Design of 25 Gbit/s half-rate CDR with 1:2 demultiplexer for 100 GbE optical interconnects

A 25 Gbit/s clock and data recovery(CDR) circuit with 1:2 demultiplexer for 100 Gbit/s Ethernet(100 Gb E) optical interconnects has been designed and fabricated in Taiwan Semiconductor Manufacture Company(TSMC) 65 nm complementary metal-oxide-semiconductor(CMOS) technology. A novel quadrature voltage-controlled-oscillator(QVCO) structure adopts two pairs of transconductance cell and inverters to acquire rail-to-rail output swing. A half-rate bang-bang phase detector adopts four flip-flops array to sample the 25 Gbit/s input data and align the data phase, so the 25 Gbit/s data are retimed and demultiplexed into two paths 12.5 Gbit/s output data. Experimental results show that the recovered clock exhibits a peak-to-peak jitter of 7.39 ps and the recovered data presents a peak-to-peak jitter of 7.56 ps, in response to 312-1 pseudorandom bit sequence(PRBS) input. For 1.2 V voltage supply, the CDR circuit consumes 92 m W(excluding output buffers).     

Preparation of Silver Nanowires via a Rapid,Scalable and Green Pathway

Rapid synthesis of silver nanowires(Ag NWs) with high quality and a broad processing window is challenging because of the low selectivity of the formation of multiply twinned particles at the nucleation stage for subsequent Ag NWs growth.Herein we report a systematic study of the water-involved heterogeneous nucleation of Ag NWs with high rate(less than 20 min) in a simple and scalable preparation method.Using glycerol as a reducing agent and a solvent with a high boiling point,the reaction is rapidly heated to 210 ℃ in air to synthesize Ag NWs with a very high yield in gram level.It is noted that the addition of a small dose of water plays a key role for obtaining highly pure Ag NWs in high yield,and the optimal water/glycerol ratio is0.25%.After investigating a series of forming factors including reaction temperature and dose of catalysts,the formation kinetics and mechanism of the Ag NWs are proposed.Compared to other preparation methods,our strategy is simple and reproducible.These Ag NWs show a strong Raman enhancement effect for organic molecules on their surface.     

高效固体缓释型阻垢剂的研制及性能分析

针对大庆油田集输管道腐蚀结垢现象,以主剂、分散剂、特殊缓蚀阻垢剂和载体配制固体缓蚀阻垢剂,通过复配试验筛选出适合其采出液水质的药剂,并对其缓蚀和阻垢性能进行分析。结果表明:加注药剂后的管道钢腐蚀速率为0.070mm/a,远低于未加注前的0.310mm/a;阻垢效果15天内稳定,阻垢率约为91%,阻垢性能良好;缓释速率为约每10天溶解8%,加注周期约为3个月。所制备药剂性价比高,缓蚀阻垢综合性能良好,可作为油田水驱采出液专用缓蚀阻垢药剂。     

柱前衍生-高效液相色谱法检测安立生坦的手性拆分剂L-脯氨酸甲酯

采用4-氯-7-硝基苯-2-（嗯）-1,3-二唑（NBD-Cl）作为柱前衍生试剂,建立了柱前衍生化-高效液相色谱法（HPLC）结合荧光检测器测定安立生坦合成过程中使用的手性拆分剂L-脯氨酸甲酯的方法.考察了衍生反应温度、时间、衍生试剂加入量、缓冲液pH对L-脯氨酸甲酯衍生反应的影响.结果表明,衍生反应优化条件为：反应温度60℃,反应时间60 min,衍生试剂加入量为每毫升反应体系中加入0.3 mg NBD-Cl,衍生反应缓冲液pH为9.0.同时对此方法进行了方法学验证,L-脯氨酸甲酯在0.625～7.5 μg/mL范围内线性关系良好,r=0.999 4;检测限为2.5×10-3μg/mL,定量限为7.5×10-3μg/mL;平均回收率为91.9％～ 106.4％;重复性实验中RSD为0.33％;此方法耐用性良好,L-脯氨酸甲酯样品溶液及衍生产物溶液体系稳定.此方法灵敏、简便、专属性强,能对安立生坦原料药中残留的杂质L-脯氨酸甲酯进行检测及定量分析.     

磷钨酸改性介孔材料HPW-HMS在汽油脱硫中的应用

以正十二胺为模板剂,正硅酸四乙酯为硅源,磷钨酸（HPW）为活性组分,采用一锅法制备了磷钨酸改性的介孔材料HPW-HMS.以30％双氧水为氧源,探索HPW-HMS催化剂对汽油氧化脱硫的效果.结果表明,当磷钨酸和正硅酸四乙酯摩尔比为0.02,催化剂质量0.2g,反应温度为55℃,反应12 h,双氧水2.5 mL时,脱硫效果达到68.3％,催化剂重复使用4次依然有良好的催化效果.     

序批式生物膜法的脱氮特性研究

对序批式生物膜工艺的脱氮特性进行了探讨，并提出了过量储存-SND脱氮作用机理，即厌氧段脱氮主要靠生物膜对含碳、氮有机物的过量储存作用，而好氧段脱氮则靠生物膜的同步硝化反硝化(SND)作用，反硝化的有机碳源主要为生物膜在厌氧段过量储存的有机物。镜检发现反应器中的优势菌属为假单胞菌属，其次为气单胞菌属、芽孢杆菌属、微球菌属、硝化杆菌属。     

地下建筑湿负荷计算

从地下建筑围护结构散湿、人体散湿、自由水面散湿、人为散湿、外部空气带湿五个方面介绍了地下建筑物内湿负荷的主要来源和计算方法。     

承德某区域集中供热设计

本文针对区域复杂的地形环境、热源的局限性以及城市现状与未来的发展对供热的需求差别,经综合分析比较,该集中供热系统采取短期直供,待电厂具备抽汽加热能力之后改为间接供热的形式。阐述了直供中为克服地形高差大等设计难题而采取的在系统主管网上设置减压站、中继泵站等一系列安全措施。运行情况表明该系统设计是成功的。     

空调-热水器一体机单独制热水模式的性能模拟和实验分析

简要介绍了空调-热水器一体机的基本原理和构成，对其在独立制热水模式下的运行工况进行了数值模拟和实验分析。结果表明，该设备具有明显的节能效果，但系统的功率和COP随着水温的升高而下降；该设备对压缩机性能的要求比普通空调器要高。