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1.
Journal of Materials Science: Materials in Electronics - Non-volatile organic memory devices were fabricated using polystyrene sulfonate (PSS)?+?nitrogen-doped multi-walled carbon...  相似文献   
2.

InN thin films are grown on sapphire substrates by remote plasma-assisted metal organic chemical vapor deposition while varying the indium pulse length and substrate temperature. The effects of the indium pulse length and temperature on the structural, morphological, electronic, and optical properties of the thin films are studied. The structural parameters are determined by X-ray diffraction and X-ray photoelectron spectroscopy and the effects of incorporating oxygen atoms in the structure is described. The N K-edge X-ray absorption spectroscopy (XAS) and X-ray emission spectroscopy (XES) measurements are used to determine the band gap and it is found to be 1.80?±?0.25 eV for all samples. A complementary measurement namely, X-ray excited optical luminescence measurement is performed to confirm the band gap value obtained from XAS and XES measurements. O K-edge XAS measurements are performed to determine the presence of oxygen impurities in the samples. Meanwhile, we carry out the density functional theory calculations for Wurtzite InN, hypothetical Wurtzite-type InO0.5N0.5, and InO0.0625N0.9375 structures. We find that the measured N-edge spectra agree well with our Wurtzite InN calculations and the measured O K-edge spectra agree better with hypothetical Wurtzite-type InO0.0625N0.9375 than Wurtzite-type InO0.5N0.5.

  相似文献   
3.
Huang J.  Ni D.  Ni X.  Chen W.  Fu Y. 《丝绸》2022,(12):187-196
Silk is a kind of natural fiber with good luster strength elasticity dyeability hygroscopicity and other advantages. Silk products are quite popular to the customers because of their excellent performance such as heat preservation air permeability and so on which make them comfortable to use. Silk floss which is made from pupa lining secondary cocoon etc. can be used as floc and filler materials and is an important part of silk products. According to its production mode silk floss can be divided into manual silk floss and machine-made silk floss and the latter has become the main processing mode of silk floss production due to its high production efficiency. In terms of composition silk flossing generally contains 20% - 30% sericin pupa oil and impurities so in the degumming process in addition to adding sodium carbonate and other degumming agents to remove sericin a large amount of hydrogen peroxide with strong oxidation property is also used to increase the cleanliness and smoothness. Unfortunately hydrogen peroxide is highly flammable and explosive and poses a risk in transportation and storage causing potential safety hazards to the silk processing industry. In order to solve this problem we innovatively propose two hydrogen peroxide-free processing methods of machine-made silk floss by using sodium percarbonate degumming or sodium carbonate-ozone. As an environmentally friendly solid oxidant sodium percarbonate can produce hydrogen peroxide and sodium carbonate after decomposition and is often used to degrade organic harmful substances. Similarly ozone is a common strong oxidant with broad-spectrum antibacterial properties and because ozone can be produced instantly by ozone generators there is no risk of transport and storage. Silk is composed of silk fibroin and sericin. Among them silk fibroin is fibrous protein which will swell in hot water while sericin is globular protein which is easy to dissolve in hot water. As a result in this paper heated sodium percarbonate solution and sodium carbonate-ozone system were used to deglue silk floss. The methods were as follows silk floss was degummed three times in boiling 0. 78 g / L sodium percarbonate solution for 30 minutes each time or was degummed three times in boiled 0. 5 g / L Na2 CO3 solution with ozone continuously flow at a rate of 100 mg / L - h for 30 minutes each time. After cleaning and drying the degummed silk floss can be obtained. After the experiment the apparent morphology sericin residual efficiency impurity rate compression resilience whiteness and other silk floss quality indexes of the two methods were analyzed and compared with superior machine-made silk floss processed by commercial way with hydrogen peroxide. The results show that both two processing methods got uniform degumming effect of silk floss and the surface of the single fiber was smooth and the degumming effect was basically the same as that of commercial products prepared with hydrogen peroxide. The sericin residual rate of silk floss was between 3% - 4% which was in line with the requirements of less than 5% of superior silk floss. There was no significant difference between silk floss obtained and commercial superior products in smoothness and whiteness. In conclusion the performance of silk floss in all aspects has reached the standard of superior products that is the sericin content is not more than 5% the impurity content is not more than 0. 1% the compression rate is not less than 45% and the response rate is not less than 92% . Based on the experimental results and analysis it can be concluded that the machine-made silk floss with good performance can be prepared without hydrogen peroxide showing the feasibility of processing machine-made silk floss without hydrogen peroxide which is of great significance to the research and development of a safe and reliable oxidant system for the removal of impurities in silk floss and to further improve the safety of machine-made silk floss production process. © 2022 China Silk Association. All rights reserved.  相似文献   
4.
