全文获取类型
收费全文 | 1559篇 |
免费 | 121篇 |
国内免费 | 22篇 |
专业分类
电工技术 | 19篇 |
综合类 | 6篇 |
化学工业 | 351篇 |
金属工艺 | 38篇 |
机械仪表 | 92篇 |
建筑科学 | 55篇 |
矿业工程 | 1篇 |
能源动力 | 109篇 |
轻工业 | 164篇 |
水利工程 | 18篇 |
石油天然气 | 27篇 |
无线电 | 141篇 |
一般工业技术 | 329篇 |
冶金工业 | 75篇 |
原子能技术 | 10篇 |
自动化技术 | 267篇 |
出版年
2024年 | 5篇 |
2023年 | 38篇 |
2022年 | 30篇 |
2021年 | 92篇 |
2020年 | 92篇 |
2019年 | 113篇 |
2018年 | 142篇 |
2017年 | 115篇 |
2016年 | 114篇 |
2015年 | 59篇 |
2014年 | 95篇 |
2013年 | 180篇 |
2012年 | 98篇 |
2011年 | 102篇 |
2010年 | 70篇 |
2009年 | 65篇 |
2008年 | 39篇 |
2007年 | 39篇 |
2006年 | 13篇 |
2005年 | 17篇 |
2004年 | 9篇 |
2003年 | 15篇 |
2002年 | 12篇 |
2001年 | 5篇 |
2000年 | 6篇 |
1999年 | 4篇 |
1998年 | 11篇 |
1997年 | 6篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 2篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 14篇 |
1981年 | 4篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1970年 | 5篇 |
1966年 | 6篇 |
1961年 | 3篇 |
排序方式: 共有1702条查询结果,搜索用时 15 毫秒
1.
2.
The effect of pMDI on physical and mechanical properties of the particleboards made from urea–glyoxal resin was investigated. The nontoxic and ecofriendly urea–glyoxal (UG) resin was synthesized under weak acid conditions, and its different properties were measured. Then, pMDI at various contents (4, 6 and 8% on resin solids) was added to the UG resin prepared. The thermal and physicochemical properties of the resins prepared as well as their water absorption, flexural properties (flexural modulus and strength) and internal bond (IB) strength of the particleboard panels bonded with them were measured according to standard methods. According to the physicochemical results obtained, the addition of pMDI significantly accelerated the gel time and increased the viscosity and solids content of UG resins. Differential scanning calorimetry indicated that the addition of pMDI decreases the onset and curing temperatures of the UG resin. Physical analysis results of the panels indicated that the particleboards made from UG resins with isocyanate yielded lower water absorption when compared to those bonded with the control UG resins. Based on the findings of this research work, the mechanical properties of particleboard panels bonded with UG resins could be significantly enhanced by the addition of increasing percentages of pMDI. The panels having 8 wt% pMDI exhibited the highest flexural modulus, flexural strength and IB strength value and the lowest water absorption among all the panels prepared. 相似文献
3.
Ahmed Labena Ahmed Hamed Eman H. I. Ismael Samy M. Shaban 《Journal of surfactants and detergents》2020,23(5):991-1004
The Egyptian oil and gas industry is suffering from severe metal corrosion problems, particularly microbial-induced corrosion. There is limited knowledge on the corrosion inhibition of carbon steels in the presence of an acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. Therefore, in this study, novel Gemini cationic surfactants, in three forms depending on variation in alkyl chains of 8, 12, and 16 carbon atoms named FHPAO, FHPAD, and FHPAH, respectively, were synthesized and characterized by Fourier transform infrared and nuclear magnetic resonance spectroscopy. The surface parameters and the thermodynamic of the synthesized surfactants were evaluated at three different temperatures, 20, 40, and 60 °C. The synthesized Gemini cationic surfactants were tested as broad-spectrum antimicrobial, antibacterial and anticandida agents. They evaluated as biocides and corrosion inhibitors against Acidithiobacillus ferrooxidans. FHPAD showed higher adsorption ability at the solution interface and higher affinity to construct micelles than FHPAO and FHPAH. Both adsorption and micellization processes were hydrophobic and temperature dependent. FHPAO, FHPAD and FHPAH exhibited wide-spectrum antimicrobial activities, and the highest activity and the lowest minimum bactericidal/fungicidal inhibitory concentrations were attributed to FHPAD. Furthermore, synthesized FHPAD demonstrated the highest metal corrosion inhibition efficiency of 95.5% at 5 mM in comparison to 87.5% and 81.7% for FHPAO and FHPAH, respectively. In conclusion, this study provides novel synthesized cationic surfactants with many applications in the oil and gas industry, such as broad-spectrum antimicrobial, biocides, and corrosion inhibitors for acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. 相似文献
4.
