Preparation and characterization of novel polyurethanes containing 4,4′‐{oxy‐1,4‐diphenyl bis(nitromethylidine)}diphenol schiff base diol

Four novel segmented polyurethanes (PUs) based on4,4′‐{oxy‐1,4‐diphenyl bis(nitromethylidine)}diphenol (ODBNMD) diol with different diisocyanates such as 4,4′‐diphenylmethane diisocyanate, toluene 2,4‐diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate have been prepared by solution method. The structures of ODBNMD and PUs have been confirmed by Fourier transform infrared (FTIR), nuclear magnetic resonance (¹H‐NMR and ¹³C‐NMR), UV‐visible, and fluorescence spectroscopies. The segmented PUs were further characterized by thermogravimetry (TGA), differential scanning calorimetry (DSC), and wide‐angle X‐ray diffraction. FTIR confirmed hydrogen bonding interactions, whereas TGA and DSC suggested that introduction of aromatic/phenyl ring in the main chain considerably increased the thermal stability. POLYM. ENG. SCI., 54:24–32, 2014. © 2013 Society of Plastics Engineers     

Improving Performance of the Synthesis of Silica Nanoparticles by Surfactant-incorporated Wet Attrition Milling

Silicon - Abundant applications of silica nanoparticles (SiNPs) have motivated many research groups for silica nanoparticles synthesis with tuned properties. Here we show the formation of SiNPs...     

Simulation of hydrogen distribution in an Indian Nuclear Reactor Containment

The management of hydrogen in a Nuclear Reactor Containment after LOCA (Loss Of Coolant Accident) is of practical importance to preserve the structural integrity of the containment. This paper presents the results of systematic work carried out using the commercial Computational Fluid Dynamics (CFD) software FLUENT to assess the concentration distribution of hydrogen in a typical Indian Nuclear Reactor Containment. In order to obtain an accurate estimate of hydrogen concentration distribution, a suitable model for turbulence closure is required to be selected. Using guidelines from the previous studies reported in the literature and a comparative simulation study using simple benchmark problems, the most suitable turbulence model for hydrogen mixing prediction was identified. Subsequently, unstructured meshes were generated to represent the containment of a typical Indian Nuclear Reactor. Analyses were carried out to quantify the hydrogen distribution for three cases. These were (1) Uniform injection of hydrogen for a given period of time at room temperature, (2) Time varying injection as has been computed from an accident analysis code, (3) Time varying injection (as used in case (2)) at a high temperature. A parametric exercise was also carried out in case (1) where the effect of various inlet orientations and locations on hydrogen distribution was studied. The results indicate that the process of hydrogen dispersal is buoyancy dominated. Further for typical injection rates encountered following LOCA, the dispersal is quite poor and most hydrogen is confined to the fuelling machine vault.     

Cooling precipitation and strengthening study in powder metallurgy superalloy U720LI

The excellent mechanical properties of powder metallurgy (P/M) superalloys strongly depend on the microstructure, such as grain size, and morphology and size distribution of the γ’ precipitates. The microstructure is, in turn, determined by the heat treatment, viz., solution annealing, quenching, and subsequent aging. To study the effect of the quenching process, two types of quenching methods were used to produce different quenched microstructures in a UDIMET 720LI (U720LI) alloy. One was a continuous quenching method, where samples were colled along linearly controlled cooling profiles, each at a fixed cooling rate. This test studied the effect of cooling rate on the size of cooling γ’ precipitates (formed during quenching) and the consequent strengthening effect. The other test was the interrupted quenching test, which allowed tracking the growth of cooling γ’ precipitates with decreasing temperature during quenching at a given cooling rate. The strengthening response at each interrupt temperature was also studied. Results from the continuous cooling tests showed that the relationship between the size of the cooling γ’ precipitate and the cooling rate obeys a power law, with an exponential being about 0.35. The tensile strength was found to increase linearly with the cooling rate. Strengthening due to the subsequent aging treatment occurred regardless of cooling rates. The interrupted cooling tests showed that γ’ growth is a linear function of decreasing temperature for a given cooling rate. A nonmontonic degradation of tensile strength against interrupt temperature was discovered.     

Effect of machining parameters and cutting edge geometry on surface integrity of high-speed turned Inconel 718

Stringent control on the quality of machined surface and sub-surface during high-speed machining of Inconel 718 is necessary so as to achieve components with greater reliability and longevity. This paper extends the present trend prevailing in the literature on surface integrity analysis of superalloys by performing a comprehensive investigation to analyze the nature of deformation beneath the machined surface and arrive at the thickness of machining affected zone (MAZ). The residual stress analysis, microhardness measurements and degree of work hardening in the machined sub-surfaces were used as criteria to obtain the optimum machining conditions that give machined surfaces with high integrity. It is observed that the highest cutting speed, the lowest feedrate, and the moderate depth of cut coupled with the use of honed cutting edge can ensure induction of compressive residual stresses in the machined surfaces, which in turn were found to be free of smeared areas and adhered chip particles.     