In this study, the optimal homotopy analysis (OHAM) technique has been examined to solve the laminar magnetohydrodynamic flow (MHD flow) on the upper-convected Maxwell fluid on an isothermal porous stretch surface. A study on the effects of parameters like the relaxation time, suction/injection velocity, as well as the magnetic number on velocity over a sheet was conducted and these results are compared to the corresponding previously available results. It was observed that the thickness of the boundary layer is lowered by enhancing s, β, and M values. Opposing this, it was observed that large β values increase the f(0) magnituIIde. It is found that OHAM is an efficient method capable of giving a greater degree of accuracy in numerical values of flow parameters even after fewer approximations.  相似文献   
5.
The present article investigates the influence of Joule heating and chemical reaction on magneto Casson nanofluid phenomena in the occurrence of thermal radiation through a porous inclined stretching sheet. Consideration is extended to heat absorption/generation and viscous dissipation. The governing partial differential equations were transformed into nonlinear ordinary differential equations and numerically solved using the Implicit Finite Difference technique. The article analyses the effect of various physical flow parameters on velocity, heat, and mass transfer distributions. For the various involved parameters, the graphical and numerical outcomes are established. The analysis reveals that the enhancement of the radiation parameter increases the temperature and the chemical reaction parameter decreases the concentration profile. The empirical data presented were compared with previously published findings.  相似文献   
6.
Journal of Materials Science - The application of ceramics in advanced functional applications often requires thicknesses below a few hundred micrometers, rendering an assessment of the...  相似文献   
7.
Telecommunication Systems - Internet of Things (IoT) has changed the way people live by transforming everything into smart systems. Wireless Sensor Network (WSN) forms an important part of IoT....  相似文献   
8.
The present level of literature on the subject matter indicates that nothing is known on the heat transfer across the couple stress rheological fluid flowing over a vertical avenue with Robin (mixed) wall conditions. The obtained conservation equations of the model are solved through DTM (differential transform method) and RPM (regular perturbation method). The nondimensional parameters obtained are a couple stress parameter, Brinkman number, mixed convection parameter, and Biot number. The computations reveal that flow acceleration and thermal enhancement is induced with increasing mixed convection parameter and Brinkman number for symmetric and asymmetric conditions. Increasing couple stress parameters dwindle the velocity and temperature for symmetric and asymmetric cases. The large values of the mixed convection parameter and Brinkman number increase the Nusselt values at the left wall and reduces at the right wall. The mass flow rate is augmented with the mixed convection parameter and Brinkman number but it is reduced with the couple stress parameter. The DTM, RKSM, and RPM solutions are in good agreement.  相似文献   
9.
Zirconolite-rich full ceramic wasteforms designed to immobilize Pu-bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and nickel (Ni) HIP canisters. A detailed profiling of the elemental compositions of the major and minor phases over the canister–wasteform interaction zone was performed using scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDS) characterization. Bulk sample analyses from regions near the center of the HIP canister were also conducted for both samples using X-ray diffraction and SEM-EDS. The sample with the Ni HIP canister showed almost no interaction zone with only minor diffusion of Ni from the inner wall of the canister into the near-surface region of the wasteform. The sample with the SS HIP canister showed ∼100–120 μm of interaction zone dominated by high-temperature Cr diffusion from canister materials to the wasteform with the Cr predominantly incorporated into the durable zirconolite phase. We also examined, for the first time, changes to the HIP canister wall thickness caused by HIPing and demonstrated that no canister wall thinning occurred. Instead, in the areas examined, the canister wall thickness was observed to increase (up to ∼20%) due to the compression occurring during the HIP cycle. Further, only sparse formation of (Cr, Mn)-rich oxide particles were noted within the HIP canister inner wall area immediately adjacent to the ceramic material, with no evidence for reverse diffusion of ceramic materials. Though the HIP canister–wasteform interaction extends to ∼120 μm when using an SS HIP canister for the system investigated, this translates to <<1 vol.% for an industrial scale HIPed wasteform. Importantly, the HIP canister–wasteform interactions did not produce any obviously less durable phases in the wasteform or had any detrimental impact on the HIP canister properties.  相似文献   
10.
Novel inks were formulated by dissolving polycaprolactone (PCL), a hydrophobic polymer, in organic solvent systems; polyethylene oxide (PEO) was incorporated to extend the range of hydrophilicity of the system. Hydroxyapatite (HAp) with a weight ratio of 55–85% was added to the polymer-based solution to mimic the material composition of natural bone tissue. The direct ink writing (DIW) technique was applied to extrude the formulated inks to fabricate the predesigned tissue scaffold structures; the influence of HAp concentration was investigated. The results indicate that in comparison to other inks containing HAp (55%, 75%, and 85%w/w), the ink containing 65% w/w HAp had faster ink recovery behavior; the fabricated scaffold had a rougher surface as well as better mechanical properties and wettability. It is noted that the 65% w/w HAp concentration is similar to the inorganic composition of natural bone tissue. The elastic modulus values of PCL/PEO/HAp scaffolds were in the range of 4–12 MPa; the values were dependent on the HAp concentration. Furthermore, vancomycin as a model drug was successfully encapsulated in the PCL/PEO/HAp composite scaffold for drug release applications. This paper presents novel drug-loaded PCL/PEO/HAp inks for 3D scaffold fabrication using the DIW printing technique for potential bone scaffold applications.  相似文献   
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