琼脂/海藻酸钠质构性能的研究

琼脂与海藻酸钠以一定的比例进行混合之后,主要研究了琼脂/海藻酸钠混合凝胶的质构性能,混合之后的胶体随海藻酸钠含量增加,硬度,咀嚼性,弹性降低,而内聚性增加。     

粗粒钾盐矿捕收剂—助剂浮选

长烃链伯铵浮选钾盐矿的机理已经确立。必然性盐溶液中电解质浓度高，其中的矿粒和气泡双电完全被压缩了，测定感应时间证实了，盐溶液中矿粒－气泡附着间的能垒被消除，这使得ＫＣｌ表面接触角和在相应物化条件下天然钾盐浮选间的以关系得以确立。用各种不同的Ｅｓｓｏ油作为粗粒钾盐矿浮选的助剂。等电点和酸值测定证实氮类化合物含量高的Ｅｓｓｏ油是好的浮选助剂，通过液解少量长烃链脂肪胺于其中，这些油助剂的性能能得到进一步     

Modeling coagulation kinetics incorporating fractal theories: comparison with observed data

There are currently four possible approaches in modeling coagulation kinetics: the traditional Euclidean rectilinear; the Euclidean curvilinear; the fractal rectilinear; and the fractal curvilinear. The fractal model includes the Euclidean case as a subset. The primary purpose of this research is to investigate which of the rectilinear models among these best predicts the evolution of experimental observed particle size distribution (PSD). Using a fractal rectilinear model previously developed by the authors, model predictions were compared with a series of observed PSD data obtained from estuarine sediment particles in a 2m settling column, where the average velocity gradient (G) was 20 or 40s(-1). Nonlinear parameter estimation was performed to estimate two free parameters for the fractal model (the fractal dimension, DF, and the collision efficiency factor, a), and one free parameter (the collision efficiency factor, alpha) for the Euclidean model. Compared with the observed PSD, the simulation showed that the fractal rectilinear model was best, and that this model fit better for the larger size particles. The estimated DF was between 2.6 and 3.0. The research demonstrated that the alpha's have multiple values for the same observed data, depending on the coagulation model used. This finding is significant because a is currently used as a single value based on the conventional Euclidean rectilinear model.     

Alkylamine odors from degradation of flocculant polymers in sludges

The cationic organic polymers used to enhance thickening and dewatering processes are potential sources of strong odors. These polymers vary in chemical structure, and some may be more susceptible to biotic or abiotic degradation than others. The product organic amines will be volatilized most noticeably at high pH, as in lime addition. These possibilities were examined using several structural types of polymers combined with anaerobically digested sludge. Two commonly used polymers gave significant production of trimethylamine (TMA), which was released upon lime addition. Their structures were correlated with reactions that yield TMA. An initial ester hydrolysis step appears to be biologically mediated, but subsequent steps can occur due to alkaline conditions. An alternative cationic polymer structure did not generate TMA but required a much higher dose to effect sufficient conditioning of the sludge. The acrylamide-based polymers were shown to be the predominant source of TMA in limed sludges.     

Role of mass transfer in overall substrate removal rate in a sequential aerobic sludge blanket reactor treating a non-inhibitory substrate

A laboratory study was undertaken to explore the role of mass transfer in overall substrate removal rate and the subsequent kinetic behavior in a glucose-fed sequential aerobic sludge blanket (SASB) reactor. At the organic loading rates (OLRs) of 2-8 kg chemical oxygen demand (COD)/m³-d, the SASB reactor removed over 98% of COD from wastewater. With an increase in OLR, the average granule diameter (d_p = 1.1-1.9 mm) and the specific oxygen utilization rate increased; whereas biomass density of granules and solids retention time decreased (13-32 d). The intrinsic and apparent kinetic parameters were evaluated using break-up and intact granules, respectively. The calculated COD removal efficiencies using the kinetic model (incorporating intrinsic kinetics) and empirical model (incorporating apparent kinetics) agreed well with the experimental results, implying that both models can properly describe the overall substrate removal rate in the SASB reactor. By applying the validated kinetic model, the calculated mass transfer parameter values and the simulated substrate concentration profiles in the granule showed that the overall substrate removal rate is intra-granular diffusion controlled. By varying different d_p within a range of 0.1-3.5 mm, the simulated COD removal efficiencies disclosed that the optimal granular size could be no greater than 2.5 mm.     

Phosphorous retention capacity of filter media for estimating the longevity of constructed wetland