An analytical model to predict specific shear energy in high-speed turning of Inconel 718

Machining of Inconel 718 at higher cutting speeds is expected to provide some relief from the machining difficulties. Therefore, to understand the material behavior at higher cutting speeds, this paper presents an analytical model that predicts specific shearing energy of the work material in shear zone. It considers formation of shear bands that occur at higher cutting speeds during machining, along with the elaborate evaluation of the effect of strain, strain rate, and temperature dependence of the shear flow stress using Johnson–Cook equation. The model also considers the ‘size-effect’ in machining in terms of occurrence of ‘ploughing forces’ during machining. The theoretical results show that the shear band spacing in chip formation increases linearly with an increase in the feedrate and is of the order of 0.2–0.9 mm depending upon the processing conditions. The model shows excellent agreement with the experimental values with an error between 0.5% and 7% for various parametric conditions.     

PERFORMANCE ANALYSIS OF A DOUBLE-DECK CONVEYOR DRYER - A COMPUTATIONAL APPROACH

This paper illustrates the use of numerical simulation models for evaluating the performance of a moving bed dryer. A finite-volume method is employed in developing a steady state, two-dimensional numerical model for a double-deck conveyor dryer. Using this numerical model, variations in the product moisture content and temperature along the length and across the height of the product beds are predicted. Similarly, the resulting variations in the temperature and relative humidity of the drying air are predicted in the entire two-dimensional domain of a dryer. Effect of air-to-product mass flow ratio and product residence lime on the average moisture content of the outgoing product are also evaluated for three different drying air temperatures.     

Optomechanical scanning systems for microstereolithography (MSL): Analysis and experimental verification

Optomechanical scanning systems with focused laser spot are used in several applications including microstereolithography (MSL), scanning optical tweezers, and laser cutting. Systems used so far in the literature for scanning a focused laser spot on a substrate are: (a) galvanomirror preobjective scanning, (b) galvanomirror postobjective scanning and (c) ‘off-axis’ lens scanning system (originally proposed by coauthors). Major performance criteria due to end application, (say for example, to obtain high resolution microdevices in MSL) translates into the following criteria on optical scanning system: (i) uniform spot size and (ii) uniform intensity profile over the entire range of scan. This paper presents comparative optical analysis, both theoretical and experimental, of these systems based on the proposed performance criteria. Optical analysis of the optomechanical scanning systems is carried out by using geometric ray tracing method. Image evaluation in this case is done using diffraction wave optics. Simulations are carried out to determine spot characteristics at image plane when scan distances are changed by moving optics in the above mentioned optomechanical scanning systems. Simulation and experimental results clearly show that there is lesser distortion of spot characteristics (size and intensity profile) in case of proposed off-axis lens scanning system as compared to other systems over wider scan range. Hence this system is more promising to fabricate high resolution micro-components and in general for other similar applications as well.     

Analysis of the wetting behaviour of pigments and the effectiveness of surfactants

A new test method is introduced to analyse the wetting behaviour of pigments and the effectiveness of surfactants. The method involves the study of torque vs time curves obtained during the wetting of pigments by surfactant solutions. These curves provide valuable information regarding the wetting behaviour of pigments and the ability of the surfactant to wet the pigment. To study the wetting behaviour, two pigments which varied widely in their surface character are studied with the same surfactant, while, to study the effectiveness of the surfactant, different surfactants with differing polarity are studied using the same pigment. The results are found to be consistent with the theoretical expectations.     

Modeling of chip–tool interface friction to predict cutting forces in machining of Al/SiCp composites

In Al/SiCp metal matrix composites, in addition to machine, tool and process-related parameters, a change in composition (size and volume fraction of reinforcement) has a influence on machining force components. In the analytical models in the literature, the effect of abrasive reinforcement particles, which affects the coefficient of friction and consequently the friction angle, has not been considered while predicting cutting forces in machining of MMCs. In this paper, chip–tool interface friction in machining of Al/SiCp composites has been considered to involve two-body abrasion and three-body rolling caused due to presence of reinforcements in composites. The model evaluates resulting coefficient of friction to predict the cutting forces during machining of Al/SiCp composites using theory of oblique cutting. Further, the model considers various frictional forces on the wiper geometry on the cutting edge that has been found to improve the integrity of machined surface on composites. The predicted cutting force values were found to agree well with the corresponding experimental values for finer reinforcements composites with the assumption that 40% of the reinforcement particles contribute to the abrasion at chip–tool interface. However, for the coarser reinforcement composites, assumption that the 60% of the particles contribute to the abrasion yields better results.