Thoria doped with cations of group VB–synthesis and sintering

The cations M⁵⁺ (M=V, Nb and Ta) were doped in thoria through gel-combustion synthesis using citric acid as fuel. Thorium dioxide feed powders thus prepared were cold compacted without binder or lubricant and sintered to a high density (9.5 Mg m⁻³) at relatively low temperatures (1623 K). The powders were characterised for the residual carbon, crystallite size, specific surface area, particle size distribution and bulk density. The distribution of the dopant in the thoria matrix was analyzed by electron probe microanalysis. The reactivity of the calcined powders was determined by measuring the density of the sintered compacts prepared from them. For the first time it is demonstrated that apart from niobia, even tantala and vanadia can bring about accelerated sintering in thoria if they are doped through a wet chemical route viz., the gel-combustion procedure. The maximum densities obtained by doping with vanadia (0.02 mol%), niobia (0.50 mol%) and tantala (0.50 mol%) were 9.8 Mg m⁻³ (1573 K), 9.68 Mg m⁻³ (1423 K) and 9.69 Mg m⁻³ (1623 K), respectively.     

Novel optimized tree-based stack-type architecture for 2n-bit comparator at nanoscale with energy dissipation analysis

Comparator is an essential building block in many digital circuits such as biometric authentication, data sorting, and exponents comparison in floating-point architectures among others. Quantum-dot Cellular Automata (QCA) is a latest nanotechnology that overcomes the drawbacks of Complementary Metal Oxide Semiconductor (CMOS) technology. In this paper, novel area optimized 2n-bit comparator architecture is proposed. To achieve the objective, 1-bit stack-type and 4-bit tree-based stack-type (TB-ST) comparators are proposed using QCA. Then, two tree-based architectures of 4-bit comparators are arranged in two layers to optimize the number of quantum cells and area of an 8-bit comparator. Thus, this design can be extended to any 2n-bit comparator. Simulation results of 4-bit and 8-bit comparators using QCADesigner 2.0.3 show that there is a significant improvement in the number of quantum cells and area occupancy. The proposed TB-ST 8-bit comparator uses 2.5 clock cycles and 622 quantum cells with area occupancy of 0.49 µm² which is an improvement by 10.5% and 38%, respectively, compared to existing designs. Scaling it to a 32-bit comparator, the proposed architecture requires only 2675 quantum cells in an area of 2.05 µm² with a delay of 3.5 clock cycles, indicating 9.35% and 28.8% improvements, respectively, demonstrating the merit of the proposed architecture. Besides, energy dissipation analysis of the proposed TB-ST 8-bit comparator is simulated on QCADesigner-E tool, indicating average energy dissipation reduction of 17.3% compared to existing works.

     

An efficient neural-network model for real-time fault detection in industrial machine

Neural Computing and Applications - Induction machines have extensive demand in industries as they are used for large-scale production and, therefore, vulnerable to both electrical and mechanical...     

Electrical transport properties of iron (II) molybdate

Electrical conductivity, thermoelectric power and static dielectric constant of iron (II) molybdate have been measured in the temperature range 300 to 1000 K on pressed pellets of polycrystalline sample. It has been found that FeMoO₄ is a p-type semiconductor with energy gap 4.1 eV. Different conduction mechanisms have been found below and above 700 K. Below 700 K conduction is due to a small polaron hopping mechanism and above 700 K conduction is due to large polarons as well as normal band conduction mechanism. Activation energy W, ₀ (T) and charge carrier mobility have been estimated in the two temperature ranges 300 to 700 K and 700 to 1000 K. Dielectric constant increases slowly with temperature up to 700 K and above 700 K, it increases exponentially with temperature.     

Peroxydisulfate initiated graft copolymerization of aniline onto poly(propylene) fiber—A kinetic approach

A novel method for the preparation of electrically conducting fibers through chemical grafting of electrically conducting polymer onto poly(propylene) (PP) fiber is described. The graft copolymerization of aniline (ANI) was performed in aqueous acidic medium by using a chemical oxidant such as peroxydisulfate (PDS). Grafting occurred with simultaneous homopolymer formation. The content of polyaniline in the backbone fiber was found to vary by varying [monomer], [initiator], and amount of PP fiber. Various graft parameters such as rate of grafting (R_g), % grafting, and % grafting efficiency were evaluated. The rate of homopolymerization (R_h) was also determined. Both R_h and R_g showed first‐order dependency on [ANI], [PDS], and amount of PP fiber variation. The chemical grafting was confirmed by use of cyclic voltammetry and conductivity measurements. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3827–3834, 2003     

