的检测方法优于现有的多标签代码异味检测方法,F1平均值达97.16%.     

A study on crystallization kinetics of pentaerythritol in a batch cooling crystallizer

The crystallization kinetics of pentaerythritol (PeE) in aqueous solution in the presence of impurity or not in a batch cooling crystallizer was explored. Also, the solubility and the nucleation and crystal growth kinetics of PeE in aqueous solution were investigated. A second-order dependence of PeE growth rate on supersaturation is observed in pure PeE-water system. The crystal growth rate of PeE-water system in the presence of impurity is proportional to the supersaturation to the 3.5 power. The nucleation and crystal growth behaviors for PeE-water system in a batch cooling crystallizer were grasped according to Mersmann's criteria. The nucleation in this crystallizer was found to act with heterogeneous nucleation. In this system, it suggests that the crystal growth is controlled by a complex mechanism behavior of surface integrated and diffusion limited. Simplified relation was derived for calculation of mean crystal size of product crystals from the batch cooling crystallizer. The obtained relation was verified by a set of experiments.     

Preparation and characterization of syndiotactic polystyrene/ethylene‐propylene copolymer blends

The reactive compatibilization of syndiotactic polystyrene (sPS)/oxazoline‐styrene copolymer (RPS)/maleic anhydride grafted ethylene‐propylene copolymer (EPR‐MA) blends is investigated in this study. First, the miscibility of sPS/RPS blends is examined by thermal analysis. The cold crystallization peak (T_cc) moved toward higher temperature with increased PRS, and, concerning enthalpy relaxation behaviors, only a single enthalpy relation peak was found in all aged samples. These results indicate that the sPS/RPS blend is miscible along the various compositions and RPS can be used in the reactive compatibilization of sPS/RPS/EPR‐MA blends. The reactive compatibilized sPS/RPS/EPR‐MA blends showed finer morphology than sPS/EPR‐MA physical blends and higher storage modulus (G') and complex viscosity (η*) when RPS contents were increased. Moreover, the impact strength of sPS/RPS/EPR‐MA increased significantly compared to sPS/EPR‐MA blend, and SEM micrographs after impact testing show that the sPS/RPS/EPR‐MA blend has better adhesion between the sPS matrix and the dispersed EPR‐MA phase. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2084–2091, 2002