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排序方式: 共有128条查询结果,搜索用时 78 毫秒
1.
Bioimaging: Shaping Luminescent Properties of Yb3+ and Ho3+ Co‐Doped Upconverting Core–Shell β‐NaYF4 Nanoparticles by Dopant Distribution and Spacing (Small 47/2017) 下载免费PDF全文
2.
Shaping Luminescent Properties of Yb3+ and Ho3+ Co‐Doped Upconverting Core–Shell β‐NaYF4 Nanoparticles by Dopant Distribution and Spacing 下载免费PDF全文
Aleksandra Pilch Christian Würth Martin Kaiser Dominika Wawrzyńczyk Michalina Kurnatowska Sebastian Arabasz Katarzyna Prorok Marek Samoć Wiesław Strek Ute Resch‐Genger Artur Bednarkiewicz 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(47)
At the core of luminescence color and lifetime tuning of rare earth doped upconverting nanoparticles (UCNPs), is the understanding of the impact of the particle architecture for commonly used sensitizer (S) and activator (A) ions. In this respect, a series of core@shell NaYF4 UCNPs doped with Yb3+ and Ho3+ ions are presented here, where the same dopant concentrations are distributed in different particle architectures following the scheme: YbHo core and YbHo@…, …@YbHo, Yb@Ho, Ho@Yb, YbHo@Yb, and Yb@YbHo core–shell NPs. As revealed by quantitative steady‐state and time‐resolved luminescence studies, the relative spatial distribution of the A and S ions in the UCNPs and their protection from surface quenching has a critical impact on their luminescence characteristics. Although the increased amount of Yb3+ ions boosts UCNP performance by amplifying the absorption, the Yb3+ ions can also efficiently dissipate the energy stored in the material through energy migration to the surface, thereby reducing the overall energy transfer efficiency to the activator ions. The results provide yet another proof that UC phosphor chemistry combined with materials engineering through intentional core@shell structures may help to fine‐tune the luminescence features of UCNPs for their specific future applications in biosensing, bioimaging, photovoltaics, and display technologies. 相似文献
3.
Tyre manufacturers aiming to remain competitive in complex modern markets must promptly adjust to the changes within the production environment. With traditional tyre-manufacturing systems, a slow response during optimization of the manufacturing process and low-level adaptability to system disturbances is evident. The presented approach to virtual holonic control of the tyre-manufacturing system enables dynamic response in the event of new optimization demands, decrease of the impact of disturbances on system productivity and smaller future investments in the manufacturing equipment. 相似文献
4.
Grzegorz Samołyk 《Journal of Materials Processing Technology》2013,213(10):1692-1702
Orbital forging is a metal forming process in which one of the dies performs a complex rocking motion. It ensures reduction in required load and allows for the cold forming of a workpiece. One of the mechanical parts formed by means of this technology is a bevel gear. However, a numerical analysis of orbital forging bevel gears is very difficult to perform due to the complex rocking motion of the die, which is confirmed by numerous works investigating the orbital forging process. In the present work, investigation results of the cold orbital forging of aluminum alloy bevel gears are presented. In contrast to other works devoted to the process, this study proposes a new procedure for forming bevel gears and the workpiece used has a shape which is different from the previously applied ones. The obtained results apply to both theoretical and technological aspects of orbital forging. The FEM simulation results have been successfully verified in laboratory conditions using the industrial PXW-100A press. 相似文献
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6.
II Gitel'zon VP Nefedov VV Mezhevikin VA Samo?lov IuV Kotlovski? 《Canadian Metallurgical Quarterly》1977,84(7):23-24
Hypoxemia (45-minute) influence in vivo on erythropoietic activity of the kidney, liver, spleen, and sternum was studied by normoxemic perfusion of the isolated organs. The erythropoietic activity proved to increase after 6-hour perfusion of the liver; this confirmed the participation of this organ in the extrarenal secretion of the erythropoietic factor. 相似文献
7.
Vlad Popa-Nita Ivan Gerli? Samo Kralj 《International journal of molecular sciences》2009,10(9):3971-4008
We review the theoretical research on the influence of disorder on structure and phase behavior of condensed matter system exhibiting continuous symmetry breaking focusing on liquid crystal phase transitions. We discuss the main properties of liquid crystals as adequate systems in which several open questions with respect to the impact of disorder on universal phase and structural behavior could be explored. Main advantages of liquid crystalline materials and different experimental realizations of random field-type disorder imposed on liquid crystal phases are described. 相似文献
8.
L. N. Maskaeva V. F. Markov I. M. Morozova N. M. Barbin V. Ya. Shur E. I. Shishkin E. S. Samoĭlova 《Technical Physics Letters》2008,34(6):472-474
Thin films of supersaturated Zn x Pb1 ? x S solid solutions containing up to 4.1 mol % ZnS have been obtained by hydrochemical deposition. The dependence of the material structure and surface morphology on the film composition has been studied. It is established that an increase in the content of zinc sulfide leads to the growth of grains with a more complicated crystalline structure, the formation of grain boundary fragments with dimensions from 60 to 100 nm, and a modification of the electrical properties of deposited layers. 相似文献
9.
10.
We present the results of first-principles cluster calculations of local distortions in doped La2CuO4. Local deformations of the CuO6 octahedra associated with the presence of an additional extrinsic hole were determined using the density-functional (DF) method on various cluster models. The results indicate that a localized hole induces a contraction of the CuO(apical) distance from 2.40 to 2.28 Å. The contracted distance is in very good agreement with the anomalous, short CuO(apical) distance of 2.3 Å, observed recently by polarized Cu K-edge extended x-ray absorption fine structure (EXAFS) in La1.85Sr0.15CuO4 and associated with the hole-rich stripe region. 相似文献