Studies on blends of natural rubber and ethylene propylene diene rubber modified with phosphorylated cardanol prepolymer: Processability,physico‐mechanical properties,and morphology

The melt processability and physico‐mechanical properties of blends of natural rubber (NR) and ethylene propylene diene rubber (EPDM) containing different dosages (0–10 phr) of phosphorylated cardanol prepolymer (PCP) were studied in unfilled and china‐clay‐filled mixes. The plasticizing effect of PCP in the blends was evidenced by progressive reduction in power consumption of the mixing and activation energy for melt flow with an increase in the dosage of PCP. The PCP‐modified blend vulcanizates showed higher tensile properties and tear strength despite a decrease in the chemical crosslink density (CLD) index. This is presumably due to the formation of a crosslinked network structure of PCP with the rubbers and improved dispersion of the filler particles in the rubber matrix, as evidenced by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Thermogravimetric analysis showed an increase in thermal stability of the blend vulcanizate in presence of 5 phr of PCP. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5123–5130, 2006     

Kinetics of esterification of cycloaliphatic epoxies with methacrylic acid

The esterification of cycloaliphatic epoxy resins CER I and CER II containing glycidyl and cyclohexane epoxy groups, respectively, as their reactive units was carried out using a 1 : 0.9 stoichiometric ratio of resin and methacrylic acid in the presence of triphenylphosphine. The reaction was performed at 80, 85, 90, 95, and 100°C and it followed second‐order kinetics. The specific rate constants, calculated by regression analysis, were found to obey an Arrhenius expression. Kinetic and thermodynamic parameters, activation energy, frequency factor, entropy, enthalpy, and free energy of the reaction, revealed that the reaction was spontaneous and irreversible and produced a highly ordered activated complex. The reactivity of CER II was found to be higher than that of CER I. The difference in the reactivity of the cycloaliphatic epoxies was explained by proposing a reaction mechanism. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3197–3204, 2002     

Finite element prediction of material removal rate due to electro-chemical spark machining

Electro-chemical spark machining (ECSM) is an innovative hybrid machining process, which combines the features of the electro-chemical machining (ECM) and electrodischarge machining (EDM). Unlike ECM and EDM, ECSM is capable of machining electrically non-conducting materials. This paper attempts to develop a thermal model for the calculation of material removal rate (MRR) during ECSM. First, temperature distribution within zone of influence of single spark is obtained with the application of finite element method (FEM). The nodal temperatures are further post processed for estimating MRR. The developed FEM based thermal model is found to be in the range of accuracy with the experimental results. Further the parametric studies are carried out for different parameters like electrolyte concentration, duty factor and energy partition. The increase in MRR is found to increase with increase in electrolyte concentration due to ECSM of soda lime glass workpiece material. Also, the change in the value of MRR for soda lime glass with concentration is found to be more than that of alumina. MRR is found to increase with increase in duty factor and energy partition for both soda lime glass and alumina workpiece material.     

An enhanced encryption algorithm for video based on multiple Huffman tables

Encryption is one of the fundamental technologies that is used in the security of multimedia data. Unlike ordinary computer applications, multimedia applications generate large amount of data that has to be processed in real time. This work investigates the problem of efficient multimedia data encryption. A scheme known as the Randomized Huffman Table scheme was recently proposed to achieve encryption along with compression. Though this scheme has several advantages it cannot overcome the chosen plaintext attack. An enhancement of this Huffman scheme is proposed in this work which essentially overcomes the attack and improves the security. The proposed encryption approach consists of two modules. The first module is the Randomized Huffman Table module, the output of which is fed to the second XOR module to enhance the performance. Security analysis shows that the proposed scheme can withstand the chosen plaintext attack. The efficiency and security of the proposed scheme makes it an ideal choice for real time secure multimedia applications.     

Equivalence of classicality and separability based on P phase–space representation of symmetric multiqubit states

Classical and quantum world views differ in peculiar ways. Understanding decisive quantum features—for which no classical explanation exist—and their interrelations is of foundational interest. Moreover, recognizing non-classical features carries practical significance in information processing tasks as it offers insights as to why quantum protocols work better than their classical counterparts. We focus here on two celebrated notions of non-classicality viz., negativity of P phase–space representation and entanglement in symmetric multiqubit systems. We prove that they imply each other.