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1.
Wireless Personal Communications - Breast cancer is one of the rapid spreading diseases resulting in the death of younger age group of women. Unfortunately, as the detection of cancer is at later...  相似文献   
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In this work, praseodymium (Pr) doped cerium oxide (CeO2) was prepared using the microwave-assisted hydrothermal method (MAH) and the properties were investigated by X-ray diffraction analysis (XRD), Raman spectroscopy, Field Emission Gun Scanning Electron Microscope (FEG-SEM), BET method, Photoluminescence spectroscopy (PL), Fourier-transform infrared spectroscopy (FTIR), Ultraviolet–visible spectroscopy (UV–Vis), Electron paramagnetic resonance spectroscopy (EPR) and Magnetometry. The results showed that increasing the Pr-doping promotes a structural disorder due to increased oxygen vacancies. XRD confirmed a cubic structure without deleterious phases with modifications in the structure caused by alteration in the cerium oxidation state as well as changes in the crystallite size and strain obtained by Wellinson-Hall method. Raman spectroscopy shows that changing the Pr content results in samples with different defect densities at short range. FEG-SEM showed that the nanocrystals are agglomerated with small particles tend to aggregate spontaneously to decrease the surface energy. BET method showed that the Pr doping results in a gain of specific surface area. PL indicated that Pr3+ leads to distinct emissions; red emission associated to oxygen vacancies located near the conduction band (shallow defects), green emission associated to electron-hole recombination and orange emission associated to shallow defects and electron-hole recombination. FTIR indicated the complete process of nucleation with no other phase. UV–Vis showed the transitions between oxygen 2p, cerium 4f and praseodymium 4f states. The EPR signal shows events occurring around 344 mT. These events can be related due the presence of paramagnetic elements containing unpaired electrons, such as Ce (III), which is indicative of cerium reduction caused by Pr ions, as evidenced by Rietveld data. Regardless of the Pr concentration used in this research, the magnetic measurements show a superparamagnetic system below the blocking temperature of ~20 K and a paramagnetic system above this temperature, which indicates no significant changes in the average size of the nanoparticles. Surface area, crystallite size and the temperature are important parameters, which control the magnetic properties of such N-type semiconductors.  相似文献   
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Garzan oil field is located at the south east of Turkey. It is a mature oil field and the reservoir is fractured carbonate reservoir. After producing about 1% original oil in place (OOIP) reservoir pressure started to decline. Waterflooding was started in order to support reservoir pressure and also to enhance oil production in 1960. Waterflooding improved the oil recovery but after years of flooding water breakthrough at the production wells was observed. This increased the water/oil ratio at the production wells. In order to enhance oil recovery again different techniques were investigated. Chemical enhanced oil recovery (EOR) methods are gaining attention all over the world for oil recovery. Surfactant injection is an effective way for interfacial tension (IFT) reduction and wettability reversal. In this study, 31 different types of chemicals were studied to specify the effects on oil production. This paper presents solubility of surfactants in brine, IFT and contact angle measurements, imbibition tests, and lastly core flooding experiments. Most of the chemicals were incompatible with Garzan formation water, which has high divalent ion concentration. In this case, the usage of 2-propanol as co-surfactant yielded successful results for stability of the selected chemical solutions. The results of the wettability test indicated that both tested cationic and anionic surfactants altered the wettability of the carbonate rock from oil-wet to intermediate-wet. The maximum oil recovery by imbibition test was reached when core was exposed 1-ethly ionic liquid after imbibition in formation water. Also, after core flooding test, it is concluded that considerable amount of oil can be recovered from Garzan reservoir by waterflooding alone if adverse effects of natural fractures could be eliminated.  相似文献   
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Multimedia Tools and Applications - Rapid advancement in technology has led to the use of biometric authentication in every field. In particular, from the past few years, iris recognition systems...  相似文献   
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Metallurgical and Materials Transactions A - Further development of high chromium cast irons (HCCI) is based on tailoring the microstructure, necessitating an accurate control over the phase...  相似文献   
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Oxylipins constitute a family of oxidized fatty acids, that are well known as tissue hormones in mammals. They contribute to inflammation and its resolution. The major classes of these lipid mediators are inflammatory prostaglandins (PGs) and leukotrienes (LTs) as well as pro-resolving resolvins (Rvs). Understanding their biosynthetic pathways and modes of action is important for anti-inflammatory interventions. Besides mammals, marine algae also biosynthesize mammalian-like oxylipins and thus offer new opportunities for oxylipin research. They provide prolific sources for these compounds and offer unique opportunities to study alternative biosynthetic pathways to the well-known lipid mediators. Herein, we discuss recent findings on the biosynthesis of oxylipins in mammals and algae including an alternative pathway to prostaglandin E2, a novel pathway to a precursor of leukotriene B4, and the production of resolvins in algae. We evaluate the pharmacological potential of the algal metabolites with implications in health and disease.  相似文献   
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Metal Science and Heat Treatment - The effect of solid boronizing at 950°C for 2 and 4 h on the phase composition, microstructure, hardness and abrasive wear of steel AISI 304L is studied...  相似文献   
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Different samples of xTeO2.(25-y)B2O3.zV2O5.yYb2O3 (or TBVY) new glass material were synthesized by the classical melt-quenching method. Structural, optical, physical, and thermal analyses of the synthesized glasses were performed in addition to Monte Carlo simulation to test radiation shielding properties. The results showed that increasing ratios of Yb2O3 (y = 0.0, 0.5, 1.0, and 1.5 mol%) produced monotonic density values of the synthesized glasses ranging from 4.70058 g cm?3 to 5.01038 g cm?3. XRD and FTIR analyses were used to confirm the glass structure of all samples. Optical transmittance and absorption parameters varied almost monotonically with increasing ratios of Yb2O3 indicating the ability to predict and control these properties using Yb2O3 additive. Furthermore, simulated radiation interaction parameters, such as attenuation coefficients and half-value layer, exhibited well-behaved dependence on the concentration ratio of the Yb2O3 additive. This approach to glass material synthesis demonstrate the useful synergetic effect of combining structural, optical, and radiation characteristics.  相似文献   
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Materials Science - We develop new methods of the laboratory defectometry of biocorroded microareas in structural steels based on the quantitative analysis of variations of their roughness. We...  相似文献   
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