Huseyin Avci Esra Akkulak Hazal Gergeroglu Hamed Ghorbanpoor Onur Uysal Ayla Eker Sariboyaci Bahar Demir Merve Nur Soykan Suat Pat Reza Mohammadigharehbagh Ceren Özel Ahmet Cabuk Fatma Doğan Güzel 《应用聚合物科学杂志》2020,137(26):49184
Among the thermoplastic elastomers that play important roles in the polymer industry due to their superior properties, styrene-based species and polyurethane block copolymers are of great interest. Poly(styrene-ethylene-butadiene-styrene) (SEBS) as a triblock copolymer seems to have the potential to meet many demands in different applications due to various industrial requirements where durability, biocompatibility, breaking elongation, and interfacial adhesion are important. In this study, the SEBS triblock copolymer was functionalized with natural (Satureja hortensis, SH) and synthetic (nanopowder, TiO2) agents to obtain composite nanofibers by electrospinning and electrospraying methods for use in biomedical and water filtration applications. The results were compared with thermoplastic polyurethane (TPU) composite nanofibers, which are commonly used in these fields. Here, functionalized SEBS nanofibers exhibited antibacterial effect while at the same time improving cell viability. In addition, because of successful water filtration by using the SEBS composite nanofibers, the material may have a good potential to be used comparably to TPU for the application. 相似文献
5.
Parisa Solhi Sodeif Azadmard‐Damirchi Javad Hesari Hamed Hamishehkar 《International Journal of Dairy Technology》2020,73(1):226-233
The qualitative properties of processed cheese (PC) fortified with different levels of asparagus powder (AP) (0.5%, 1% and 1.5% wt/wt) were evaluated during storage. AP decreased the pH and lipolysis indexes and increased the phenolic content, antioxidant activity and proteolysis of the processed cheeses. AP made the structure of the cheese more elastic, increased the rigidity and decreased the spreadability compared with the control sample, which corresponded to the results obtained using dynamic oscillatory rheometry. The results showed that AP as a rich source of bioactive components could be used for the fortification of processed cheeses. 相似文献
6.
7.
Nadir Ouldhamadouche Amine Achour Raul Lucio-Porto Mohammad Islam Shahram Solaymani Ali Arman Azin Ahmadpourian Hamed Achour Laurent Le Brizoual Mohamed Abdou Djouadi Thierry Brousse 《材料科学技术学报》2018,34(6):976-982
Vanadium nitride(VN) was deposited by DC-sputtering on a vertically aligned carbon nanotube(CNTs)template for the purpose of nano-structuration. This led to the fabrication of hierarchically composite electrodes consisting of porous and nanostructured VN grown on vertically aligned CNTs in a nano-treelike configuration for micro-supercapacitor application. The electrodes show excellent performance with an areal capacitance as high as 37.5 m F cm~(-2) at a scan rate of 2 mV s~(-1) in a 0.5 MK_2SO_4 mild electrolyte solution. Furthermore, the capacitance decay was only 15% after 20,000 consecutive cycles. Moreover,the capacitance was found to increase with VN deposit thickness. The X-ray photoelectron spectroscopy analyses of the electrodes before and after cycling suggest that the oxide layers that form at the VN surface is the responsible for the redox energy storage in this material. Such electrodes can compete with other transition metal nitride based electrodes for micro-supercapacitors. 相似文献
8.
Multilayer assembly of ionic starches on old corrugated container recycled cellulosic fibers 下载免费PDF全文
Hamidreza Rudi Yahya Hamzeh Esmaeil Rasooly Garmaroody Seyed Rahman Djafari Petroudy Mousa M Nazhad 《Polymer International》2018,67(1):85-90
In this study, old corrugated container recycled fibers were treated with polyelectrolyte multilayers consisting of biopolymer cationic starch with two degrees of substitution (DS) each in combination with one anionic starch. Pulp zeta potential, paper strength and the thin layer ellipsometry technique were applied to examine the influence of cationic starch DS on the formation of polyelectrolyte multilayers. The results indicated a significant interaction between the DS of cationic starch and the number of ionic starch layers formed. When low‐DS cationic starch was used, the pulp zeta potential and the paper strength increased significantly in assembling the first cationic layer. However, in depositing high‐DS cationic starch a greater zeta potential and a stronger influence on the paper strength were observed with a larger number of starch layers. This was confirmed by thin layer ellipsometry when a greater thickness of multilayers was achieved by employing high‐DS cationic starch to form a higher number of layers. © 2017 Society of Chemical Industry 相似文献
9.
10.
Shafirah Samsuri Ngiam Li Jian Farah Wahida Jusoh Eduard Hernández Yáñez Noor Yahida Yahya 《化学工程与技术》2020,43(3):447-456
The application of solvent-aided crystallization (SAC) is based on the addition of a solvent, here 1-butanol, to crude biodiesel to catalyze the purification process by separating biodiesel from contaminants via crystallization process. Response surface methodology was applied to optimize the process parameters of SAC, represented by biodiesel purity. The purified biodiesel was analyzed by means of gas chromatography-mass spectrometry for the composition of the present fatty acid methyl ester (FAME). Under the predicted optimum process conditions within the experimental ranges for the highest biodiesel purity, the predicted biodiesel purity was 99.375 %. 相似文献