The filter medium could be selected and the longevity of the filter medium by the phosphorus saturation could be predicted in the constructed wetland system, accordingly proposing the scheme to remove the phosphorus for a long period. The phosphorus adsorption capacities of various filter media were investigated in relation to the size and types of filter media to screen the optimal condition. The objective of this study was to evaluate the constructed wetland longevity by improving P adsorption capacity. The maximum P adsorption capacities of filter media A (4--10 mm), B (2--4 mm), and C (0.1--2 mm) were 7.7, 11.6, and 22.5 mg/kg, respectively, showing that they increased as the filter media size decreased. Among the experimental media, the optimal filter media size was 0.1--2 mm. When Ca, Mg, Al and Fe were added to the filter medium C, which is the optimal filter medium, the addition of Ca improved mostly the P adsorption capacity. In the alternative proposal to use these facts, the oyster shell was added to the filter medium and the P adsorption capacity was examined: adding 2% oyster shell increased the P adsorption capacity from 23 to 36 mg/kg. In the column where the oyster shell was mixed, when the oyster shell content was 5%, 10%, 20%, 40%, 60%, 80%, and 100% in the filter medium C, the respective saturation times of the P adsorption were about 6, 9, 17, 30, 43, 56, and 70 days. When the oyster shell content was 0%, 5%, 10%, 20%, 40%, 60%, 80%, and 100% after 1 month in the column, the P adsorption amount was about 180, 600, 1560, 4280, 6157, 7089, 7519, and 7925 mg/kg, respectively. The increment of the P adsorption amount was small if the oyster shell content was 60% or more, because the filter medium with more than 60% oyster shell content did not approach the saturation time by the P adsorption yet. The P adsorption amount for 60%, 80%, and 100% could be predicted as about 9702, 12,879, and 16,056 mg/kg, respectively. The largest amount of extracted P in the filter media with oyster shell after 30 days of P solution application was bound to Ca, followed by water soluble-P, Al--P, and Fe--P. Therefore, it was concluded that the adsorption amount of the phosphorus could be increased by adding the oyster shell to the filter medium. Also, it was concluded that adding the oyster shell to the filter medium in the constructed wetland was the scheme to extend the longevity of the constructed wetland by the phosphorus saturation, and using the oyster shell would be useful in aspect of economical efficiency and easiness. Especially, it would be the alternative proposal to reduce the environmental pollution in aspect of recycling wastes.     

Mercury and methylmercury concentrations in high altitude lakes and fish (Arctic charr) from the French Alps related to watershed characteristics

Total mercury (THg) and methylmercury (MeHg) concentrations were measured in the muscle of Arctic charr (Salvelinus alpinus) and in the water column of 4 lakes that are located in the French Alps. Watershed characteristics were determined (6 coverage classes) for each lake in order to evaluate the influence of watershed composition on mercury and methylmercury concentrations in fish muscle and in the water column. THg and MeHg concentrations in surface water were relatively low and similar among lakes and watershed characteristics play a major role in determining water column Hg and MeHg levels. THg muscle concentrations for fish with either a standardized length of 220 mm, a standardized age of 5 years or for individualuals did not exceed the 0.5 mg kg^− 1 fish consumption advisory limit established for Hg by the World Health Organization (WHO, 1990). These relatively low THg concentrations can be explained by watershed characteristics, which lead to short Hg residence time in the water column, and also by the short trophic chain that is characteristic of mountain lakes. Growth rate did not seem to influence THg concentrations in fish muscles of these lakes and we observed no relationship between fish Hg concentrations and altitude. This study shows that in the French Alps, high altitude lakes have relatively low THg and MeHg concentrations in both the water column and in Arctic charr populations. Therefore, Hg does not appear to present a danger for local populations and the fishermen of these lakes.     

Cortisol levels in hair of East Greenland polar bears

To demonstrate the ability to assess long-term hypothalamic-pituitary-adrenocortical (HPA) axis activity in polar bears (Ursus maritimus), a pilot study was conducted in which cortisol concentrations was analyzed in hair from 7 female (3-19 years) and 10 male (6-19 years) East Greenland polar bears sampled in 1994-2006. The hair was chosen as matrix as it is non-invasive, seasonally harmonized, and has been validated as an index of long-term changes in cortisol levels. The samples were categorized according to contamination: eight were clean (2 females, 6 males), 5 had been contaminated with bear blood (2 F, 3 M), and 4 with bear fat (3 F, 1 M). There was no significant difference in cortisol concentration between the three categories after external contamination was removed. However, contaminated hair samples should be cleaned before cortisol determination. Average hair cortisol concentration was 8.90 pg/mg (range: 5.5 to 16.4 pg/mg). There was no significant correlation between cortisol concentration and age (p = 0.81) or sampling year (p = 0.11). However, females had higher mean cortisol concentration than males (females mean: 11.0 pg/mg, males: 7.3 pg/mg; p = 0.01). The study showed that polar bear hair contains measurable amounts of cortisol and that cortisol in hair may be used in studies of long-term stress in polar bears.     

Fluorine geochemistry in bedrock groundwater of South Korea

High fluoride concentrations (median=4.4 mg/L) in deep bedrock groundwater of South Korea prevent the usage of it as a drinking water source. The hydrogeochemistry of deep thermal groundwaters (N=377) in diverse bedrocks has been studied in order to evaluate the geologic and geochemical controls on fluoride concentrations in groundwater. The groundwater samples were clustered geologically, and the average and median concentrations of fluoride were compared by the Mann-Whitney U test. The order of median fluoride concentration with respect to geology is as follows: metamorphic rocks> or =granitoids > or =complex rock>volcanic rocks> or =sedimentary rocks. This result indicates that the geological source of fluoride in groundwater is related to the mineral composition of metamorphic rocks and granitoids. With respect to groundwater chemistry, the fluoride concentration was highest in Na-HCO3 type groundwater and lowest in Ca-HCO3 type groundwater. Ionic relationships also imply that the geochemical behavior of fluoride in groundwater is related to the geochemical process releasing Na and removing Ca ions. The thermodynamic relationship between the activities of Ca and F indicates that fluoride concentration is controlled by the equilibrium of fluorite (CaF2). In other words, the upper limits of fluoride concentration are determined by the Ca ion; i.e., Ca concentrations play a crucial role in fluoride behavior in deep thermal groundwater. The result of this study suggests that the high fluoride in groundwater originates from geological sources and fluoride can be removed by fluorite precipitation when high Ca concentration is maintained. This provides a basis for a proper management plan to develop the deep thermal groundwater and for treatment of high fluoride groundwater frequently found in South Korea.